• Title/Summary/Keyword: polymer material

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Formation of Bioactive Ceramic Foams by Polymer Pyrolysis and Self-Blowing (고분자 열분해와 자가발포를 이용한 생체활성 다공체의 제조)

  • Kwak, Dae-Hyun;Kim, Jin-Ho;Lee, Eun-Ju;Kim, Deug-Joong
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.412-417
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    • 2011
  • Formation and characterization of hydroxyapatite-based porous ceramics derived from polymer pyroysis were investigated. Polymer based process is chosen for preparing porous hydroxyapatite-based ceramics having a high mechanical strength. The hydroxyapatite-based porous ceramic was prepared by a self-blowing process of a polymethylsiloxane with filler and pyrolyzed at above $1000^{\circ}C$. Biphasic material consisted of hydroxyapatite and CaO has been prepared by solid state reaction from calcium hydroxide($Ca(OH)_2$) and calcium hydrogen phosphate dihydrate($CaHPO_4{\cdot}2H_2O$) as a filler material. The influence of filler content on mechanical properties was evaluated. The change of crystalline phase, microstructure and mechanical properties were investigated and discussed.

Study on compensation of thermal stresses in multilayered materials

  • Han, Jin-Woo;Kim, Jong-Yeon;Kim, Byoung-Yong;Han, Jeong-Min;Moon, Hyun-Chan;Park, Kwang-Bum;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.413-413
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    • 2007
  • In recent years, flexible display devices such as liquid crystal display (LCD), organic light emitting diode (OLED), etc. have attracted considerable interest in a wide variety of applications. Polymer substrate is absolutely necessary to realize this kind of flexible display devices. Using the polymer as a substrate, there are lots of advantages including not only mechanical flexibility such as rolling and bending characteristics but also light weights, low cost and so on. In detail, thickness and weights is only one forth and one second of glass substrate, respectively. However, it needs low temperature below $150^{\circ}C$ in the fabrication process comparing to conventional deposition process. The polymer substrate is not thermally stable as much as the glass substrate so that some deformation can be occurred according to variation of temperature. In particular, performance of devices can be easily deteriorated by shrinkage of substrate when heating it. In this paper, pre-annealing and deposition of buffer layer was introduced and studied to solve previously mentioned problems of the shrinkage and followed shear stress.

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Bending strength of GFRP for Insulator according to Winding Angle (전기절연물용 GFRP의 winding 각도에 따른 굽힘강도)

  • Park, Hoy-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Lee, Tae-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.429-432
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    • 2004
  • The demand for electric power keeps growing, and tends to be more effective. Polymer insulators have been manufactured for almost twenty years and the excellent insulation performance of polymer insulators is attractive. Polymeric materials are now widely used as a replacement for inorganic materials such as porcelain or glass for the outdoor insulation of high voltage insulation. GFRP has been used widely as a core materials for polymer insulators. This paper reports the mechanical properties of GFRP for insulators. The bending strength was simulated and evaluated according to the winding angle. The fiber orientation in GFRP has a great effect on the strength of GFRP because the strength of GFRP mainly depends on the strength of fiber. Results of simulated and evaluated strength of GFRP were compared each other. The simulated strength of GFRP rod was different from the evaluated strength. It was caused that the shear stress had a great effect on the strength of GFRP although the stress of parallel direction of GFRP was much higher.

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Examination of Tensile and Adhesion Performance According to Components and Application Environment of Cement-mixed Polymer-based Waterproofing (시멘트 혼입 폴리머계 방수재의 구성요소 및 적용환경에 따른 인장·부착성능 평가)

  • Lee, Jin-Yong;Choi, Jeong-Kyun;Kim, Seong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.41-49
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    • 2021
  • Cement-mixed polymer-based waterproofing materials are generally used in the form of application by mixing in the field, and it is necessary to supplement the construction ability for air bubbles and uneven coating thickness due to irregularities during construction. The final purpose of this study is to improve the waterproofing performance by adding a sheet attaching process to the composite construction rather than the single process of painting and applying the construction method when applying the polymer waterproofing material to the field. In this regard, the applicability was evaluated by examining the material, environment, and manufacturing method.

Relationship of the U-Factor and Chemical Structure with Applied Metal and Polymer Material Assembly in Curtain Wall Frame

  • Park, Tongso
    • Korean Journal of Materials Research
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    • v.31 no.8
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    • pp.450-457
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    • 2021
  • From measured thermal conductivity and modeling by simulation, this study suggests that U-factors are highly related to materials used between steel and polymer. The objective and prospective point of this study are to relate the relationship between the U-factor and the thermal conductivity of the materials used. For the characterization, EDX, SEM, a thermal conductive meter, and computer simulation utility are used to analyze the elemental, surface structural properties, and U-factor with a simulation of the used material between steel and polymer. This study set out to divide the curtain wall system that makes up the envelope into an aluminum frame section and entrance frame section and interpret their thermal performance with U-factors. Based on the U-factor thermal analysis results, the target curtain wall system is divided into fix and vent types. The glass is 24 mm double glazing (6 mm common glass +12 mm Argon +6 mm Low E). The same U-factor of 1.45 W/m2·K is applied. The interpretation results show that the U-factor and total U-value of the aluminum frame section are 1.449 and 2.343 W/m2·K, respectively. Meanwhile, those of the entrance frame section are 1.449 and 2.

Fabrication of Nitrogen Self-Doped Porous Carbons from Melamine Foam for Supercapacitors (슈퍼커패시터용 멜라민 폼으로부터 질소가 자가 도핑된 다공성 탄소 재료의 제조)

  • Lee, Byoung-Min;Chang, Hyeong-Seok;Choi, Jae-Hak;Hong, Sung-Kwon
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.264-271
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    • 2021
  • Porous carbons have been widely used as electrode material for supercapacitors. However, commercial porous carbons, such as activated carbons, have low electrochemical performance. Nitrogen-doping is one of the most promising strategies to improve electrochemical performance of porous carbons. In this study, nitrogen self-doped porous carbon (NPC) is prepared from melamine foam by carbonization to improve the supercapacitive performance. The prepared NPC is characterized in terms of the chemical structures and elements, morphology, pore structures, and electrochemical performance. The results of the N2 physisorption measurement, X-ray diffraction, and Raman analyses reveal that the prepared NPC has bimodal pore structures and pseudo-graphite structures with nitrogen functionality. The NPC-based electrode exhibits a gravimetric capacitance of 153 F g-1 at 1 A g-1, a rate capability of 73.2 % at 10 A g-1, and an outstanding cycling ability of 97.85 % after 10,000 cycles at 10 A g-1. Thus, the NPC prepared in this study can be applied as electrode material for high-performance supercapacitors.

A Study on the Additive Manufacturing Process using Copper Wire-Nylon Composite Filaments (구리 와이어-나일론 복합소재 필라멘트를 이용한 적층제조 공정에 관한 연구)

  • Kim, Ye Jin;Kim, Seok;Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.5
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    • pp.1-8
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    • 2022
  • Fused deposition modeling (FDM), based on stacking a continuous filament of polymer or composite materials, is well matured and is thus widely used in additive manufacturing technology. To advance FDM-based 3D printing technology, the mechanical properties of additively manufactured composite materials must be improved. In this study, we proposed a novel FDM 3D printing process using metal wire-polymer composites, enabling enhanced mechanical properties. In addition, we developed a new type FDM filament of copper wire wrapped in nylon material for stable 3D printing without thermal damage during the printing process. After FDM printing of the copper wire-nylon composite filament, we conducted a tensile test to investigate the mechanical behavior of the printed composite materials. The experimental results confirmed that the tensile strength of the 3D-printed metal wire-polymer composites was higher than that of the conventional single polymer material. Thus, we expect that the FDM printing process developed in this study may be promising for high-load-bearing applications.

Microstructure, Thermal Properties and Rheological Behavior of PLA/PCL Blends for Melt-blown Nonwovens (멜트블론 부직포 제조를 위한 PLA/PCL 블렌드의 미세구조, 열적특성, 및 유변학적 성질)

  • Sun, Hui;Yu, Bin;Han, Jan;Kong, Jinjin;Meng, Lingrui;Zhu, Feichao
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.477-483
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    • 2014
  • Poly(lactic acid) (PLA) and poly(${\varepsilon}$-caprolactone) (PCL) blends with various components for melt-blown non-wovens were prepared by a twin-screw extruder. Tributyl citrate (TBC) was added in order to improve the miscibility between PLA and PCL. The results showed that small circular particles of PCL were dispersed in PLA matrix uniformly. The addition of PCL had the heterogeneous nucleation effect on the crystallization of PLA and decreased thermal stability of PLA. The flow of pure PLA and blends approached to Newtonian liquid at a low shear rate and expressed more obvious viscoelasticity at a high shear rate.

Color and Fastness Properties of Nylon Transfer Digital Textile Printing(DTP) using Acrylic-based Polymer as Pre-treatment Agent (나일론 전사 DTP 원단 전처리에 따른 발색성 및 견뢰도 특성)

  • Kim, Hyeok-Jin;Hong, Jin-Pyo;Kwak, Dong-Sup;Seo, Hye-Ji;Kim, Hyun-Jo
    • Textile Coloration and Finishing
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    • v.31 no.2
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    • pp.88-97
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    • 2019
  • In this study, when printed on a nylon material, the color strength and fastness are lower than that of a polyester material, and the nylon material shrinks due to heat and pressure, resulting in poor design and poor compatibility. To overcome this problem, we investigated the possibility of transfer DTP by adding pre-treatment process to nylon transfer DTP process. For the basic study of pre-treatment preparation, we used pure nylon material which is not compounded and dispersion ink and transfer paper applied to existing PET transfer DTP. Pre-treatment preparations were classified into three types of acryl-base polymer and pre-treated with nylon and then applied to transfer DTP to confirm their color strength and fastness. The color strength of the pre-treated nylon material increased and poly-methyl-acrylate amulsion pre-treatment showed the best color at $210^{\circ}C$, 1.5m/min and 0.3MPa. The nylon material pre-treated with washing, friction, and light fastness was judged to be more excellent and stable.

Properties of Polymer-Modified Mortar with Styrene-Butyl Acrylate and Styrene Butadiene Rubber (S/BA와 SBR을 혼입한 폴리머 시멘트 모르타르의 특성)

  • Mun, Kyung-Ju;Song, Hae-Ryong;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.555-560
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    • 2008
  • Polymer-modified mortars have been largely used as paving materials, flooring, waterproofing material, adhesives, anticorrosive linings, deck coverings, and other various materials. The various types and properties of the mixed polymer largely affect the characteristics of polymer-modified mortar that has been mixed with polymer latexes. Consequently, its application purposes are varied according to these properties. This paper investigates the typical properties of polymer-modified mortars that contain styrene and butyl acrylate latexes and styrene butadiene rubber. They are then tested to obtain air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the superior flexural strength of polymer-modified mortars is obtained at a S/BA-2 and a polymer-cement ratio of 20%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the types of polymer. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete.