• Title/Summary/Keyword: polymer network

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3-D Underwater Object Restoration Using Ultrasonic Transducer Fabricated with 1-3 Type Piezoceramic/Polymer Composite and Neural Networks (1-3형 복합압전체로 제작한 초음파 트랜스듀서와 신경회로망을 이용한 3차원 수중 물체복원)

  • Jo, Hyeon-Cheol;Lee, Gi-Seong;Choe, Heon-Il;Sa, Gong-Geon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.6
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    • pp.456-461
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    • 1999
  • In this study, the characteristics of Ultrasonic Transducer fabricated with PZT-Polymer 1-3 type piezoelectric ceramic/polymer composite are investigated. 3-D underwater object restoration using the self-made ultrasonic transducer and modified SCL(Simple Competitive Learning) neural network was presented. The ultrasonic transducer was satisfied with the required condition of commerical ultrasonic transducer in underwater. The modified SCL neural network using the acquired object data $16\times16$ low resolution image was used for object restoration of $32\times32$ high resolution image. The experimental results have shown that the ultrasonic transducer fabricated with PZT-Polymer 1-3 type piezoelectric ceramic/polymer composite could be applied for SONAR system.

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Study on lowering the percolation threshold of carbon nanotube-filled conductive polypropylene composites

  • Park, Seung Bin;Lee, Moo Sung;Park, Min
    • Carbon letters
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    • v.15 no.2
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    • pp.117-124
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    • 2014
  • Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive-filler percolation-threshold as much as possible. In this study, we investigated the effect of polymer/conductive-filler interactions, as well as the processing and morphological development of low-percolation-threshold (${\Phi}c$) conductive-polymer composites. The aim of the study was to produce conductive composites containing less multi-walled CNTs (MWCNTs) than required for pure polypropylene (PP) through two approaches: one using various mixing methods and the other using immiscible polymer blends. Variants of the conductive PP composite filled with MWCNT was prepared by dry mixing, melt mixing, mechanofusion, and compression molding. The percolation threshold (${\Phi}c$) of the MWCNT-PP composites was most successfully lowered using the mechanofusion process than with any other mixing method (2-5 wt%). The mechanofusion process was found to enhance formation of a percolation network structure, and to ensure a more uniform state of dispersion in the CPCs. The immiscible-polymer blends were prepared by melt mixing (internal mixer) poly(vinylidene fluoride) (PVDF, PP/PVDF, volume ratio 1:1) filled with MWCNT.

Processing of Porous Ceramics with a Cellular Structure Using Polymer Beads

  • Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1159-1164
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    • 2003
  • Two processing routes (i.e., the gel casting and polymer preform routes) using polymer beads were studied to fabricate porous ceramics with a cellular structure. The gel casting route, comprising the gel casting of a ceramic slurry mixed with polymer beads, was found to be inadequate to produce porous ceramic bodies with a interconnected pore structure, due to complete coating of the slurry on the polymer beads, which left just isolated pores in the final sintered bodies. The polymer preform route, involving the infiltration of a polymer beads preform with the ceramic slurry, successfully produced porous ceramics with a highly interconnected network of spherical pores. The pore size of 250-300 $\mu\textrm{m}$ was demonstrated and the porosity ranged from 82 to 86%. This process is advantageous to control the pore size because it is determined by the sizes of polymer beads used. Another feature is the avoidance of hollow skeleton, giving a high strength.

A Study on Curing Behaviors and Structures of Chiral Liquid Crystal-Polymer composite films (키랄네마틱액정-고분자 복합막의 경화거동과 내부구조에 관한 연구)

  • 남수용;김종원;김용욱
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.15-27
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    • 1998
  • Several aspects of polymer dispersed liquid crystal(PDLC) film properties make them interesting for display application. Most versions of PDLC materials are able to modulate light without the use of polarizers, which offers advantages in optical throughput(brightness) and viewing angle compared to polarizer-based display. In this papers, we attemped to doe minimum of remaining liquid crystals at polymer network for the liquid crystal-polymer composite (LCPC) films. In results, best phase separation behaviors turned out liquid crystal/monomer/oligomer mixture system.

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Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.232-235
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    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

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Fast Switching of a Polymer-networked Twisted Nematic Liquid Crystal Cell (폴리머 네트워크가 형성된 TN 액정셀의 고속응답 특성)

  • Jin, Hye-Jung;Kim, Ki-Han;Baek, Jong-In;Kim, Jae-Chang;Yoon, Tae-Hoon
    • Korean Journal of Optics and Photonics
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    • v.21 no.2
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    • pp.69-73
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    • 2010
  • We propose a method to enhance the response time of a twisted nematic liquid crystal (TN-LC) cell using an anisotropic polymer. Polymer networks are formed by the phase separation between a LC and a UV-curable polymer. A TN-LC cell is exposed to UV light after the mixture of LC and anisotropic polymer is injected into the TN-LC cell. As a result, turn-off time of a TN-LC cell can be decreased remarkably without any loss of the transmittance. The turn-off time of a TN-LC cell with pure LC was 16 ms, but those of polymer networked TN-LC cells were 12, 11, and 9 ms when the concentration of the polymer was 3, 5, and 10 wt%, respectively. Moreover, by virtue of the polymer network, the backflow effect and the delay time generated during the turn-off process disappeared.

Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.187-187
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    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

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The Influence of acid rein upon Tracking resistance of Epoxy Composite Materials (에폭시 복합재료의 내트래킹성에 미치는 산성비의 영향)

  • Son, In-Hwan;Kim, Tag-Yong;Choi, Seong-Min;Kim, Kyung-Hwan;Kim, Jae-Hwan
    • Proceedings of the KIEE Conference
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    • 1997.07e
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    • pp.1813-1815
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    • 1997
  • In this study, in order to develop outdoor insulating materials, SIN(simultaneous interpenetrating polymer network) was introduced to Epoxy resin and the environment resistance was investigated. Six kinds of specimen were manufacture by filler($SiO_2$) content. SEM was untilized in order to confirm their network structure changes. Also, tracking test, UV test and acid rain test were carried out investigate the environment resistance characteristic. Therefore it was confirmed that simultaneous interpenetrating polymer network specimens were more excellent than single network structure specimens. But, acid rain almost never changed resistance.

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Synthesis of Novel Network Polyesters Containing Malonate Group in Main Chain and Their Fluorescence Image Patterning via Photodegradation (주사슬에 말로네이트기를 가지는 신규 폴리에스테르의 합성과 광분해 특성을 이용한 형광 이미지 패터닝)

  • Jeong, Seon-Ju;Kwak, Gi-Seop;Jung, In-Tae;Lee, Dong-Ho;Roh, Hyung-Jin;Yoon, Keun-Byoung
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.56-62
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    • 2008
  • Three types of network polyesters have been newly synthesized by a two-step condensation reaction by the various combination of several diols and diacids. When these polymer films were thermally treated at $240^{\circ}C$, they exhibited absorptions in a visible range despite the forbidden transition of carbonyl group. When excited at wavelengths above 330 nm, the polymers showed fluorescences in a wide visible range from blue to near yellow. These fluorescence phenomena are due to the formation of certain conjugated structures by the Knoevenagel type self-condensation under the high-temperature thermal treatment. These polymers showed significant difference in the thermal properties as a function of the degrees of chemical crosslinking. They also underwent photodegradation. Highly resolved, fluorescent image patterns were successfully obtained by the photodegradation of malonate group under a strong UV-light irradiation.

Poly(L-lysine) Based Semi-interpenetrating Polymer Network as pH-responsive Hydrogel for Controlled Release of a Model Protein Drug Streptokinase

  • Park, Yoon-Jeong;Jin Chang;Chen, Pen-Chung;Victor Chi-Min Yang
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.5
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    • pp.326-331
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    • 2001
  • With the aim of developing of pH-sensitive controlled drug release system, a poly(Llysine) (PLL) based cationic semi-interpenetrating polymer network (semi-IPN) has been synthesized. This cationic hydrogel was designed to swell at lower pH and de-swell at higher pH and therefore be applicable for achieving regulated drug release at a specific pH range. In addition to the pH sensitivity, this hydrogel was anticipated to interact with an ionic drug, providing another means to regulate the release rate of ionic drugs. This semi-IPN hydrogel was prepared using a free-radical polymerization method and by crosslinking of the polyethylene glycol (PEG)-methacrylate polymer through the PLL network. The two polymers were penetrated with each other via interpolymer complexation to yield the semi-IPN structures. The PLL hydrogel thus prepared showed dynamic swelling/de-swelling behavior in response to pH change, and such a behavior was influenced by both the concentrations of PLL and PEG-methacrylate. Drug release from this semi-IPN hydrogel was also investigated using a model protein drug, streptokinase. Streptokinase release was found to be dependent on its ionic interaction with the PLL backbones as well as on the swelling of the semi-IPN hydrogel. These results suggest that a PLL semi-IPN hydrogel could potentially be used as a drug delivery platform to modulate drug release by pH-sensitivity and ionic interaction.

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