• Title/Summary/Keyword: polymer network

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Permeation of Solutes Through Interpenetrating Polymer Network Hydrogels Composed of Poly(vinyl alcohol) and Poly(acrylic acid)

  • Shin, Heung-Soo;Kim, So-Yeon;Lee, Young-Moo
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.05
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    • pp.7-10
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    • 1997
  • Poly(acrylic acid) 와 poly(vinyl alcohol) 을 이용하여 온도와 pH 에 감응성을 가지는 상호침투 가교 고분자 히드로겔을 합성하고 약물의 투과도를 측정하였다. 이 히드로겔은 고분자 구조 내에 이온기를 포함하고 있으므로 팽윤 시에 외부의 pH 와 이온 세기의 영향을 크게 받았으며 이온기와 용액과의 상호작용이 증가할수록 팽윤도가 감소하였다. 히드로겔을 이용한 약물의 투과실험에서 비이온성 약물의 경우 약물 입자의 크기에 따른 분리가 가능하였으며 이온성 약물의 경우 고분자 히드로겔의 구조차 외부 pH, 약물의 구조에 따른 상호작용에 의하여 투과가 이루어짐을 알 수 있었다.

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Impulse Dielectric Breakdown Characteristics due to Network Structure Variation of Epoxy Composites (Epoxy 복합재료의 망목구조 변화에 따른 임펄스 절연파괴 특성)

  • 이덕진;김경환;김명호;손인환;김탁용;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.164-167
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    • 1997
  • A series of interpenetrating polymer networks(IPN) based on Epoxy, MA and PU were synthesized in order to improve withstand voltage properties of Epoxy resin. Dielectric breakdown characteristics are investigated for six types of specimens. As a result, it was found that impulse voltage dielectric breakdown characteristic of SIN specimen was the most excellent. It was also found that SIN specimens were stronger than anything else in scanning electron microscopy. On the other hand, as a result of consideration of dielectric breakdown strength change according to adding fi1ter, it was confirmed that the decrease of dielectric breakdown strength are controlled slightly by IPN method.

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Analysis of Branched PEG-Conjugated Interferon Alpha by Capillary Electrophoresis and MALDI- TOF Mass Spectrometry

  • Na, Dong-Hee;Park, Eun-Ji;Lee, Snag-Deuk;Jo, Young-Woo;Lee, Sung-Hee;Kim, Won-Bae;Lee, Kang-Choon
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.406.3-407
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    • 2002
  • Analysis of interferon alpha (IFN) modified with high molecular weight branched PEG was performed by capillary electrophoresis (CE) and MALDI-TOF mass spectrometry (MALDI-TOF MS). IFN was modified by the reaction of amine residues with an active ester of monomethoxy polyethylene glycol at various molar ratios. As a CE method. capilary electrophoresis sodium dodecyl sulfate nongel sieving (CE-SDS NGS) was performed using an uncoated capilary filled with a hydrophilic replaceable polymer network matrix. (omitted)

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Process Optimization of Composite-based Capacitor for LC Resonant Circuits

  • Mun, Sei-Young;Cha, Cheol-Ung;Choi, Jong-Chan;Lim, Seung-Ok;Hong, Sang-Jeen
    • Journal of the Speleological Society of Korea
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    • no.80
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    • pp.21-24
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    • 2007
  • The need for high-frequency decoupling capacitors to supply the transient current requirements to high-speed devices is ubiquitous in current microelectronics applications. Even though materials and their processes have already been developed in terms of their performances, low manufacturing cost cannot be overemphasized in current microelectronics industry. For this reason, we revisited low cost ceramic filled polymer integrated capacitor. Experiments were performed according to the design of experiment (DOE). The best recipe that has the optimized ratio of material composite was obtained using by response optimizer in Minitab. And also, high-frequency measurements were performed to get frequency dependent data using network analyzer.

A Study on the Enhancement of Oxygen Permeability by Silicone in Polymeric Membranes (고분자분리막의 실리콘에 의한 산소투과향상에 관한 연구)

  • 변홍식
    • Membrane Journal
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    • v.9 no.3
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    • pp.151-156
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    • 1999
  • Silicone was used in this study to enhance the oxygene permeability of gas separation membranes. PMP and PMMA were used to prepare the copolymers and IPN membranes, respectively. In the case of copolymers, there were two methodsCswelling and solvent evaporation) in this study and it was revealed that this preparation method affected the oxygene permeability. It was also shown that the IPN method brought the enhacement of oxygen permeability and slight decrease of separation factor. Regarding oxygen permeability 10 wt% of PMMA was the best composition of IPN membrane.

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전략케이블에 쓰이는 절연재료의 변천과 발달과정

  • 구자윤
    • 전기의세계
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    • v.34 no.8
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    • pp.476-488
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    • 1985
  • 전기공학분야의 여러다른 부분과 같이 전력케이블 분야에서도 수많은 연구와 아울러 특히 19세기후반에 전력케이블의 제작에 성공한 것은 20세기에 들어와서 케이블과 이에 관련된 모든 기술이 빠른 속도로 발달하게된 주원동력이 되었다고 보아도 과언은 아니다. 비록 19세기 후반에 고무(rubber)를 사용하여 케이블 절연 하였지만, 그이후 약 70여년이상을 Impergnated paper(오일복합수지(oil compound resin)나 오일(oil)을 종이에 스며들게한 후 그 종이를 절연재료로 이용함)를 전력케이블 절연재료로 많이 사용하여 왔다. 아울러 OF cable의 제조기술도 향상되어 현재 매우 높은 전압과 상당한 전력용량를 충족시키는 전력케이블로서 발달을 계속하고 있다. 1960년대에 들어서서 extruded polymer material 이 전력케이블의 절연재료로 쓰이게 되었는데 현저하게 주로 쓰이는 재료로 폴리에틸렌인대, 그대로 순수한 상태로 또는 어떤 처리를 하여 쓰기도 한다. 그러나 EPR(ethylene propylene rubber)도 역시 개발중에 있다. Extruded synthetic insulation을 사용한 케이블은 현재 모든 필요한 전류와 전압을 망라하여 널리 쓰이고 있으며 다른재료를 사용한 케이블 보다 설치하기에 쉽고 사용법이 비교적 간단하고, 또한 전력망(network)에서의 신뢰서이도 높은 것으로 나타나 매우 만족스런 재료로 인정받고 있다.

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The Effect of Discoloration on the Electrical Properties of Alumina Filled Epoxy (Alumina Filler가 충진된 에폭시 경화물(硬化物)의 변색(變色)이 전기적(電氣的) 특성(特性)에 미치는 영향(影響))

  • Hahn, K.M.;Kim, D.W.;Oh, M.W.;Kweon, H.S.;Kim, Y.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.59-62
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    • 1993
  • This Paper studies on thermal oxidation of alumina filled epoxy network polymer used in Extra-High voltage application. The thermal oxidation of surface has investigated by yellow index variation and various electrical properties which are surface resistivity, tracking resistance and AC dielectric strength are estimated by yellow index.

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Replication of Polyethylene Nano-Microstructures Using Ultrasonic Forming (초음파성형을 이용한 폴리에틸렌 나노 마이크로 구조물의 복제)

  • Lee, Chi-Hoon;Yu, Hyun-Woo;Shin, Bo-Sung;Ko, Jong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.11
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    • pp.1209-1216
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    • 2009
  • Nano-micro hierarchical structures that nanoprotrusions were formed on the network-type microstructures were fabricated using an ultrasonic vibration forming technology. A commercial ultrasonic welding system was used to apply ultrasonic vibration energy. To evaluate the formability of ultrasonic vibration forming, nickel nano-micro hierarchical mold was fabricated and polyethylene (PE) was used as the replication material. The optimal molding time was 3.5 sec for PE nano-micro hierarchical structures. The molding process was conducted at atmospheric pressure.

For Implementation of Real Time Optical Network Optimization and Application of Vertical Asymmetric Polymer-Optical Coupler (실시간 광전송망 구현을 위한 수직형 비대칭 폴리머 광 결합기의 최적화 및 응용)

  • 이소영;권재영;이종훈;김영조;신미경;김상호;송재원
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.140-141
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    • 2000
  • 집적광학 회로의 구성요소 중 광 결합기는 파장에 따른 채널간 결합기로써 WDM은 물론 광 스위칭 소자로서 매우 중요한 위치에 있다. 더우기 수직형의 구조를 갖는 광결합기가 새로이 제안되면서 결합 길이를 줄여 전체 소자길이를 감소시킴으로써 고집적화는 물론, 도파로를 진행하는 동안 겪게되는 도파 손실을 최소화하려는 움직임 또한 활발하다. 그러나 이들 수직형 광결합기는 결합효율을 높이기 위하여 대부분 상 하부 도파로의 구조가 동일한 대칭형으로 제작됨에 따라, 이들은 매우 까다롭고 복잡한 공정을 갖게된다. 또한 이러한 공정의 복잡성과 두 도파로의 대칭성을 위한 반복작업은 오히려 제작공정의 불완전함으로 인하여 이론상의 이상적 결합에 비하여 효율이나 성능 면에서 상당한 저하를 가져오게 된다. 최근 연구되고있는 대부분의 폴리머를 이용한 광 결합기 역시 대칭형 구조를 가지며 $O_2$ RIE(Reactive ion etching) 건식 식각법으로 제작된다.$^{[1]}$ (중략)

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Simulation of the Corona Charging Process in Polypropylene Electret for Sensor Material

  • Park, Geon-Ho;Park, Young-Chull;Yang, Jung-Yoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.10a
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    • pp.68-72
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    • 2000
  • In order to estimate spatial charging process in the corona charging which has been used to make polymer electret, the electrical properties of polypropylene film were obtained from Thermally Stimulated Current (TSC) measurements after corona charging between knife electrode and cylinder electrode with the voltages of -5, -6, -7 and -8[kV], respectively. And then the electrostatic contour and the electric field vector were also simulated by using Finite Element Method (FEM). The edge effect around edge of knife electrode affected the electrostatic contour on surface of specimen and the electric field concentration inside specimen. The uneven charging state in the electret due to the mistake on design could be calculated and so the optimal design of corona charging device which is appropriate to various materials is come to be practicable.

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