• Journal of Integrative Natural Science
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• v.2 no.2
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• pp.69-72
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• 2009

Pentiptycenediacetylene is very useful precursor materials for the synthesis of conducting polymer materials. The incorporation of rigid three-dimensional pentiptycene moieties into conjugated polymer backbones would offer several design advantages. They prevent ${\pi}$-stacking of the polymer backbones and thereby maintain high fluorescence quantum yields and spectroscopic stability in thin films. The pentiptycenediactylene was synthesized and characterized by 1H- and 13C-NMR spectroscopy.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.54.2-54
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• 1998

• Proceedings of the Korean Society of Rheology Conference
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• 2002.11a
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• pp.167-170
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• 2002

No Abstract, See Full Text

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.199-202
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• 2002

The synthesis of materials with controlled composition and architectures continues to be a focus of considerable current research. Dendritic multiarm polymers such as dendrimer, hyperbranched polymer, and star polymers are three dimensional macromolecules, in which a large number of linear arms of similar molecular weight and narrow molecular weight distribution emanate from a central core. (omitted)

• Macromolecular Research
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• v.13 no.6
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• pp.545-548
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• 2005

• Proceedings of the Korean Magnestics Society Conference
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• 2008.12a
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• pp.124.2-124.2
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• 2008

• Proceedings of the Korean Fiber Society Conference
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• 1994.04a
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• pp.39-39
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• 1994

• Proceedings of the Korean Fiber Society Conference
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• 1997.10a
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• pp.27-31
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• 1997

• Bulletin of the Korean Chemical Society
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• v.34 no.7
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• pp.2016-2022
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• 2013

Ionically modified ${\beta}$-cyclodextrins, which have excellent water-solubility, have been interested in purification technology as well as drug carrier system. The present study summarizes the synthesis and characterization of cationic and anionic ${\beta}$-cyclodextrin (${\beta}$-CyD) products using by polycondensation. The oligo (${\beta}$-CyD)s are synthesized from ${\beta}$-CyD, epichlorohydrin (EP) and choline chloride (CC; for cationic polymer) or chloroacetic acid (CAA; for anionic polymer) through one step polycondenstaion process. Unlike the previous studies, we successfully purified the ionic ${\beta}$-CyD condensation products from the ${\beta}$-CyD reaction mixtures and accomplished a great level of structural analysis. The detailed structural analysis of these ionic ${\beta}$-CyD compounds is done by $^1H$ NMR, MALDI-TOF as well as GPC analysis and confirms the formation of oligomers with a few units of ${\beta}$-CyD. We found that the sequence of reactant addition also could effect on the molecular weight of the resulting product as well as the molar ratio of the reactants. Finally, we used the cationic and anionic ${\beta}$-CyD oligomers for fabricating multilayer films by layer-layer process.

• Bulletin of the Korean Chemical Society
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• v.25 no.9
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• pp.1299-1300
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• 2004