• 제목/요약/키워드: polysiloxane

검색결과 74건 처리시간 0.021초

Effect of impression coping and implant angulation on the accuracy of implant impressions: an in vitro study

  • Jo, Si-Hoon;Kim, Kyoung-Il;Seo, Jae-Min;Song, Kwang-Yeob;Park, Ju-Mi;Ahn, Seung-Geun
    • The Journal of Advanced Prosthodontics
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    • 제2권4호
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    • pp.128-133
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    • 2010
  • PURPOSE. The purpose of this study was to compare the accuracy of the implant master cast according to the type (pick-up, transfer) and the length (long, short) of the impression copings. MATERIALS AND METHODS. The metal master cast was fabricated with three internal connection type implant analogs (Osstem GS III analog), embedded parallel and with $10^{\circ}$ of mesial angulation to the center analog. Four types of impression coping were prepared with different combinations of types (transfer, pick-up) and lengths (long, short) of the coping. The impressions were made using vinyl polysiloxane (one step, heavy + light body) with an individual tray, and 10 impressions were made for each group. Eventually, 40 experimental casts were produced. Then, the difference in the distance between the master cast and the experimental cast were measured, and the error rate was determined. The analysis of variance was performed using the SPSS (v 12.0) program (${\alpha}$= .05), and the statistical significance was set at P < .05. RESULTS. The ANOVA showed that the pick-up type impression coping exhibited a significantly lower error rate than the transfer type. However, no significant difference was observed with respect to the length of the impression coping. Additionally, no significant difference was observed between the parallel and mesial angulated groups. CONCLUSION. Within the limitations of this study, the pick-up type impression coping exhibited a more accurate implant master cast than the transfer type in parallel group. The accuracy of the implant master cast did not differ for different lengths of impression coping of at least 11 mm. Additionally, the accuracy of the implant cast was not different for the parallel and $10^{\circ}$ mesial angulated groups.

Evaluation of internal fit of interim crown fabricated with CAD/CAM milling and 3D printing system

  • Lee, Wan-Sun;Lee, Du-Hyeong;Lee, Kyu-Bok
    • The Journal of Advanced Prosthodontics
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    • 제9권4호
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    • pp.265-270
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    • 2017
  • PURPOSE. This study is to evaluate the internal fit of the crown manufactured by CAD/CAM milling method and 3D printing method. MATERIALS AND METHODS. The master model was fabricated with stainless steel by using CNC machine and the work model was created from the vinyl-polysiloxane impression. After scanning the working model, the design software is used to design the crown. The saved STL file is used on the CAD/CAM milling method and two types of 3D printing method to produce 10 interim crowns per group. Internal discrepancy measurement uses the silicon replica method and the measured data are analyzed with One-way ANOVA to verify the statistic significance. RESULTS. The discrepancy means (standard deviation) of the 3 groups are $171.6\;(97.4){\mu}m$ for the crown manufactured by the milling system and 149.1 (65.9) and $91.1\;(36.4){\mu}m$, respectively, for the crowns manufactured with the two types of 3D printing system. There was a statistically significant difference and the 3D printing system group showed more outstanding value than the milling system group. CONCLUSION. The marginal and internal fit of the interim restoration has more outstanding 3D printing method than the CAD/CAM milling method. Therefore, the 3D printing method is considered as applicable for not only the interim restoration production, but also in the dental prosthesis production with a higher level of completion.

Evaluation of different approaches for using a laser scanner in digitization of dental impressions

  • Lee, Wan-Sun;Kim, Woong-Chul;Kim, Hae-Young;Kim, Wook-Tae;Kim, Ji-Hwan
    • The Journal of Advanced Prosthodontics
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    • 제6권1호
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    • pp.22-29
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    • 2014
  • PURPOSE. This study aimed to investigate the potential clinical application of digitized silicone rubber impressions by comparing the accuracy of zirconia 3-unit fixed partial dentures (FPDs) fabricated from 2 types of data (working model and impression) obtained from a laser scanner. MATERIALS AND METHODS. Ten working models and impressions were prepared with epoxy resin and vinyl polysiloxane, respectively. Based on the data obtained from the laser scanner (D-700; 3Shape A/S, Copenhagen, Denmark), a total of 20 zirconia frameworks were prepared using a dental CAD/CAM system (DentalDesigner; 3shape A/S, Copenhagen, Denmark / Ener-mill, Dentaim, Seoul, Korea). The silicone replicas were sectioned into four pieces to evaluate the framework fit. The replicas were imaged using a digital microscope, and the fit of the reference points (P1, P2, P3, P4, P5, P6, and P7) were measured using the program in the device. Measured discrepancies were divided into 5 categories of gaps (MG, CG, AWG, AOTG, OG). Data were analyzed with Student's t-test ($\alpha$=0.05), repeated measures ANOVA and two-way ANOVA (${\alpha}=0.05$). RESULTS. The mean gap of the zirconia framework prepared from the working models presented a narrower discrepancy than the frameworks fabricated from the impression bodies. The mean of the total gap in premolars (P=.003) and molars (P=.002) exhibited a statistical difference between two groups. CONCLUSION. The mean gap dimensions of each category showed statistically significant difference. Nonetheless, the digitized impression bodies obtained with a laser scanner were applicable to clinical settings, considering the clinically acceptable marginal fit ($120{\mu}m$).

고분자의 자체발포를 이용한 세라믹 다공질체 (Ceramic Foams by the Self-Blowing of Polymer)

  • 백종원;김득중
    • 한국세라믹학회지
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    • 제41권7호
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    • pp.555-559
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    • 2004
  • 폴리실록산 고분자의 자가 발포과정을 이용하여 세라믹 다공질체를 제조하였다. 고분자가 가교반응을 하는 과정에서 발생하는 물과 알콜 증기를 이용하면 고분자 용융액 내에 기공을 형성할 수 있다. 세라믹 다공질체 내의 기공의 크기와 모양은 고분자 용융액의 점도에 따라 크게 달라진다. 충진제인 A1$_2$O$_3$ 함량이 증가하면 기공 크기는 감소하며 이는 A1$_2$O$_3$의 입자크기가 감소하여도 비슷한 양상을 보였다. 고분자 용융액의 점도는 고분자의 가교반응정도에 따라서도 영향을 받는다. 발포 전에 13$0^{\circ}C$에서 열처리를 하면 점도는 증가하며 다공질체의 기공 안정성은 증가한다. 제조된 세라믹 다공질체의 밀도와 압축강도는 발포과정에서의 승온속도에 따라 다른 값을 보였다.

세개의 Gauss 동을 중첩한 간섭계형 결상계의 진폭임펄스와 초분해능 (Amplitude impulse and superresolution of interferometric imaging system obtained by superposing three Gauss pupils)

  • 송영란;이민희;이상수
    • 한국광학회지
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    • 제8권1호
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    • pp.1-6
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    • 1997
  • 역변환 문제(Inverse Problem)로 접근하여 상면에서의 최초 진폭임펄스 S$_{0}$(x)를 Gauss 함수 g$_{1}$(x), -1/2g$_{2-}$ (x+.DELTA.x$_{1}$), -1/2g$_{2+}$(x-.DELTA.x$_{1}$)를 중첩하여 설정하였다. 이를 Inverse Fourier Transform으로 동함수 A(.omega.)를 구하고, 유한구경 (-.omega.$_{0}$~+.omega.$_{0}$)에서 A(.omega)를 Fourier Transform하여 회절상의 진폭임펄스(Amplitude Impulse) S(x)를 구하였다. .lambda.=193nm, NA=0.5인 광학계에서 S(x)의 반치폭, 즉 1/2(FWHM)을 수치계산하여 49nm를 얻었다. 이는 Rayleigh 한계분해능 .epsilon.$_{R}$의 반, 1/2.epsilon.$_{R}$=96.5nm 보다 작으므로 초분해능 광학계임을 알 수 있다. OTF를 구하여 광학계의 성능을 평가한 결과 고주파영역에서 성능이 우수함을 알 수 있었다. 광학계는 Twyman-Green 간섭계를 포함하는 간섭결상계가 되고, Gauss 진폭변조판은 Polysiloxane Glass Resin을 사용하여 만들 수 있음을 제안하였다.제안하였다.

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썬글라스용 반미러(Half-Mirror) 코팅의 분석과 설계 (Analysis and Design of half-mirror coating for sunglasses)

  • 박문찬;정부영;횡보창권
    • 한국안광학회지
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    • 제8권2호
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    • pp.111-117
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    • 2003
  • 국내외 썬글라스 반미러 코팅렌즈의 광학적 특성을 파악하기 위해, 분광광도계를 이용하여 반미러 코팅렌즈의 반사율을 측정하였으며, Macleod 프로그램을 이용해 계산한 결과와 비교 분석하였다. 또한 황금 색깔이 나는 TiN을 이용한 반미러 코팅렌즈를 설계하였고, 광학특성을 조사하였다. 반미러 코팅렌즈의 분석결과, 은색 투톤(two tone) 반미러 코팅은 금속 크롬(Cr)을 사용하였으며 경도를 증가시키기 위하여 크롬위에 $SiO_2$(또는 $Al_2O_3$)를 증착하여 사용하였다. 크롬 위에 증착되는 $SiO_2$의 두께는 10nm 정도가 적정한 것으로 판단된다. 칼라 반미러 코팅의 경우 디자인 결과는 각각 다음과 같다 ; blue 계열은 [air|$SiO_2$(66.3)|$TiO_2$(129.0)|$SiO_2$(62.9)|$SiO_2$(26.0)|$TiO_2$(120.3)|$SiO_2$(9.1)|glass]이며, gold 계열은 [air|$SiO_2$(60.6)|$TiO_2$(86.2)|$SiO_2$(13.5)|$TiO_2$(86.8)|$SiO_2$(214.38)|glass]이며, green 계열은 [air|$SiO_2$(74.3)|$TiO_2$(75.8)|$SiO_2$(44.3)|$TiO_2$(11.6)|$SiO_2$(160.8)|$TiO_2$(12.9)|$SiO_2$(183.3)|$TiO_2$(143.8)|glass]이며, silver 계열은 [air|$SiO_2$(21.2)|$TiO_2$(49.7)|$SiO_2$(149.3)|glass]이다. white 반미러 코팅인 경우는 [air|$SiO_2$(17nm)|$TiO_2$(43nm)(또는 $ZrO_2$)|$SiO_2$(87nm) polysiloxane($4.46{\mu}m$)|glass or CR-39]이며, 가시광선 영역(400~700 nm)에서 평균 19%의 반사율을 가지며 흡수가 적기 때문에 약 80%의 투과율을 보이는 white 타입의 반미러가 되게 된다. 황금빛 색깔을 띠는 반미러 코팅렌즈의 설계에 있어서 [air|$SiO_2$(170nm)|TiN(15nm)|glass]가 되면 CIE 좌표값은 거의 [air|Au(150nm)|glass]의 좌표값과 유사해지는 것을 볼 수 있었다.

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발전구조물의 환경조건을 반영한 도장계 선정 경제성 평가 모델 개발 (Development of an Economic Evaluation model for Coating System Based on Environmental Conditions of Power Generation Structure)

  • 김인태;이수영;안진희;김창학
    • 대한토목학회논문집
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    • 제40권1호
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    • pp.77-85
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    • 2020
  • 현재 국내의 대형 인프라시설물의 유지관리를 위해 생애주기비용분석 방법을 도입하고 있다. 그러나 시설물의 위치 및 주변환경 등의 조건을 반영한 유지관리 모델을 적용하는 사례가 많지 않다. 적절한 유지관리 전략을 수립하기 위해서는 시설물의 환경조건을 반영한 비용예측, 열화모델, 불확실성을 반영한 의사결정모델이 수립되어야 한다. 본 연구에서는 발전구조물에 적용되는 도장 사양을 대상으로 유지관리 방법과 판단기준에 따라 사용자의 의사결정에 따른 장기적인 비용 계획 및 관리를 할 수 있는 경제성 분석 모델을 개발하였다. 경제성 분석 모델의 적용을 위하여 도장열화실험을 통하여 도장의 성능을 평가하였으며, 제안 경제성 분석 모델에 적용하여 각각의 적용도장 사양(우레탄, 폴리실록산, 불소)에 따른 경제성 분석결과를 확인하였다. 본 연구에서는 도장의 성능보다 보수 주기의 선정과 개발 모델을 적용한 평가 방법을 제시한 결과로 도장에 국한되지 않더라도 유지관리 방안 수립 시 보수 주기 등을 위한 기초적인 자료로 활용을 기대할 수 있을 것으로 판단된다.

COMPARATIVE ACCURACY OF THE SPLINTED AND UNSPLINTED IMPRESSION METHODS FOR INTERNAL CONNECTION

  • Choi, Jung-Han;Kim, Chang-Whe;Jang, Kyung-Soo;Lim, Young-Jin
    • 대한치과보철학회지
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    • 제43권3호
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    • pp.352-362
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    • 2005
  • Statement of problem. Accurate impression is essential to success of implant prostheses. But there have been few studies about the accuracy of fixture-level impression techniques in internal connection implant systems. Purpose. The purpose of this study was to compare the accuracy of two fixture-level impression techniques in two conditions (parallel and divergent) and to assess the effect of tightening sequences and forces on stresses generated on superstructures in internal connection implant system (Astra Tech). Material and methods. Two metal master frameworks made from two abutments (Cast-to Abutment ST) each and a corresponding, passively fitting, dental stone master cast with four fixture replicas (Fixture Replica ST) were fabricated. Ten dental stone casts for each impression techniques (direct unsplinted & splinted technique) were made with vinyl polysiloxane impressions from the master cast. Strain gauges for each framework were fixed midway between abutments to measure the degree of framework deformation on each stone cast. Pairs of strain gauges placed opposite each other constituted one channel (half Wheatstone bridge) to read deformation in four directions (superior, inferior, anterior, and posterior). Deformation data were analyzed using one-way ANOVA and the Tukey test at the .01 level of significance. And the effect of tightening sequences (right-to-left and left-to-right) and forces (10 Ncm and 20 Ncm) were assessed with ten stone casts made from parallel condition by the splinted technique. Deformation data were analyzed using paired t-test at the .01 level of significance. Conclusions. Within the limitations of this study, the following conclusions could be drawn. 1. Frameworks bent toward the inferior side on all casts made by both direct unsplinted and splinted impression techniques in both parallel and divergent conditions. 2. There was no statistically significant difference of accuracy between the direct unsplinted and splinted impression techniques in both parallel and divergent conditions (P>.01). 3. There was no statistically significant difference of stress according to screw tightening sequences in casts made by the splinted impression technique in parallel condition (P>.01). 4. Greater tightening force resulted in greater stress in casts made by the splinted impression technique in parallel condition (P<.01).

임상적 방법을 이용한 내부연결 임플랜트에서 고정체수준 인상법의 정확도 평가 (EVALUATION OF THE ACCURACY OF FIXTURE-LEVEL IMPRESSION TECHNIQUE FOR INTERNAL CONNECTION IMPLANT USING CLINICAL METHODS)

  • 최정한
    • 대한치과보철학회지
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    • 제44권4호
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    • pp.421-431
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    • 2006
  • Statement of problem : Accurate impression is essential to success of implant prostheses. But there have been few studies about the accuracy of fixture-level impression technique in internal connection implant system. Purpose: This study evaluated the accuracy of splinted fixture-level impression technique using clinical methods and the effect of internal hex on fit of superstructure in internal connection implant system (Astra Tech). Material and method : Two metal master frameworks made from two abutments (Cast-to Abutment ST) each for parallel and divergent conditions and a corresponding. passively fitting, dental stone master cast with four future replicas (Fixture Replica ST) were fabricated. Ten dental stone casts were made with vinyl polysiloxane impressions from the master cast by acrylic resin splinted fixture-level impression technique. To evaluate the accuracy of impression technique, the fit of master frameworks for test models was evaluated using screw resistance test (SRT) and one-screw test. The results of SRT were recorded as SRT values from grade 1 to grade 5 by 1/4 turn. And to evaluate the effect of hex on fit of superstructure, the same tests were performed after removing hexes of master frameworks. Results: 1. There was only one case (2.5%) showing SRT value of test model below ade 2 in total before and after removing hexes of master frameworks. And, by removing hexes. SRT values decreased in only one test model (5%) and did not change in 17 test models (85%). 2. SRT values of the 1$^{st}$ screws were grade 2 in 80% of cases before, and grade 1 in 80% of cases after removing hexes. And, by removing hexes, SRT values decreased in 72.5% of cases. 3. SRT values of the 2$^{nd}$ screws were grade 3 in 85% of cases before, and grade 3 in 95% of cases after removing hexes. And, by removing hexes, SRT values did not change in 85% of cases. 4. There were only 2 cases regarded as acceptable fit by one-screw test, and SRT values of 2$^{nd}$ screws of both cases were grade 2. Conclusion. Within the limitations of this study, future-level impression of internal connection implant system is considered to obtain inaccurate working cast, even using acrylic resin splinted impression technique. And, it is considered to be unable improve the fit to remove the hexes of implant restoration.

소수성 폴리이미드공중합체 막에 의한 저농도 톨루엔함유 수용액의 투과증발분리 (Pervaporation Separation of Trace Toluene from Water Using Hydrophobic Copolyimide Membranes)

  • 김정훈;장봉준;이수복
    • 멤브레인
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    • 제17권4호
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    • pp.287-293
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    • 2007
  • 수질오염을 일으키는 휘발성 유기 화합물(Volatile Organic Compounds; VOCs)의 대표적인 종류의 하나인 저농도의 톨루엔이 함유된 수용액을 소수성 폴리이미드공중합체막을 이용한 투과증발법으로 분리하였다. 이를 위해 폴리실록산디아민(SIDA)과 과불소알킬기를 가진 방향족 디아민(PFDAB)의 비율에 따른 폴리이미드 공중합체 막을 제조하였다. 막제조에 사용된 SIDA/PFDAB 비에 따른 선택투과특성의 변화를 살펴보았다. 얻어진 투과특성을 용해확산이론으로 해석하기 위해 톨루엔 수용액의 수착특성을 조사하였으며 이를 토대로 확산도 특성을 조사하였다. 그 결과 실록산 고분자에 대한 톨루엔의 친화도의 증가로 SIDA의 함량이 많을수록 막 내의 톨루엔에 대한 용해도 및 톨루엔/물의 수착선택도가 커졌으며, 자유부피가 큰 실록산의 함량증가로 인해 톨루엔의 확산계수, 확산선택도가 증가하는 것을 확인하였다. 이러한 결과로 SIDA의 함량이 증가함에 따라 톨루엔에 대한 투과도는 0.005 $kg/m^2h$에서 0.049 $kg/m^2h$로 증가하고, 톨루엔/물의 투과선택도는 9에서 6380로 증가함을 관찰하였다.