• Title/Summary/Keyword: polymorph

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New Data on the Synthetic $Pt_{34}Sb_7$ and $Pt_3Sb$ Phases (합성화합물 $Pt_{34}Sb_7$$Pt_3Sb$에 대한 새로운 자료)

  • 김원사
    • Journal of the Mineralogical Society of Korea
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    • v.1 no.1
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    • pp.15-19
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    • 1988
  • In the process of re-checking the phase relations of the Pt-Sb system the previously reported Pt4+Sb phase did not occur. Instead, Pt34Sb7 phase with an average chemical composition (wt%) Pt 89.3, Sb 11.4, total 100.7, has been newly found to exist, and the formula Pt34Sb7 has been tentatively assigned to it, It is pale brownish grey to yellowish grey under refloecting microscope and non-bireflectant, VHN100=225 (206-243). X-ray powder patterns are (d(I/Io)): 2.318(100), 2.293(100), 2.110(30), 1.440(50), 1.390(15), 1.283(5), 1.203(70) and 1.192(40)$\AA$. They are indexable on the basis of tertragonal cell with $\alpha$=3.948(3), c=16.85(1)$\AA$. A question whether the tetragonal Pt34Sb7 is the new phase or a polymorph of the cubic Pt4+Sb phase remains unclear and awaits better X-ray diffraction, electron microprobe analysis and DTA for the Pt4+Sb phase. The Pt3Sb phase reported to be of tetragonal symmetry has been confirmed to exist. It is greyish yellow in air and in oil, very weakly bireflectant, and weakly anisotropic. VHN25=216 (183-240). Its X-ray powder data have been successively indexed on a tetragonal cell with $\alpha$=3.9455(7), c=16.959(5)$\AA$.

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Differences in Characteristics of Recycled ONP for CaCO3 Adding Techniques (CaCO3 첨가법에 따른 재생 ONP의 특성변화)

  • Ahn, Young-Jun;Nam, Seong-Young;Um, Nam-Il;Ahn, Ji-Whan;Han, Choon
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.97-102
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    • 2014
  • In order to improve the refresh rate of old newspaper(ONP), PCC shape-controlling experiments were carried out. The effect of a PCC polymorph on improving the quality of old newspaper was studied for a transformation from waste paper to eco-friendly paper. The synthesis of PCC consists of an in-situ process and a loading process to enhance the refresh rate of old newspaper. The characteristics between the in-situ process and the loading process could be analysed by SEM analyses of coated fiber surfaces. The retention rate ranges from 65 to 67% after the application of the in-situ process, and that after the loading process ranges from 55 to 58%. The retention rates thus show a difference of about 7-10%. In addition, the whiteness and ERIC characteristics of the in-situ process gave more efficient results than those of the loading process.

Genetic Polymorphisms in Drug Transporters and Regulatory Xenobiotic Receptors in Korean Population

  • Lee, Sang-Seop;Shin, Jae-Gook
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2004.05a
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    • pp.27-29
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    • 2004
  • Drug transporters play an essential role in the absorption, distribution and elimination of clinical drugs, nutrients and toxicants. The importance of the transporters is exampled by therapeutic failure in cancer chemotherapy that is mainly caused by the overexpression of multidrug resistance (MDR)-related transporters. In addition, the transporters may involve in drug-drug interactions that lead to serious adverse drug responses and some transporters also contribute to inter-individual variation in drug responses. As an effort to understand the mechanism underlying the inter-individual variation of transporters activity, genetic and environmental factors influencing the expression or function of the transporters have extensively explored through last decade. Among them, genetic polymorphism of drug transporter encoding genes has generated much interest since the discovery of functional single nucleotide polymorphisms (SNP) of MDRl gene. Besides drug transporters, xenobiotic receptors also modulate drug disposition by regulating the transcription of drug metabolizing enzymes and drug transporters. Among many xenobiotic receptors, pregnane X receptor (PXR) and constitutive androstane receptor (CAR) are two most well characterized since these receptors show wide substrate specificities and regulate the expression of various enzymes involved in drug disposition. Recently, several functional genetic polymorphisms were reported in PXR coding gene. In the present study, genetic polymorph isms of two drug transporters, MDR1 and BCRP, and two xenobiotic receptors, PXR and CAR, were investigated in Korean population.

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Electrical Characteristics According to the Manufacturing Process of the Flexible Li/MnO2 Primary Cell (플렉서블 Li/MnO2 일차전지의 제조공정에 따른 전기적 특성)

  • Lee, Mi-Jai;Chae, Yoo-Jin;Kim, Jin-Ho;Hwang, Jong-Hee;Park, Sang-Sun
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.717-721
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    • 2012
  • Manganese dioxide ($MnO_2$) is one of the most important cathode materials used in both aqueous and non-aqueous batteries. The $MnO_2$ polymorph that is used for lithium primary batteries is synthesized either by electrolytic (EMD-$MnO_2$) or chemical methods (CMD-$MnO_2$). Commonly, electrolytic manganese dioxide (EMD) is used as a cathode mixture material for dry-cell batteries, such as a alkaline batteries, zinc-carbon batteries, rechargeable alkaline batteries, etc. The characteristics of lithium/manganese-dioxide primary cells fabricated with EMD-$MnO_2$ powders as cathode were compared as a function of the parameters of a manufacturing process. The flexible primary cells were prepared with EMD-$MnO_2$, active carbon, and poly vinylidene fluoride (PVDF) binder (10 wt.%) coated on an Al foil substrate. A cathode sheet with micro-porous showed a higher discharge capacity than a cathode sheet compacted by a press process. As the amount of EMD-$MnO_2$ increased, the electrical conductivity decreased and the electrical capacity increased. The cell subjected to heat-treatment at $200^{\circ}C$ for 1 hr showed a high discharge capacity. The flexible primary cell made using the optimum conditions showed a capacity and an average voltage of 220 mAh/g and 2.8 V, respectively, at $437.5{\mu}A$.

Mapping QTLs for drought tolerance using an introgression line population from a cross between Ilpumbyeo and Moroberekan in rice (벼 일품벼/모로베레칸 조합의 이입계통을 이용한 내건성 유전자 탐지)

  • Kang, Ju-Won;Ju, Hong-Guang;Yang, Paul;Ahn, Sang-Nag
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.199-204
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    • 2011
  • This study was conducted to map quantitative trait loci (QTLs) related to drought stress tolerance. An introgression line population derived from a cross, "Ilpum" / "Moroberekan" was used in this study. $F_1$ plants were backcrossed three times to Ilpum to produce $BC_3F_1$ plants. These plants were advanced by selfing for four generation and a total of 117 $BC_3F_5$ introgression lines were developed. These lines were evaluated for percent seed set and spikelets per panicle under the control (field) and drought condition. To identify QTLs related to drought tolerance, 134 SSR markers showing polymorph isms between the parents were genotyped for the 117 $BC_3F_5$ lines. A total of 6 QTLs associated with drought stress were detected on chromosomes 1, 3, 4, 7 and 10. These include two QTLs for phenotypic acceptability, two QTLs for percent seed set ($R^2$ = 19.0 - 20.9%), and two QTLs for spikelets per panicle ($R^2$ = 22.3 - 23.10%). The Moroberekan alleles at three loci contributed the positive effect for drought tolerance. The SSR markers linked to drought stress tolerance can not only facilitate the selection of valuable genes from Moroberekan, but also allow identification of lines with drought tolerance.

STAT6 Gene Polymorphisms in Allergic Rhinitis

  • Kim, Jeong Joong;Kim, Min Su;Lee, Jung Hun;Choi, Tae Wook;Choi, Sang Heon;Lee, Jae Hoon;Chung, Hun Taeg
    • Genomics & Informatics
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    • v.2 no.3
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    • pp.126-130
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    • 2004
  • T helper-type 2 cytokines, such as IL-4 and IL-13, may play a central role in allergic diseases. The protein known as signal transducers and activators of transcription 6 (STAT6) is a key transcription factor involved in both IL-4- and -13-mediated biological responses. Two polymorphisms of the STAT 6 gene (exon 1 and G2964A variant) have been found. We investigated whether these STAT6 gene polymorph isms were associated with allergic rhinitis. Blood samples for genetic analysis were obtained from 285 individuals with allergic rhinitis and from 271 healthy subjects without atopic disease. The G2964A variant of the STAT6 gene was genotyped using PCR-RFLP analysis. The GT repeat polymorphism in exon 1 of the STAT6 gene was genotyped by fragment analysis. There was no association between the 2964A variant and GT repeat polymorphism in exon 1 of the STAT6 and allergic rhinitis in a Korean population (both p > 0.05). Our results suggest that a combination of STAT6 gene polymorphisms is not a useful marker for predicting allergic rhinitis.

Preparation of Lignocellulose Nanofiber by Mechanical Defibrillation After Pretreatment Using Cosolvent of Ionic Liquid and DMF (이온성 액체/DMF 혼합용매 전처리 후 기계적 해섬을 통한 리그노셀룰로오스 나노섬유의 제조)

  • Han, Song-Yi;Park, Chan-Woo;Lee, Seung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.3
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    • pp.268-277
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    • 2017
  • In this study, lignocellulose nanofibrils (LCNFs) were prepared from Pussy willow wood powder by disk-milling after pretreatment using the cosolvent of 1-ethyl-3-methylimidazolium acetate ([EMIM]Ac) and N,N-dimethylformamide (DMF) with different mixing ratios for different time. All pretreated samples showed native cellulose I polymorph and cellulose crystallinity was lowest when cosolvent of DMF with 30% [EMIM]Ac was used. Average crystallite size of raw material and the pretreated product by MDF and its cosolvent with 10% [EMIM]Ac was found to be about 3.2 nm and decreased with increasing pretreatment time at the DMF cosolvent with 30% [EMIM]Ac. Defibrillation efficiency was improved by loosening wood cell wall structure by the pretreatment using co-solvent system of [EMIM]Ac and DMF.

TEM Investigations of Structures and Phase Transitions in Tridymite (투과전자현미경을 이용한 Tridymite의 구조 및 상전이 연구)

  • 김윤중
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.44-58
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    • 2002
  • A new polymorph of tridymite, an incommensurately modulated phase (IC phase), has been identified. While the symmetry of the IC lattice is same as that of the Ll phase, the geometry of the IC lattice structure is same as the basis of the L3 structure with a different modulation (modulation vector q=0.22 $c*_{H}$;$\lambda$ 37 ). On the other hand, the characteristic curved diffuse diffration observed from the Ll atoms could occur even at room phase suggests that the dynamic disordering of atoms, especially oxygen atoms could occur even at room temperature. The phase transition of Ll to L3 by grinding is gradual but very conspicuous: LllongrightarrowL1+IClongrightarrowIC+L3longrightarrowL3. However, it is revealed that real transition processes of individual grains are directly related to the local stress fields and preexisting microstructures.

Process variables of gamma-type aluminum trihydride in wet chemical synthesis (감마형 삼수소 알루미늄 습식합성반응의 공정변수 연구)

  • Yang, Yo-Han;Kim, Woo-Ram;Gwon, Yoon-Ja;Park, Mi-Jeong;Kim, Jun-Hyung;Cho, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.214-222
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    • 2018
  • Alane(aluminum trihydride, $AlH_3$) is a candidate material involving high energetic capacity for solid propellant or explosives. In this study aluminum trihydride-etherate ($AlH_3{\cdot}(C_2H_5)_2O$) was synthesized through a wet process, and solid alane was extracted by controlled crystallization. Alane crystals were grown during the crystallization step with phase conversion of aluminum trihydride-etherate to alane using an anti-solvent. Stable crystal forms were found by a 2 hour crystallization process at $85^{\circ}C$. Finally the extracted solid aluminium trihydride consisted mainly of ${\gamma}-type$ with $50-100{\mu}m$ in size.

Fabrication of Crystalline $ZrO_2$ Nanotubes by ALD

  • Kim, Hyeon-Cheol;Panda, Sovan K.;Yu, Hyeon-Jun;Kim, Myeong-Jun;Yang, Yun-Jeong;Lee, Seon-Hui;Sin, Hyeon-Jeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.241.1-241.1
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    • 2011
  • Numerous possible applications for $ZrO_2$ nanotubes exist such as for catalyst support structures, for sensing or for applications as a solid state electrolyte. Especially, because of a large specific surface area, high efficiency for solid oxide fuel cell (SOFC) application at low temperature can be expected for nanotublar structures in even small size. A zirconium precursor, Tetrakis (ethylmethylamino) zirconium, TEMAZr and $H_2O$ oxidant were used to deposit$ZrO_2$ thin films on an anodized aluminum oxide (AAO) templates having sub-100nm cylindrical pores by atomic layer deposition (ALD) in the temperature range of 150~250$^{\circ}C$. The crystalline structures of as-prepared and post-annealed $ZrO_2$ nanotubes were characterized by x-ray diffraction and high-resolution transmission electron microscopy. The as-prepared samples at $150^{\circ}C$ and $200^{\circ}C$ were showed amorphous, whereas a mixed phase of tetragonal, monoclinic and amorphous polymorph was observed at $250^{\circ}C$. In the bulk, zirconia remains monoclinic phase up to $1,175^{\circ}C$, however, $ZrO_2$ nanotubes were showed tetragonal phase upon post thermal treatments merely at $400^{\circ}C$. This trend may be indicative of high-curvature surfaces of nanotubes and thereby the presence of intrinsic compressive strain. The amount of amorphous structures in the mixed phase as well as as-grown $ZrO_2$ nanotubes were also gradually decreased by subsequent heat treatment.

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