• 폴리머
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• 제37권4호
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• pp.500-506
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• 2013

비혼화성인 선형의 폴리페닐렌설파이드(PPS)와 상용 폴리에틸렌테레프탈레이트(PET)의 블렌드 물성에 미치는 상용화제의 구조에 따른 영향을 조사하였다. 머독 혼련 스크류가 장착된 단축 압출기를 통하여 제조한 블렌드를 성형하여 그 특성들을 살펴보았다. 물성과 경제성을 고려하여 PPS/PET(40/60)을 기초 블렌드로 선정한 후 여기에 도메인 크기감소와 계면접착력 향상을 위하여 상용화제로 styrene-ethylene/butylene-styrene(SEBS), modified SEBS(m-SEBS), modified polystyrene(m-PS) 등을 사용하였다. 이들을 기초블렌드에 첨가하여 삼원블렌드를 제조한 후 열적, 유변학적, 기계적 특성을 측정하고 모폴로지를 관찰하였다. 기계적 물성은 각각 m-SEBS와 m-PS 첨가량 1 phr 부근에서 최대값을 보였는데 그 값이 이론적인 혼화성계의 값에 거의 근접하였으며 m-PS가 가장 뛰어난 성능을 보였다. m-SEBS와 m-PS는 선형 PPS와/또는 PET와의 부분적인 반응을 통해 상용성을 증대시켜서 더 큰 효과를 보인 것으로 판단된다. 이러한 삼원블렌드는 경제성있는 PPS 알로이로서 적용이 가능하리라 사료된다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2003년도 춘계학술대회 논문집
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• pp.144-148
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• 2003

현재 섬유 분야에서 많은 부분을 차지하고 있는 폴리에틸렌테레프탈레이트(Polyethylene terephthalate, PET) 섬유는 강도, 혼방성, 내열성 등이 우수한 반면, 염색성, 필링성, 흡습성, 대전성 등의 결점들을 가지고 있어 이러한 단점들을 개선하려는 연구가 현재까지 지속적으로 진행되어 오고 있다 PET의 개질 방법 가운데 촉감개선을 위한 알칼리 감량 가공은 영국에서 처음으로 시도되었고, 1970년대 중반 이후 일본에서 공업화시켰으며 현재에도 가장 널리 사용되고 있는 방법 중의 하나이다. (중략)

• 한국염색가공학회지
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• 제3권4호
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• pp.17-21
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• 1991

A rigid polymer, cellulose triacetate (CTA) dissolved in a combination of trifluoroacetic acid (TFA) and methylene chloride (MC) solution are liguid crystalline above a certain concentration. A flexible polymer, polyethylene terephthalate (PET) also dissolves in TFA/MC, but does not form liguid crystal phase. Ternary solutions, CTA/PET/TFA-MC which CTA and PET were mixed in a same solvent TFA/MC (6/4 : v/v) showed phase separation and mesophase formation.

• 한국염색가공학회지
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• 제2권1호
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• pp.21-30
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• 1990

In order to obtain high dye uptake initially, polyethylene terephthalate (PET) filaments were dyed with C.I.Disperse Orange 3 and Red 1 in mixed solvents of tetrachloroethylene acidic solvent, ethyl alcohol and tetrachloroethylene basic solvent, DMF. The dyeing behavior in the mixed solvent of tetrachloroethylene and basic solvent, DMF, the initial uptake of disperse dyes increased rapidly. The shrinkage of PET increased when the solubility parameter values of PET fiber and mixed solvent approached graduately.

• Elastomers and Composites
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• 제47권2호
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• pp.96-103
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• 2012

본 논문에서는 PET를 재활용하는 최근의 기술들을 소개한다. PET가 광범위하게 사용되고 또한 썩지 않기 때문에 환경 문제를 야기하고 또한 이 물질의 폐기 및 소각은 경제적 손실이기도 하다. PET의 화학적 재활용은 이 폐기물들을 유용한 원료물질로 전환하여 PET를 재생산하는 것이 가능하게 한다. PET의 화학적 재활용은 글리콜에 의한 글리콜리시스, 메탄올에 의한 메탄올리시스, 물에 의한 가수분해 등의 반응에 의한 PET 고분자 사슬의 분해가 이루어지고, 분리정제 과정을 거쳐 MEG, DMT, PTA와 같은 단량체 혹은 폴리에스터 올리고머로 만들어진다. 이 물질들은 폴리에스터를 합성하는 데 사용될 수 있다.

• Advances in concrete construction
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• 제12권6호
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• pp.461-467
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• 2021

Polyethylene-terephthalate (PET) from bottle waste and linear low-density polyethylene (LLDPE) from barrels and tanks waste are widely available and need to be recycled. Recycling them in concrete and mortar is an alternative solution for their disposal. In this study various quantities of sand (5%, 10%, 15% and 20%) were substituted by powder from LLDPE waste. In addition, PET waste fibers (corrugated, straight) were added to the mortar with different percentages (0.5%, 1%, 1.5% and 2%) of cement mass. This paper evaluate the mechanical and physical properties of the composites in fresh (workability, air content and density) and hardened state (compressive and flexural strength, water absorption and total shrinkage). From the experimental results, it can be concluded that the strengthening in tensile of the mortar with plastic waste corrugated fibers is improved. Other important results are that the water absorption and the density rate are less than that of the ordinary mortar.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.163-166
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• 1998

In this paper, breakdown strength and dielectric characteristics were experimented in the structures of insulation/insulation/insulation and insulation/semiconductor/insulation by using of insulation material of polyethylene terephthalate film. The breakdown strength and the permitivity of each specimen were measured as a function of temperature and frequency respectively. The breakdown strength of PET/PET/PET did not changed greatly but that of PET/SEMl/PEr increased as a function of temperature. As the frequency inclosed, the permitivity of PET/PET/PET and PET/SEMI/PET decreased. The tan $\delta$ of PET/PET/PET showed lower than that of PET/SEMl/PET in low frequency but higher in high frequency .

• E2M - 전기 전자와 첨단 소재
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• 제8권3호
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• pp.316-323
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• 1995

A vital step in magnetic tape manufacturing is the surface modification of polymer substrate prior to ink application. A critical element for good adhesion of magnetic ink on polymeric substrate is the ability to join ink in cost-effective manner. Corona discharging is one of the effective methods of modifying polymer surface to improve adhesion while maintaining the desirable properties of the film itself. Surface treatment by corona which is exposure of film surface to electron or ion bombardment, rather than mere exposure to active species, like atomic oxygen or ozone, can enhance adhesion by removing contaminant, electret, roughening surface, and/or introducing reactive chemical groups. Reactive neutrals, ions, electron and photons generated during the corona treatment interact simultaneously with polymers to alter surface chemical composition, wettability, and thus film adhesion. However, it is highly recommended that extensive chains scission be avoided because it can lead to side-effect by forming sticky matter, resulting in dropouts. This paper reviews principles of surface preparation of polymer substrate by corona discharging. In addition, the experimental section provides a description of parameter optimization on corona discharging treatment and its side-effect. Experimental results are discussed in terms of surface wetting as determined by contact angle measurements.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.224-227
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• 2002

In this paper, we have investigated the physical properties and electrical conduction properties of polyethylene terephthalate film due to temperature variation, and the measurement of volume resistivity used to highmegohm meter is measured from 1 to 10 minutes when the specimen applied the voltage accroding to the step voltage appling method. From FT-IR spectrum as an analysis of physical properties, the strong absorption in wavenumbers $1019[cm^{-1}]$, $1266[cm^{-1}]$ and $1752[cm^{-1}]$ observed by the C=O and benzene ring. From the analysis of DSC, the crystalline melting points of the specimen observed in the temperature $80[^{\circ}C]$ and $263[^{\circ}C]$, respectively.

• 한국레이저가공학회지
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• 제6권3호
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• pp.19-28
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• 2003

The manufacturing process for the microfluidic device can include sequential steps such as master fabrication, electroforming, and injection molding. The laser ablation, using masks, has been applied to the fabrication of channels in microfluidic devices. In this research, an excimer laser was used to engrave microscopic channels on the surface of PET (polyethylene terephthalate), which shows a high absorption ratio for an excimer laser beam with a wavelength of 248 m. When 50-${\mu}{\textrm}{m}$-wide rectangular microscopic channels are ablated with a 500 ${\times}$ 500 ${\mu}{\textrm}{m}$ square mask at a magnification ratio of 1/10, ditch-shaped defects were found in both corners. The measurement of laser beam intensity showed that a coherent image in the PET target caused such defects. Analysis based on the Fourier diffraction theory enabled the prediction of the coherent shape at the image surface as well as the diffraction beam shape between the mask and the image surface. It also showed that the diameter of the aperture had a dominant effect. The application of aperture with a diameter of less than 3 mm helped to eliminate such defects in the ablated rectangular microscopic channels on PET without such ditch-shaped defects.