• Applied Chemistry for Engineering
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• v.29 no.2
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• pp.201-208
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• 2018

The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

• Journal of the Korea Institute of Building Construction
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• v.8 no.6
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• pp.131-137
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• 2008

In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2000.06a
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• pp.52-57
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• 2000

This paper discusses frequency analysis based on frequency spectrum in orthogonal cutting of fiber-matrix composite materials. A glass reinforced polyester (GFRP) was used as workpiece. Analysis method employs a force sensor and the signals from the sensor are processed using a fast Fourier transform (FFT) technique. The experimental correlation between the different chip formation mechanisms and model coefficients are then established. (omitted)

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.88-91
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• 2004

In this study, a number of natural fiber henequen reinforced polymer matrix composites were successfully fabricated by means of a compression molding technique using chopped henequen fibers surface-treated with different electron beam irradiation (EBI) dosages, thermoplastic poly(butylene succinate), thermosetting unsaturated polyester and phenolic resins. Their interfacial and thermal characteristics were studied in terms of interfacial shear strength, fracture surface, dynamic mechanical properties, dimensional stability, and thermal stability using single fiber microbonding test, SEM, DMA, TMA, and TGA. The results show that their interfacial and thermal properties significantly depend on the intensity of EBl treatment on the natural fiber surface.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.54-57
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• 2003

Since passenger cars require five wheels including a spare, the weight reduction of wheels without sacrificing performance is important. Recently, the structured components of cars made of steel are replaced by composites. plastics and other nonmetallic materials such as aluminum and magnesium for weight reduction. From these new tried materials are most promising due to their high specific stiffness and specific strength. The composites manufactured by resin transfer molding (RTM) process has not only low cost for the manufacturing but also reduces the lead time and development because the molds for RTM is easy to manufacture. In this work, composite wheels for passenger cars were designed and manufactured by RTM process. Since surface quality of wheels is important for passenger cars, the optimal stacking sequence for composite wheels was selected considering surface quality and mechanical properties. Also, the manufacturing method for the composite mold was depicted.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.04a
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• pp.103-108
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• 1999

A synthesized model of pultrusion process considering thermally induced deformatiion was established. The model was composed of liquid resin flow model thermo-chemical analysis and linear elastic analysis. in order to verify the above-mentioned models several experiments were performed. A laboratory scale pultrusion line was established and glass/polyester composites were fabricated. the experimental results were compared with the calculated ones. The model successfully could estimate degree of cure pulling force and amount of process-induced deformation.

• Composites Research
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• v.12 no.2
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• pp.62-69
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• 1999

During fatigue loading of composite materials, damage accumulation can be monitored by measuring their material properties. In this study, fatigue modulus is used as the damage index. Fatigue life of composite materials may be predicted analytically using damage models which are based on fatigue modulus and resultant strain. Damage models are propesed as funtions of applied stress level, number of fatigue cycle and fatigue life. The predicted life was comparable to the experimental result obtained using E-glass fiber reinforced epoxy resin materials and pultruded glass fiber reinforce polyester composites under two-stress level fatigue loading.

• Polymer(Korea)
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• v.24 no.4
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• pp.564-570
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• 2000

The waste FRP occured in the fabrication of SMC (sheet molding compound) bathtubs and the waste polyurethane foam occured in electronic manufacture and waste insulator were applied as a soundproof and light weight pannel in the waste FRP unsaturated polyester matrix resin composites to recycle. The effect of filler contents on the mechanical properties and interfacial phenomena of the filler and matrix on the composites was evaluated. The tensile strength of composites reached its maximum value of 82.34 MPa when the filler content was 70 wt%, and the more content of reinforcement is increased, the more tensile modulus was decreased. The flexural strength and modulus of composites, reinforced 70 wt% with filler content, were dominant compared to the other samples to 72.5 MPa, 958.4 MPa respectively. When composite of reinforced 70 wt% with filler content, it was confirmed that pull out phenomena and cracks did not occur in the interface of reinforcement and matrix resin through the SEM observation. Also, waste FRP and urethane foam were dispersed well into matrix resin as filler.

• Polymer(Korea)
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• v.25 no.6
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• pp.774-781
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• 2001

In order to reuse the waste matters, the polyester hybrid composites were fabricated with the waste stone (WSP) and waste tire (WTC). Before mixing, the waste fillers were treated with the silane coupling agent [${\gamma}$-methacryloxy propyl trimethoxy silane(${\gamma}$-MPS)] for enhancing the dispersion of the fillers and interfacial bonding with polymer matrix. Mechanical properties and morphologies of the resulted hybrid composites were investigated with the filler content. The hybrid composites containing surface treated fillers have high initial thermal decomposition temperature and low weight loss compared to the untreated one. The highest mechanical properties of composites were obtained with the ${\gamma}$-MPS (2 wt%) treated fillers. The porosity of composite increased with the content of organic filler which can be reduced by the silane surface treatment of fillers. The pore size distribution of the composites varied with the waste filler content.

• Elastomers and Composites
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• v.49 no.1
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• pp.31-36
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• 2014

Polyester polyols were synthesized by using each one mole of sebacic acid, isophthalic acid, ethylene glycol, and neopentyl glycol. The synthesized polyol had 56.6 mg KOH/g of hydroxy value and 1980 g/mole of molecular weight. From FT-IR structure analysis of polyester polyol, Hydroxy group(-OH) was observed around 3600 $cm^{-1}$, -CH shoulder of sebacic acid at 2950 $cm^{-1}$, carbony group of ester around 1730 $cm^{-1}$, and benzene ring of isophthalic ring was represented at 1600 $cm^{-1}$, 740 $cm^{-1}$. In case of polyurethane, hydroxy peak was showed at 3600 $cm^{-1}$, and -NH group around 3300 $cm^{-1}$, 1530 $cm^{-1}$. From $^1H$ NMR measurement of polyester polyol, it was found that sebacic acid was represented at 1.3, 1.5, 2.1 ppm, isophthalic acid at 7.3, 8.1, 8.7 ppm, ethylene glycol at 4.2 ppm, and neopentyl glycol at 0.8, 3.2, 3.9 ppm, respectively. In the polyurethane, it is almost the same as spectrum of polyester polyol, but showed very week peak at 7 ppm by benzene ring of toluene diisocyanate.