• Journal of the Korea Institute of Building Construction
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• v.15 no.5
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• pp.483-489
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• 2015

The Purpose of this study was to establish the basic data on the mechanical properties of PCM in the high temperature range. To this end, an experiment was conducted on the characteristics of the residual compressive strength by temperature (100, 200, 400 and $600^{\circ}C$) with a fixed temperature heating. An after heating test was performed to investigate the properties after fire damage. The result showed that the residual compressive strength of PCM had a tendency to decrease, regardless of the type of polymer. It was also found that when the contents were low, the residual compressive strength started to greatly decrease from the high temperature range of $400^{\circ}C$, and that the specimen containing PAE showed a steeper slope than the specimen containing EVA. However, since little studies have been conducted on the mechanical properties of PCM with the high temperature, it is considered that, in addition to this study, basic studies must be preceded, including studies on the repairing methods.

• Polymer(Korea)
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• v.35 no.4
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• pp.363-369
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• 2011

To study the effect of incorporation of a surface crosslinking layer on a crosslinked poly (sodium acrylate) (cPSA) absorbent with ethylene glycol dimethacrylate CEGDMA), we synthesized several surface crosslinked cPSAs with EGDMA by an inverse emulsion polymerization method to delay the absorption of excess water in concrete, Liquid paraffin was used as a continuous phase. cPSA was synthesized with acrylic acid (AA) neutralized with aqueous 8 M sodium hydroxide solution as a monomer, N,N-methylene bisacrylamide (MBA) as crosslinking agent and ammonium persulfate (APS) and sodium metabisulfite (SMBS) as a redox initiator system by inverse emulsion polymerization. FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with cPSA and cPSA-EGDMAs. The swelling ratios of synthesized absorbents were evaluated from the absorption in deionized water, cement saturated aqueous solution and aqueous solution of calcium hydroxide (pH 12). Equilibrium swelling times for cPSA and surface crosslinked cPSA with EGDMA were 2 and 3 hrs, respectively. We also observed an increase in setting time of the cement and an increase in the compressive strength of mortar by addition of the synthesized cPSA-EGDMA.