• Journal of the Korean Electrochemical Society
• /
• v.17 no.1
• /
• pp.37-43
• /
• 2014

In this study, capacitive deionization (CDI) was introduced for desalination of mining water. Ion-exchange polymer coated carbon electrodes (IEE) were used in CDI to desalt mining water. The CDI performance using the IEE for desalination of mining water was carried out and then was compared with that using general carbon electrodes without ion-exchange polymer coating (GE). Moreover, to investigate the effect of the concentration of influent solutions on CDI performance, the CDI performance using the IEE for desalination of brackish water (NaCl 200 ppm) was also performed and analyzed. As a result, the higher salt removal efficiency, rate and the lower energy consumption in the CDI process using the IEE and mining water were obtained compared with those using the GE and mining water. It is mainly due to higher non-Faradaic current, low ohmic resistance of the influent, overlapping effect of electric double layers in micropore of the electrode. In addition, the CDI process using the IEE and brackish water shows much higher salt removal efficiency and lower salt removal rate than that using the IEE and mining water. This results from the lower concentration (i.e., higher ohmic resistance) and salt amount of the influent.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.65-65
• /
• 2015

In this talk, I will introduce two topics. The first topic is the polymer light emitting diodes (PLEDs) using graphene oxide quantum dots as emissive center. More specifically, the energy transfer mechanism as well as the origin of white electroluminescence in the PLED were investigated. The second topic is the facile synthesis of eco-friendly III-V colloidal quantum dots and their application to light emitting diodes. Polymer (organic) light emitting diodes (PLEDs) using quantum dots (QDs) as emissive materials have received much attention as promising components for next-generation displays. Despite their outstanding properties, toxic and hazardous nature of QDs is a serious impediment to their use in future eco-friendly opto-electronic device applications. Owing to the desires to develop new types of nanomaterial without health and environmental effects but with strong opto-electrical properties similar to QDs, graphene quantum dots (GQDs) have attracted great interest as promising luminophores. However, the origin of electroluminescence (EL) from GQDs incorporated PLEDs is unclear. Herein, we synthesized graphene oxide quantum dots (GOQDs) using a modified hydrothermal deoxidization method and characterized the PLED performance using GOQDs blended poly(N-vinyl carbazole) (PVK) as emissive layer. Simple device structure was used to reveal the origin of EL by excluding the contribution of and contamination from other layers. The energy transfer and interaction between the PVK host and GOQDs guest were investigated using steady-state PL, time-correlated single photon counting (TCSPC) and density functional theory (DFT) calculations. Experiments revealed that white EL emission from the PLED originated from the hybridized GOQD-PVK complex emission with the contributions from the individual GOQDs and PVK emissions. (Sci Rep., 5, 11032, 2015). New III-V colloidal quantum dots (CQDs) were synthesized using the hot-injection method and the QD-light emitting diodes (QLEDs) using these CQDs as emissive layer were demonstrated for the first time. The band gaps of the III-V CQDs were varied by varying the metal fraction and by particle size control. The X-ray absorption fine structure (XAFS) results show that the crystal states of the III-V CQDs consist of multi-phase states; multi-peak photoluminescence (PL) resulted from these multi-phase states. Inverted structured QLED shows green EL emission and a maximum luminance of ~45 cd/m2. This result shows that III-V CQDs can be a good substitute for conventional cadmium-containing CQDs in various opto-electronic applications, e.g., eco-friendly displays. (Un-published results).

• Journal of the Korea Concrete Institute
• /
• v.16 no.4 s.82
• /
• pp.451-458
• /
• 2004

This study describes the basic concept and the applicability of Hybrid Reinforcement System using conventional steel reinforcing bars and Fiber Reinforced Polymer bars. The concrete bridge decks are assumed to be supported by beams and reinforced with two layers of reinforcing bars. In concrete bridge deck using HRS, the top tensile force for negative moment zone on beam supports is assumed to be resisted by FRP reinforcing bars, and the bottom tensile force for positive moment zone in the middle of hem supports is assumed to be resisted by conventional steel reinforcing bars, respectively. The FRP reinforcing bars are non-corrosive. Thus, the steel reinforcement is as far away as possible from the top surface of the deck and protected from intrusion of corrosive agent. HRS concrete bridge deck has sufficient ductility at ultimate state as the following reasons; 1) FRP bars have lower elastic modulus and higher ultimate strain than steel re-bars have, 2) FRP bars have lower ultimate strain if provided higher reinforcement ratio, 3) ultimate strain of FRP bars can be reduced if FRP bars are unbonded. Test results showed that FRP and HRS concrete slabs are not failed by FRP bar rupture, but failed by concrete compression in the range of ordinary reinforcement ratio. Therefore, in continuous concrete bridge deck using HRS, steel reinforcing bars for positive moment yield and form plastic hinge first and compressive concrete fail in the bottom of supports or in the top of the middle of supports last. Thus, bridge deck consumes significant inelastic strain energy before its failure.

• Journal of the Korea Concrete Institute
• /
• v.26 no.4
• /
• pp.421-428
• /
• 2014

This paper describes the experimental results of insulated concrete sandwich wall panels (CSWP) with corrugated glass fiber-reinforced polymer (GFRP) shear connectors under in-plane shear loading. Corrugated GFRP shear connectors were used to improve the thermal property of insulated CSWP and to achieve composite action between the interior and exterior concrete wall panels. Test specimens were consist of three concrete panels with two insulation layers between concrete panels and middle concrete panels was loaded in the direction of gravity. To evaluate the effects of insulation types (extruded polystyrene, XPSS and expanded polystyrene, EPS), shear connector pitch (300 and 400 mm) and width (10 and 15 mm) on in-plane shear behavior of insulted CSWP, failure mode and shear flow-average relative slip relationship of specimens were investigated. Test results indicate that the bond stress between concrete panel and insulation is considerable initially. Especially in case of insulated CSWP without shear connector, initial stiffness of CSWP with XPSS is superior to that of CSWP with EPS. The shear connector's contribution to in-plane shear performance of insulated CSWP depends on the type of insulation.

• Polymer(Korea)
• /
• v.33 no.5
• /
• pp.407-412
• /
• 2009

Vacuum deposited N,N-di-1-naphthyl-N,N-diphenyl-1,1'-biphenyl-4,4'-diamine (NPD) as a hole transporting (HTL) materials in OLEDs was placed on PEDOT-PSS, a hole injection layer (HIL). PEDOT-PSS was spin-coated on to the ITO glass. $C_{60}$-doped NPD-$C_{60}$(10 wt%) film was formed via co-evaporation process and the morphology of NPD-$C_{60}$ films was investigated using XRD and AFM. The J - V, L - V and current efficiency of multi -layered devices were characterized. According to XRD results, the deposited $C_{60}$ thin film was partially crystalline, but NPD-$C_{60}$ film was observed not to be crystalline, which indicates that $C_{60}$ molecules are uniformly dispersed in the NPD film. By using $C_{60}$-doped NPD-$C_{60}$ film as a HTL, the current density and luminance of multi-layered ITO/PEDOT-PSS/NPD-$C_{60}/Alq_3$/LiF/Al device were significantly increased by about 80% and its efficiency was improved by about 25% in this study.

• Applied Chemistry for Engineering
• /
• v.17 no.6
• /
• pp.604-608
• /
• 2006

Polymer composites for measuring the radioactive contamination are prepared by coating ZnS(Ag) powders as a scintillator on polysulfone base layer. The composites consist of the active layer for a scintillation reaction with radioactive wastes and the transparent support layer for transmittance of light photons emitted by scintillation in the active layer. The binding of the active layer, including ZnS(Ag), on the support layer is proceeded via coating with polysulfone as a binder, without any extra adhesive. The coating was obtained by either casting via a Doctor Blade as applicator or screen printing. The prepared composites feature a monolithic structure, resulting in the complete adhesion between two layers. The composite prepared by the casting technique using an applicator holds a good detection efficiency in measuring the alpha radionuclide, but its structure becomes fragile because of warping in morphology. On the contrary, the composite prepared by the screen printing shows a good detection capacity as well as a good stability in a mechanical shape.

• Polymer(Korea)
• /
• v.38 no.5
• /
• pp.640-644
• /
• 2014

As a process of plat panel display production, slot coating is widely used for the coating of photoresist on a wide glass substrate. A uniform coating thickness is important, and the coating uniformity is divided into nozzle and machine directions. The machine and nozzle directions coating uniformities are influenced by the operation condition of coater and flow uniformity inside the die, respectively. Non-uniform coating during steady coating process occurs according to those factors, however, non-uniform coating along the machine and nozzle directions has been observed at the beginning of coating by unsteady flow. In this study, steady and unsteady state flow simulations have been performed and compared with experiment to examine the causes of non-uniform coating. Computational results exhibited that it took a time to get a uniform pressure distribution at whole inside the die, and during this period of time edge regions showed lower exit velocity compared with center region. Subsequently edge regions had thinner coated layers than center region. However edge regions showed higher exit velocity than center region after steady state, and this made edge regions had thicker coated layer than center region.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.457-457
• /
• 2010

Flexible organic light emitting diodes (F-OLEDs) requires excellent moisture permeation barriers to minimize the degradation of the F-OLEDs device. Specifically, F-OLEDs device need a barrier layer that transmits less than $10^{-6}g/m^2/day$ of water and $10^{-5}g/m^2/day$ of oxygen. To increase the life time of F-OLEDs, therefore, it is indispensable to protect the organic materials from water and oxygen. Severe groups have reported on multi-layerd barriers consisting inorganic thin films deposited by plasma enhenced chemical deposition (PECVD) or sputtering. However, it is difficult to control the formation of granular-type morphology and microscopic pinholes in PECVD and sputtering. On the contrary, atomic layer deoposition (ALD) is free of pinhole, highly uniform, conformal films and show good step coverage. Thus, $Al_2O_3/TiO_2$ multi-layer was deposited onto the polyethersulfon (PES) substrate by electron cyclotron resonance atomic layer deposition (ECR-ALD), and the water vapor transmission rates (WVTR) were measured. WVTR of moisture permeation barriers is dependent upon density of films and initial state of polymer surface. A significant reduction of WVTR was achieved by increasing density of films and by applying low plasma induced interlayer on the PES substrate. In order to minimize damage of polymer surface, a 10 nm thick $TiO_2$ was deposited on PES prior to a $Al_2O_3$ ECR-ALD process. High quality barriers were developed from $Al_2O_3$ barriers on the $TiO_2$ interlayer. WVTR of $Al_2O_3$ by introducing $TiO_2$ interlayer was recorded in the range of $10^{-3}g/m^2.day$ at $38^{\circ}C$ and 100% relative humidity using a MOCON instrument. The WVTR was two orders of magnitude smaller than $Al_2O_3$ barriers directly grown on PES substrate without the $TiO_2$ interlayer. Thus, we can consider that the $Al_2O_3/TiO_2$ multi-layer passivation can be one of the most suitable F-OLEDs passivation films.

• Polymer(Korea)
• /
• v.34 no.4
• /
• pp.294-299
• /
• 2010

Clay-loaded polypropylene (PP) nanocomposites were fabricated via melt-compounding of two molecular weight ($M_w$) PPs (140 and 410 kg/mol) and octadecylammine-treated clay (C18MMT), with the assistance of maleic anhydride-grafted PP(PP-MAH), respectively, at $170^{\circ}C$ and $190^{\circ}C$. At both melt-compounding temperatures, the low-$M_w$ PP tends to easily diffuse into silicate layers, especially in the presence of the mobile PP-MAH, resulting in a marked increase in silicate layer spacing (above 58 $\AA$), when compared to 27 $\AA$ in the high-$M_w$ PP-based system. Due to relatively lower melt-viscosity of the low-$M_w$ PP-based system, however, there existed quasi-stacked clay aggregates with a thickness of 60~80 nm, while the high-$M_w$ PP-based nanocomposites showed relatively homogeneous dispersion of clays. The different morphologies are mainly related to changes in the viscoelastic properties of PPs, dependent on the processing temperature and their $M_{w}s$. The slight differences in nanocomposites induce discernible crystallization and mechanical behaviors. High-$M_w$ PP-based nanocomposites containing 1~3 wt% C18MMT showed improvement in both tensile strength and modulus, while maintaining the inherent ductility of pure PP.

• Journal of Conservation Science
• /
• v.37 no.5
• /
• pp.606-616
• /
• 2021

From the collection of the National Kimhae Museum, qualitative analyses using microscopic observation, SEM-EDS, Raman spectroscopy, FT-IR-ATR spectroscopy, and GC-MS were conducted on three burnished red potteries-Jeoksaekmaoyeonwa burnished red pottery (Neolithic age red pottery), Dandomaoyeonwan burnished red pottery(Bronze age red pottery) and Jeoksaekmaoyeongajimun burnished red pottery(Bronze age red pottery)-to investigate the components of the red pigments and the binder. After the layers of the primer were separated from the red surface, crystals of red pigment particles and minerals were found on the red surface. Through SEM-EDS, Raman estimates that the red pigment is Among soil pigments with iron oxide(Fe₂O₃) as the main color development source, Red Ocher(Fe₂O₃). A band characteristic of the Urushiol polymer was detected in the FTIR-ATRspectra(4000~600cm^-1), GC-MS analysis confirmed the presence of the benzenemethanol-2-prophenyl, 4-heptylphenol, 1-tetracecanol, heptafluorobutyric texidecane, all of which are the ingredients of the directional structure of the lacquer present in the red layer. Therefore, it seemed that the three burnished red pottery: Jeoksaekmaoyeonwan pottery(Neolithic age burnished red pottery), Dandomaoyeonwan pottery(bronze age burnished red pottery) and the Jeoksaekmaoyeongajimun pottery(bronze age burnished red pottery) made by mixing minerals and Red Ocher(Fe₂O₃), with lacquer.