• Title/Summary/Keyword: polymerization of cross section

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Analysis of the Ease in Basic Bodice Pattern Using 3-D Measuring Instrument (3차원 계측장치를 이용한 길 원형의 여유량 분석)

  • Shim, Kue-Nam;Suh, Jung-Kwon;Lee, Won-Ja
    • Fashion & Textile Research Journal
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    • v.2 no.3
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    • pp.239-245
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    • 2000
  • The purpose of this study was for analysis of ease about basic bodice pattern, as the first step of the research process for the drawing method of basic bodice for women in their twenties. The five selected basic bodice were made and they were worn by FRP body The garment space of each bodice was measured by analysis of the garment space of each section in figure of polymerization of cross section by a 3-D measuring instrument. The research suggests that this compared analysis is an objective reference. This analysis not only of the area of cross section of garment space and ease but also of the girth of the body shape and wearing shape, using the PAD system and 3-D measuring instrument, can be helpful in making garment patterns.

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Effects of the Content of Hydrophilic Crosslinking agents in Acrylate Copolymers on Physical Properties of Lens (아크릴계 공중합체에서 친수성가교제 특성에 따른 렌즈의 물리적 성질 변화)

  • Kim, Ki Sang;Shim, Sang-Yeon
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.305-311
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    • 2019
  • The acrylic copolymer was designed and prepared for soft lens with high content. The copolymers were prepared using 2-hydroxyethyl methacrylate(HEMA) as a monomer and ethylene glycol dimethacrylate(EGDMA), glycerol dimethacrylate(GD), or glycerol 1,3-diglycerolate diacrylate (GDD) as a cross linking agent. The water content for high water content lens was 46%, which was higher compared to general purpose of 36%. The contact angle decreased from 38.6 to 34.4, which appears hydrophilic surface. The tensile strength decreased from 0.1 Mpato 0.08, then again to 0.05 as hydrophilic properties of cross linking agents increased. No phase separation was observed in the cross section of lens using scanning electron microscope. The real-time infrared technique was used in photo-polymerization. The initial polymerization rate increased from 0.6 to 0.9, depending on crosslinking agent.

Graft Polymerization of Methacrylic acid onto PET Film (PET필름에 Methacrylic 산의 그라프트 중합)

  • Chung Hae Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.10 no.2
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    • pp.79-84
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    • 1986
  • Methacrylic acid was graft polymerized with benzoyl peroxide in itiator onto the commercial PET film. Graft polymerization was carried out in emulsion, which consisted of BPO (1), chlorobenzene(8) as swelling agent, tween 80(1) and sodium lauryl sulfate(1) as emulsifier and water(1,000). Original PET film has poor reactivities and, so the film preswdled with benzyl alcohol($150^{\circ}C$, 1hr) was also examined. The graft yield of PET film was increased with reaction temperature and monomer concentration. The graft yield of preswelled PET film was higher than that of no-treated PET film. Moisture regain was linearly increased with graft yield. DSC thermodiagram showed the Tm of grafted PET film was same as that of original PET film. Grafted PET film was dyed with methylene blue solution. The photograph of the cross section showed that grafting was occured not at the center but near surfaces.

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EFFECT OF FIBER DIRECTION ON THE POLYMERIZATION SHRINKAGE OF FIBER-REINFORCED COMPOSITES (섬유 보강 복합레진의 섬유 방향이 중합수축에 미치는 영향)

  • Yom, Joong-Won;Lee, In-Bog
    • Restorative Dentistry and Endodontics
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    • v.34 no.4
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    • pp.364-370
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    • 2009
  • The aim of this study was to evaluate the effect of fiber direction on the polymerization shrinkage of fiber-reinforced composite. The disc-shaped flowable composite specimens (d = 10 mm, h = 2 mm, Aeliteflo A2, Bisco, Inc., IL, USA) with or without glass fiber bundle (X-80821P Glass Fiber, Bisco, Inc., IL, USA) inside were prepared, and the longitudinal and transversal polymerization shrinkage of the specimens on radial plane were measured with strain gages (Linear S-series 350${\Omega}$, CAS, Seoul, Korea). In order to measure the free polymerization shrinkage of the flowable composite itself, the disc-shaped specimens (d = 7 mm, h = 1 mm) without fiber were prepared, and the axial shrinkage was measured with an LVDT (linear variable differential transformer) displacement sensor. The cross-section of the polymerized specimens was observed with a scanning electron microscope to examine the arrangement of the fiber bundle in composite. The mean polymerization shrinkage value of each specimen group was analyzed with ANOVA and Scheffe post-hoc test (${\alpha}$=0.05). The radial polymerization shrinkage of fiber-reinforced composite was decreased in the longitudinal direction of fiber, but increased in the transversal direction of fiber (p<0.05). We can conclude that the polymerization shrinkage of fiber-reinforced composite splint or restoratives is dependent on the direction of fiber.

A Study on Dyeability of Polyester Fabrics Grafted with Methacrylic Acid (MA 그라프트 폴리에스테르직물의 염색성에 관한 연구)

  • Baik, Chun-Eui;Cho, Seung-Sik;Song, Hwa-Sun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.6
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    • pp.946-954
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    • 1995
  • The purpose of this study is to modify the hydrophobic property and dyeability of polyethylene terephthalate fiber. Methacrylic acid (2nA) was graftpolymerized with benzoyl peroxide (BPO) as initiator onto polyethylene terephthalate fabrics. The results were as follow; 1. Graft-polymerization exhibited maximum graft ratio at a temperature of 100"C. 2. The polymer was gradually grafted in great amount to the surface of MA-g-PET as graft ration increase; with the cross-section examination of MA-g-PET, it was discovered that graft-polymeriation had also taken place inside the textile core. 3. Dyes absorption of basic dyes and disperse dyes was improved as craft ratio increase; with resistance to laundering, the former showed grade 3-4 and the latter showed grade 5.de 5.

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Fine Structure of the Ampullate ilk Glands in the Wolf Spider, Pardosa astrigera (Araneae: Lycosidae)

  • Myung-Jin Moon
    • Animal cells and systems
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    • v.2 no.4
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    • pp.513-520
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    • 1998
  • Though the wandering spiders do not produce webs for prey-catching, they have silk producing apparatus. Among the four kinds of silk glands in the wolf spider, Pardosa astrigera, the ampullate one is the most predominant gland in both sexes, and is composed of three functional parts; excretory duct, storage ampulla and convoluted tail regions. The duct is basically composed of three superposed types of layers which are inner cuticles, monolayered epithelial cells and peripheral connective cells. The electron lucent subcuticles which have the functions of water removal and orientation of silk fibers during polymerization are well developed at the anterior region near the spinneret. Whereas the endocuticles which contain two types of banding patterns at the cross section are developed at the rest of the duct region. The secretory silks are synthesized within the glandular epithelial cells of the tail as secretory granules, and then released to the inner cavity of the storage ampulla by the mechanism of apocrine secretion. Most of these secretory vesicles are originated from the rough endoplasmic reticula of the glandular epithelial cells, whereas no Golgi complexes are found in any of the cells which have been examined.

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Effect of propyl gallate on the properties of regenerated cellulose fiber spun from NMMO dope system (Propyl gallate가 NMMO계에서 제조된 셀룰로오스 섬유의 물성에 미치는 영향)

  • Lee, Soo;Lee, Sang-Won;Lee, Hyang-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.508-514
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    • 2010
  • Regenerated cellulose fibers were prepared from three pulps containing different degree of polymerization(DP) and $\alpha$-cellulose contents by dry-jet wet spinning technique with cellulose dope in N-methylmorpholin N-oxide (NMMO). The effect of antioxidant, n-propyl gallate (PG) on the properties of different regenerated celluloses was studied using X-ray diffraction, copper number calculation, and viscometry. The degradaqtion of regenerated cellulose from pulp containing higher DP and lower $\alpha$-cellulose content was occurred more seriously. The tensile strength and initial modulus of regenerated cellulose fiber obtained from NMMO dope with PG were higher than those of fiber obtained from NMMO dope without PG. All fibers showed the round shape cross section and typical cellulose II crystalline structure.

A Study on a Pattern Design for Pleated Skirts Based on the Amount of Waist Darts by Somatotype (체형별 허리 다트량을 활용한 플리츠 스커트 원형 설계에 관한 연구)

  • Lee, Jung-Hwa;Maruta, Naomi;Hirokawa, Taeko
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.8
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    • pp.933-945
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    • 2011
  • This research proposes a pattern design method for 24 pleated skirts in order to develop an automatic draft program for pleated skirts that will enhance fit and enable mass production. The research method and results are outlined as follow. 1. Three-dimensional body measurements were conducted on 30 randomly selected women in their 20s. By using 34 body measurement items and 6 types of calculations among the items, the items required in the designing of an original pleated skirt were extracted. They were then interpreted through correlation analysis, variance analysis, a t-test, linear regression analysis and multiple regression analysis. 2. An extra amount was added to the waist measurement and external capsule measurement according to the number of times the pleats coincided and the thickness of the fabric by the degree of polymerization of the horizontal cross section (the test of this research: 0.518mm). The extra amount of waist measurement was 3.6cm while the hip measurement was 4.3cm larger than the hip measurement combined with the external capsule measurement and the extra amount. 3. Based on the ${\pm}$standard deviation/2 as the average of the difference between the external capsule measurement and waist measurement, the subjects were classified into 3 somatotypes. Somatotype 1 presented an average total length of waist darts of 23.6cm while that of somatotype 2 was 26.2cm and that of somatotype 3 was 30.2cm. It has been confirmed that there is a significant difference among somatotypes in the total length of waist darts from the front center to the front side and the total length of waist darts from the side to the back center in terms of the average amount of waist darts for every 12 parts on the WL.

The Effects of Coupling Agent and Crosslinking Agent in the Synthesis of Acrylic Pressure Sensitive Adhesive for Polarizer Film (편광필름용 아크릴 점착제의 합성에서 커플링제와 가교제의 효과)

  • Lim, Chang-Hyuk;Ryu, Hoon;Cho, Ur-Ryong
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.319-325
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    • 2009
  • The solution polymerization was conducted to synthesize pressure sensitive adhesive for polarizer film using acrylic monomers. 2-Ethylhexylacrylate, butylacrylate, acrylic acid were used as acrylic monomers. The ratio was 2-ethylliexylacrylate:butylacrylate:acrylic acid=25:50:3.6 by reflecting $-40^{\circ}C$ of glass transition temperature in the pressure sensitive adhesive. When 1 wt% of coupling agent was added to the polymerized pressure sensitive adhesive, the light transmissivity was significantly increased. This result is due to the enhancement of adhesive power against liquid crystal cell by Si-O bond of coupling agents. Cross-linking agent was added by 0.5, 1.0, and 1.5 wt% with respect to the synthesized polymer. Initial tackiness decreased, while cohesion increased with increasing crosslinking agent. In the analysis of contact angle, the increase of crosslinking agents yielded the enhancement of surface energy, resulting in the decrease of contact angle. From the measurement of heat resistance, the acrylic pressure sensitive adhesive showed excellent heat resistance regardless of change in temperature and contents in crosslinking agent. In the observation of a cutting plane, the increased crosslinking agent represented a smoother and cleaner section. Comprehensively, the optimum additive amount of crosslinking agent was determined to be 1.0 wt% to monomer.