• Macromolecular Research
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• v.17 no.6
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• pp.397-402
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• 2009

In emulsifier-free, emulsion polymerization with ionizable comonomer, the ionization of the comonomer is critical in determining the size of the final polymerie particles at sub-micrometer scale. In this study, polystyrene latex beads with carboxylates on the surface were synthesized using acrylic acid as a comonomer. Specifically, ammonium hydroxide was added to the emulsifier-free polymerization system to promote the ionization of acrylic acid by increasing pH. Smaller polystyrene latex particles were produced by increasing the ammonium hydroxide concentration in the reaction system, due to the enhanced stability promoted by the ionization of acrylic acid during the nucleation step. In addition, the surface morphology of the polystyrene latex particles was controlled by the concentration of acrylic acid, the dissociation of which was influenced by the ammonium hydroxide concentration.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.633-636
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• 2008

Concrete structures are occur many various deteriorations in the course of time and many efforts have progressed to improve on performance of concrete. The purpose of this study is to evaluate the durability of latex modified mortar in order to repair concrete structure which are happened deterioration. In this study, we tested plastic shrinkage, drying shirnkage, repeated freezing and thawing, permeability and resistance of chemical solution. Latex modified mortar and two kinds of sprayed polymer mortar used on durability test. As a result of test, latex modified repair mortar was exhibited durablilty improvement compared to the conventional sprayed polymer mortars. It is judged the fact that latex modified mortar have no problem in site application but additionally many research will be necessary.

• Elastomers and Composites
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• v.46 no.1
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• pp.60-69
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• 2011

The various types of PBA/PMMA composite latexes were prepared by $2.1\;{\mu}m$ PBA seeded batch and seeded semi-continuous dispersion polymerization. The morphology of the PBA/PMMA composite latexes by seeded batch process was found to be closely dependant on the weight ratios of methanol/water in polymerization medium and of PBA seed/MMA at the second stage. In general, egg, snowman, confetti, peanut-like nonspherical composite latex particles were formed with increasing amount of water and MMA as a result of the occurrence of the phase separation between PBA seed and PMMA. The morphology of the PBA/PMMA composite latexes by seeded semi-continuous process was controlled by the addition time of MMA, especially, spherical shaped core(PBA)/shell(PMMA) composite latex particles were prepared under the monomer-starved condition at the second stage.

• Macromolecular Research
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• v.15 no.2
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• pp.95-99
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• 2007

The most recent developments in two areas: (a) synthesis of inorganic particles with control over size and shape by polymer additives, and (b) synthesis of inorganic-polymer hybrid materials by bulk polymerization of blends of monomers with nanosized crystals are reviewed. The precipitations of inorganics, such as zinc oxide or calcium carbonate, in presence and under the control of bishydrophilic block or comb copolymers, are relevant to the field of Biomineralization. The application of surface modified latex particles, used as controlling agents, and the formation of hybrid crystals in which the latex is embedded in otherwise perfect crystals, are discussed. The formation of nano sized spheres of amorphous calcium carbonate, stabilized by surfactant-like polymers, is also discussed. Another method for the preparation of nanosized inorganic functional particles is the controlled pyrolysis of metal salt complexes of poly(acrylic acid), as demonstrated by the syntheses of lithium cobalt oxide and zinc/magnesium oxide. Bulk polymerization of methyl methacrylate blends, with for example, nanosized zinc oxide, revealed that the mechanisms of tree radical polymerization respond to the presence of these particles. The termination by radical-radical interaction and the gel effect are suppressed in favor of degenerative transfer, resulting in a polymer with enhanced thermal stability. The optical properties of the resulting polymer-particle blends are addressed based on the basic discussion of the miscibility of polymers and nanosized particles.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.225-230
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• 1995

Concrete structures need repair and rehabilitation due to functional deficiencies such as cracks, scaling and spalling. Loss of section such as spalling is caused by corrosion of reinforcing bar, fire, temperature change, poor design and etc. This study aims to examine the characteristics of polymer(epoxy)and polymer-cement(latex) for repair materials and to provide the proper repair scheme through static and fatigue tests. Totally 12 beams were tested. Results from static and fatigue tests of beams repaired with polymer and polymer-cement were compared.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.83-84
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• 2006

In aqueous phase, we directly prepared conducting and photoluminescent nano-structured particles by oxidation polymerization. Thiophene(PT) was initiated by $FeCl_{3}/H_{2}O_{2}$ (catalyst/oxidant) combination system. And, polydispersed core-shell poly(styrene/thiophene) and polyaniline(PANI)-coated multi core-shell polystyrene latex particles were successfully prepared by oxidative and radical polymerization. The resulting latex particles have fine improved luminescence and conductive efficiency and dispersion state due to the PT and PANI shell. Hyper functionalized nanoparticle would be expected to increase the processibility in various electrical and electro-optical fields.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.51-57
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• 1996

The purpose of this study is to improve the properties by increasing of the adhesion strength of styrene-butadiene rubber(SBR) latex coated powdered rubber in cement mortar. SBR-modified mortar using powdered rubber is also tested as the same method. From the test results, the cement mortar using SBR latex coated powdered rubber have a good mechanical properties compared with that using uncoated powdered rubber. The mechanical properties of SBR-modified mortar using powdered rubber with polymer-cement ratios of 10% are also improved.

• International Journal of Concrete Structures and Materials
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• v.10 no.2
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• pp.249-256
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• 2016

This paper deals with the effects of silica fume content and polymer-binder ratio on the properties of ultrarapid-hardening polymer-modified mortar using silica fume and ethylene-vinyl acetate redispersible polymer powder instead of styrene-butadiene rubber latex to shorten the hardening time. The ultrarapid-hardening polymer-modified mortar was prepared with various silica fume contents and polymer-binder ratios, and tested flexural strength, compressive strength, water absorption, carbonation depth and chloride ion penetration depth. As results, the flexural, compressive and adhesion strengths of the ultrarapid-hardening polymer-modified mortar tended to increase as increasing polymer-binder ratio, and reached the maximums at 4 % of silica fume content. The water absorption, carbonation and chloride ion penetration resistance were improved according to silica fume content and polymer-binder ratio.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.289-292
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• 2006

The purpose of this study was to evaluate a performance of latex-modified repair material applied to the substrate concrete. The experimental variables were latex-cement ratios (5, 10, 15%), polymer(0.5%, 1%) and admixtures. The flow, air content, compressive strength, flexural strength were tested. Test results showed that compressive and flexural strength decreased by adding hydroxyethyl cellulose and increasing water-binder ratio. The compressive and flexural strength were increased when addition of defoamer.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.265-268
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• 2004

Plastic shrinkage cracking is a major concern for concrete, especially for flat structures as highway pavement, bridge deck slabs, and bridge deck pavement. LMC(Latex Modified Concrete) be used mainly for bridge deck overlays, so occurrence possibility of plastic shrinkage cracking is very high. But LMC is form a close-packed layer of polymer particles in very early time from the time of adds the latex and water. So plastic shrinkage cracking compare with normal concrete is not occur at final setting time. Results indicates that LMC is advantage to prevent occurrence of plastic shrinkage crack and it's possible co construction for bridge deck overlay effectively.