• Title/Summary/Keyword: polymer column

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계면활성제를 이용한 토양내 유기오염물 (NAPL) 정화 방법의 연구

  • 이민희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.96-98
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    • 2000
  • Column experiments were peformed to evaluate the efficiency of surfactant flushing for remediation of non-aqueous phase liquid (NAPL) in the soil under controlled conditions. In column experiment less than 0.1 % of the original mass of tetrachloroethylene (PCE), remained in the column after 15 pore volumes of 1% sorbitan monooleate solution were passed through columns. To determine the influence of soil parameters that may affect the remediation process, column tests were repeated with different values of grain size, application rate, surfactant type, surfactant concentration, and solution viscosity (polymer mixed with surfactant). Experimental works suggest that surfactant flushing has a great potential to rapidly remove mass from NAPL in the soil.

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An Experimental Study on Seismic Retrofitting of RC Beam-Column Connections with Carbon FRP (탄소 FRP를 이용한 철근콘크리트 보-기둥 접합부의 내진 성능 보강 실험)

  • Kim Min;Lee Kihak;Lee Jae-Hong;Woo Sung-Woo;Lee Jung-Wean
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.263-266
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    • 2005
  • Many RC structures built without seismic provisions have exhibited brittle shear failures in the beam-column joint area, and resulted in large permanent deformations and structural collapse. This paper presents the results of an experimental investigation pertaining to the use of carbon fiber-reinforced polymer(FRP) for strengthening of RC beam-column connections. The selective upgrade is obtained by choosing different combinations and locations of carbon FRP sheets to determine the effective way to improve the structural performance of joints. Experimental results demonstrate significant improvement of flexural capacity and ductility of beam-column connections originally built without seismic details.

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Toluene Removal and Microbial Growth of Candida tropicalis Immobilized with Polymer Media in Airlift Bioreactors (효모 Candida tropicalis 고정화 담체를 이용한 Airlift 미생물반응기의 톨루엔 제거 및 미생물 성장)

  • Namgung, Hyeong-Kyu;Song, JiHyeon;Jung, Mi-Young;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.2
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    • pp.175-180
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    • 2009
  • This study was conducted to improve biological degradation efficiency of toluene as a model volatile organic compound (VOC) using yeast Candida tropicalis and to suggest an effective method for bioreactor operation. The yeast strain was immobilized with polyethylene glycol (PEG), alginate, and powdered activated carbon (PAC). The yeast-immobilized polymer media were used as fluidized materials in an airlift bioreactor. Polymer media without PAC were also made and operated in another airlift bioreactor. The two bioreactors showed toluene removal efficiencies ranging 80-96% at loading rates of $10-35 g/m^3-hr$, and the bioreactor containing the polymer media with PAC achieved higher removal efficiency. Protein contents in the liquid phase showed that the bioreactor using the yeast-immobilized polymer media with PAC had a higher rate of microbial growth initially than that without PAC. In addition, the microbial growth rate inside of the polymer media with PAC was five times higher than that without PAC. Consequently, the polymer media containing the yeast strain and PAC could enhance removal efficiencies for VOCs, and the immobilization method improve microbial activity and stability for a long-term operation of biological systems.

A practical model for simulating nonlinear behaviour of FRP strengthened RC beam-column joints

  • Shayanfar, Javad;Bengar, Habib Akbarzadeh
    • Steel and Composite Structures
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    • v.27 no.1
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    • pp.49-74
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    • 2018
  • Generally, beam-column joints are taken into account as rigid in assessment of seismic performance of reinforced concrete (RC) structures. Experimental and numerical studies have proved that ignoring nonlinearities in the joint core might crucially affect seismic performance of RC structures. On the other hand, to improve seismic behaviour of such structures, several strengthening techniques of beam-column joints have been studied and adopted in practical applications. Among these strengthening techniques, the application of FRP materials has extensively increased, especially in case of exterior RC beam-column joints. In current paper, to simulate the inelastic response in the core of RC beam-column joints strengthened by FRP sheets, a practical joint model has been proposed so that the effect of FRP sheets on characteristics of an RC joint were considered in principal tensile stress-joint rotation relations. To determine these relations, a combination of experimental results and a mechanically-based model has been developed. To verify the proposed model, it was applied to experimental specimens available in the literature. Results revealed that the model could predict inelastic response of as-built and FRP strengthened joints with reasonable precision. The simple analytic procedure and the use of experimentally computed parameters would make the model sufficiently suitable for practical applications.

Structural repairing of damaged reinforced concrete beam-column assemblies with CFRPs

  • Yurdakul, Ozgur;Avsar, Ozgur
    • Structural Engineering and Mechanics
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    • v.54 no.3
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    • pp.521-543
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    • 2015
  • Depending on the damage type as well as the level of damage observed after the earthquake, certain measures should be taken for the damaged buildings. In this study, structural repairing of two different types of damaged RC beam-column assembly by carbon fiber-reinforced polymer sheets is investigated in detail as a member repairing technique. Two types of 1:1 scale test specimens, which represent the exterior RC beam-column connection taken from inflection points of the frame, are utilized. The first specimen is designed according to the current Turkish Earthquake Code, whereas the second one represents a deficient RC beam-column assembly. Both of the specimens were subjected to cyclic quasistatic loading in the laboratory and different levels of structural damage were observed. The first specimen displayed a ductile response with the damage concentrated in the beam. However, in the second specimen, the beam-column joint was severely damaged while the rest of the members did not attain their capacities. Depending on the damage type of the specimens, the damaged members were repaired by CFRP wrapping with different configurations. After testing the repaired specimens, it is found that former capacities of the damaged members were mostly recovered by the application of CFRPs on the damaged members.

Phenol Removal Using Horseradish Peroxidase(HRP)-Mediated Polymerization Reaction in Saturated Porous Media (다공성 포화 매질에서 효소 중합반응을 이용한 페놀 제거)

  • Kim, Won-Gee;Lee, Seung-Mok
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.984-991
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    • 2008
  • This paper reports experimental results, demonstrating the feasibility of horseradish peroxidase(HRP) and H$_2$O$_2$ to reduce phenol transport in saturated porous media. A laboratory-scale packed column reactor(ID: 4.1 cm, sand-bed height 12 cm) column was utilized to simulate injection of HRP and H$_2$O$_2$ into an aquifer contaminated with phenol. Effluent concentrations of phenol and polymerization products were monitored before and after enzyme addition under various experimental conditions(enzyme dose: 0$\sim$2 AU/mL, [ionic strength]: 5$\sim$100 mM, pH: 5$\sim$9). The concentration of phenol in the column effluent was found to decrease by nearly 90% in the presence of HRP(2 AU/mL) and H$_2$O$_2$ in the continuous flow system at pH 7 and ionic strength 20 mM. The influent phenol was converted in the system to insoluble precipitate, which deposited in pore spaces. The remains were discharged as soluble oligomers. About 8% of total pore volume in column system was decreased by deposition of polymer produced.

A Study on the Risk of Spontaneous ignition to Butadiene Popcorn Polymer (Butadiene Popcorn Polymer의 자연발화 위험성에 관한 연구)

  • Koo, Chae-Chil;Lee, Jung-Suk;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.1-8
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    • 2019
  • This study was conducted to investigate the possibility of spontaneous ignition in Butadiene popcorn polymer, which is used as raw material and product in a chemical plant. A component analysis, thermogravimetric analysis, thermal stability analysis, spontaneous ignition point measurement and accelerated velocity calorimetric analysis were performed. As a result of analysis, various kinds of flammable components were measured and thermogravimetric analysis showed a weight loss of 95.6% in air and 89.2% in nitrogen. As a result of the thermal stability analysis, heat generation started at $88^{\circ}C$ in the air atmosphere, and the heat generation rate increased sharply in the vicinity of the natural ignition point ($220^{\circ}C$). The heat generation started at about $70^{\circ}C$ in nitrogen atmosphere, and the two exothermic peak values were observed up to $450^{\circ}C$. As a result of accelerated rate calorimetry, there was no exothermic phenomenon, and the lowest ignition temperature was $211.7^{\circ}C$ as a result of analysis of natural ignition point. Based on the results obtained from the thermal stability evaluation, it is considered that the possibility of inducing the thermal deformation of the column by the heat of reaction is sufficient.

Compressive behavior of galvanized steel wire mesh (GSWM) strengthened RC short column of varying shapes

  • Marthong, Comingstarful
    • Structural Monitoring and Maintenance
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    • v.7 no.3
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    • pp.215-231
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    • 2020
  • In a reinforced concrete building different shapes of column are adopted depending on the structural orientation and the architectural aspect. When there is an increase in loading due to changes in usage or revision in the design codes these columns need to be strengthened for enhanced performance during their service life. Strengthening materials such as carbon fiber and glass fiber polymer has been successfully used however, due to high cost application other alternative materials need to be explore. Galvanized steel wire mesh (GSWM) is one of the suitable materials locally available. High tensile strength, low weight, corrosion resistance, easy installation, minimum change in dimensions of the sections and cost effectives are the advantages of GSWM. Therefore, in this paper, four different shapes of column such as circular, square, rectangular and L were wrapped with different layers GSWM and jacketed with mortar. All the specimens were tested under axial compression. The objective of the study is to investigate the effectiveness of GSWM as a confining material for strengthening of column having varying shape. Test results shows that the axial strength enhanced with wrapping of GSWM jacket and a circular column presented the highest load carrying capacity and ductility as compared to the others. From the study of 22 column specimens, it is found that axial load is increased upto 20% and 19% when circular and square column are strengthened with one wrap of GSWM respectively, while a rectangular and L column required a wraps of two and three layers respectively in order to achieved the same load capacity as that of a circular column. Based on the present study, it is concluded that GSWM can be effectively used for strengthening of different shapes of concrete columns economically.

Application of Concentrated FRP Bars to Enhance the Capacity of Two-Way Slabs (2방향 슬래브의 성능 향상을 위한 집중 배근된 FRP 바의 적용)

  • Lee, Joo-Ha;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.19 no.6
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    • pp.727-734
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    • 2007
  • The influence of the differences in the physical and mechanical properties between fiber-reinforced polymer (FRP) and conventional steel, concentrated reinforcement in the immediate column region, as well as using steel fiber-reinforced concrete (SFRC) in the slab near the column faces, on the punching behavior of two-way slabs were investigated. The punching shear capacity, stiffness, ductility, strain distribution, and crack control were investigated. Concentrating of the slab reinforcement and the use of SFRC in the slab enhanced the punching behavior of the slabs reinforced with glass fiber-reinforced polymer (GFRP) bars. In addition the test results of the slabs with concentrated reinforcement were compared with various code equations and the predictions proposed in the literature specifically for FRP-reinforced slabs. An appropriate method for determining the reinforcement ratio of slabs with a banded distribution was also investigated to allow predictions to properly reflect the benefit of the slab reinforcement concentration.

Study on Analysis of Vulcanized Rubber by Pyrolysis-Gas Chromatography(I) (Vulcanizates of NR BR and SBR) (Pyrolysis-Gas Chromatography를 이용한 가황 고무의 열분석에 관한연구(I) (NR, BR 및 SBR의 가황체))

  • Huh, D.S.;Kim, J.S.;Kim, K.J.;Ahn, B.K.;Suh, S.K.;Han, O.K.
    • Elastomers and Composites
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    • v.22 no.1
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    • pp.11-19
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    • 1987
  • A coil pyrolyzer and processor-controlled gas chromatograph were used for analysis of rubber for compounding ratio of the single and blend rubber vlucanizates. Variables such as sample size, pyrolysis temperature, time allowed for pyrolysis, the column packing material, its length and programmable temperature for gas chromatography were examined to obtain optimum condition for application to NR, BR and SBR blends. By application fixed conditions, three kinds of standard curves were finally obtained from thirty samples of blend vulcanizates which were prepared in the pilot plant, NIRI. It is possible to determine rubber composition and their ratio in NR, BR and SBR products by pyrolysis.

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