• Title/Summary/Keyword: polyQ

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Structure-Property Relationship of PVA-SbQ Water Soluble Photosensitive Polymer and its Application to Screening Process of Color Monitor (PVA-SbQ 수용성 감광성 고분자의 구조와 감도관계 및 칼라 수상관 스크린 공정에의 응용)

  • Park, Lee Soon;Han, Yoon Soo;Kim, Bong Chul
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.379-386
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    • 1996
  • Photosensitive compound, 1-methyl-4-[2-(4-diethylacetylphenyl)ethenyl] pridinium methosulfate(SbQ-A salt), was synthesized from dimethyl sulfate, terephthalaldehyde mono-(diethylacetal) and 4-picoline. SbQ-A salts were reacted with poly(vinyl alcohol)s, (PVA) in aqueous solution with phosphoric acid as catalyst to give photosensitive PVA-SbQ with different SbQ content and molecular weight. Relative photosensitivity of PVA-SbQ was determined by gray scale(GS) method. The rotative sensitivity of PVA-SbQ increased with increasing amount of bound SbQ in the case of high molecular weight(MW=77,000-79,000g/mol) as substrate and decreased with decreasing molecular weight of PVA with about constant(1.3mol%) amount of bound SbQ. The most sensitive polymer was obtained when SbQ group content in PVA-SbQ reached about 2.63mol% in the case of high molecular weight(77,000-79,000g/mol) PVA. This sample showed 90 times greater sensitivity than dichromated PVA as reference photosensitive system. PVA-SbQ photosensitive polymer synthesized was applied to the photolithographic screening process of phosphor on the panel of cathode ray tube(CRT). Phosphor slurry was made with PVA-SbQ, phosphor, a small amount of surfactant and other additives using water as medium. The slurry was coated onto panel, dried by heater, exposed to UV light and then developed by distilled water. When a small amount of cationic surfactant such as cetyltrimethylammonium chloride was used in the slurry formulation, the sharpness of phosphor pattern was equal to or better than that of dichromated PVA photosensitive polymer system used currently.

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Highly Fluorescing Solid DNA-Cationic Polyelectrolyte Complexes Prepared from a Natural DNA and a Poly(fluorenevinylene-alt-phenylene) Bearing Quaternary Ammonium Pendants

  • Yu, Young-Jun;Kwon, Young-Wan;Kim, Kyu-Nam;Do, Eui-Doo;Choi, Dong-Hoon;Jin, Jung-Il;Shin, Hee-Won;Kim, Yong-Rok;Kang, Ik-Joong;Mikroyannidis, John A.
    • Macromolecular Research
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    • v.17 no.4
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    • pp.245-249
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    • 2009
  • A fluorescing, copolymer(Q)-bearing, quaternary ammonium pendant was mixed with excess natural salmon sperm DNA with a molecular weight of $1.3{\times}10^6$(2,000 base pairs) to afford highly fluorescing, complex mixtures. The fluorescence life-time of the polymer Q was greatly increased when mixed with DNA: for the mixture of Q:DNA=1:750 the fast and slow decay lifetimes increased from ca. 10 to 100 ps and from 20 ps to ca. 1 ns, respectively. The enhanced fluorescence of the mixtures was ascribed to efficient compartmentalization and reduced conformational relaxation of the polymer Q by complexation with excess DNA.

ISFET Urea Sensor Using PVA-SbQ Polymer (PVA-SbQ 고분자 물질을 이용한 ISFET 尿素센서)

  • Sung Moon Choi;Chang-Soo Kim;Dong-Hyun Nam;Byung-Ki Sohn;Ui-Rak Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.496-503
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    • 1992
  • An ISFET urea sensor was fabricated by immobilizing the urease using photosensitive polymer, poly(vinyl alcohol)-SbQ on the H$^+$ sensing $Si_3$$N_4$ thin film of pH-ISFET. The sensor could determine the urea concentration in the range of 1∼50 mg/dl with fast response and good repeatability. For its application to clinical analysis, the interferences of the various materials which cause inhibition in urease catalytic reactions in blood was investigated. The results of the urea measurements in blood plasma using the ISFET urea sensor were compared with these of conventional spectrophotometric method.

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Swelling Controlled Delivery of Antibiotic from a Hydrophilic Macromolecular Matrix with Hydrophobic Moieties

  • Shukla, Sandeep;Bajpai, Anil Kumar;Bajpai, Jaya
    • Macromolecular Research
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    • v.11 no.4
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    • pp.273-282
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    • 2003
  • A hydrophilic macromolecular network containing hydrophobic moieties has been prepared by free radical copolymerization of acrylamide and styrene in the presence of poly(vinyl alcohol) (PVA) and its potential as controlled drug delivery carrier was evaluated with tetracycline as a model antibiotic drug. The amount of drug was assayed spectrophotometrically. The network was characterized by optical microscopy, infra-red spectroscopy and structural parameters such as average molecular weight between cross1inks ($M_c$), cross1ink density (q) and number of elastically effective chains ($V_e$) were evaluated. It was found that with increasing concentration of PVA, ST and MBA in the hydrogel, the release rate initially increases but after definite concentrations of the above components the release rate falls. In the case of AM, release rate constantly decreases with increasing AM concentration in the hydrogel.

Design of 8-bit DAC for System on Panel using Low Temperature Poly-Si TFTs (저온 Poly-Si TFT를 이용한 System on Panel용 8-Bit DAC 설계)

  • Byun, Chun-Won;Choi, Byong-Deok
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.841-842
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    • 2006
  • This paper has proposed a serial 8-bit DAC for column driver circuits of mobile displays using LTPS TFTs. The DAC circuit takes very small area by using parasitic capacitance of column lines as sampling and holding capacitors. Moreover, the proposed DAC does not need the analog buffer, because the DAC operation is performed on the column lines. For the data driver circuits of 2-inch qVGA OLED panel, the DAC area is $84um{\times}800um$ and the simulated DAC power consumption is 8.5mW with 10-V supply voltage.

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A Study on Wafer Level Vacuum Packaging using Epi poly for MEMS Applications (Epi poly를 이용한 MEMS 소자용 웨이퍼 단위의 진공 패키징에 대한 연구)

  • 석선호;이병렬;전국진
    • Journal of the Semiconductor & Display Technology
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    • v.1 no.1
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    • pp.15-19
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    • 2002
  • A new vacuum packaging process in wafer level is developed for the surface micromachining devices using glass silicon anodic bonding technology. The inside pressure of the packaged device was measured indirectly by the quality factor of the mechanical resonator. The measured Q factor was about 5$\times10^4$ and the estimated inner pressure was about 1 mTorr. And it is also possible to change the inside pressure of the packaged devices from 2 Torr to 1 mTorr by varying the amount of the Ti gettering material. The long-term stability test is still on the way, but in initial characterization, the yield is about 80% and the vacuum degradation with time was not observed.

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The Design of A 1.9 GHz CMOS RF Bandpass Amplifier (1.9GHz CMOS RF 대역통과 증폭기의 설계)

  • 류재우;주홍일유상
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.1121-1124
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    • 1998
  • A CMOS RF bandpass amplifier which performs both functions of low-noise amplifier and bandpass filter is designed for the application of 1.9 ㎓ RF front-end in wireless receivers. The positive-feedback Q-enhancement technique is used to overcome the low gain and low Q factor of the bandpass amplifier. The designed bandpass amplifier is simulated with HSPICE and fabricated using HYUNDAI $0.8\mu\textrm{m}$ CMOS 2-poly 2-metal full custom process. Under 3 V supply voltage, results of simulation show that the CMOS bandpass amplifier provides the power gain 23dB, noise figure 3.8 dB, and power dissipation 55mW.

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Structural modal identification through ensemble empirical modal decomposition

  • Zhang, J.;Yan, R.Q.;Yang, C.Q.
    • Smart Structures and Systems
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    • v.11 no.1
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    • pp.123-134
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    • 2013
  • Identifying structural modal parameters, especially those modes within high frequency range, from ambient data is still a challenging problem due to various kinds of uncertainty involved in vibration measurements. A procedure applying an ensemble empirical mode decomposition (EEMD) method is proposed for accurate and robust structural modal identification. In the proposed method, the EEMD process is first implemented to decompose the original ambient data to a set of intrinsic mode functions (IMFs), which are zero-mean time series with energy in narrow frequency bands. Subsequently, a Sub-PolyMAX method is performed in narrow frequency bands by using IMFs as primary data for structural modal identification. The merit of the proposed method is that it performs structural identification in narrow frequency bands (take IMFs as primary data), unlike the traditional method in the whole frequency space (take original measurements as primary data), thus it produces more accurate identification results. A numerical example and a multiple-span continuous steel bridge have been investigated to verify the effectiveness of the proposed method.

Preparation and Characteristics of Organic Electroluminescence Devices Using Multilayer structure with Carrier Transport Materials (다층막 구조를 이용한 유기 EL소자의 제작과 특성에 관한 연구)

  • 이상윤;김태완;최종선;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.249-252
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    • 1997
  • Electroluminescence(EL) devices based on organic thin layers have attracted lot of interests because of their possible application as large-area display-emitting display. One of the problems of such devices is lifetime of the cell, where the degradation of the cell is partially due to the crystalliyzation of organic layers. In large part, this problem can be solved by using a multilayer device structure prepared by vapor deposition technique. In this study, blue light-emitting multilayer organic electroluminescence devices were fabricated vsing Poly (9-vinylcarbaEole) (PVK) and 2- (4-tert-butylphenyl)-5-(4$^{#}$-bis-phenyl) 1,3,4-oxadiazole (PBO) as hole trasport and electron transport material, respectively, where trim(8-hyd roxyquinolinate) aluminum (Al $q_3$) was used as a luminescenct material. A cell structure of glass sub- strate/indume-tin-oxide(ITO)/PCK/Al $q_3$/PBD/Mg:In was employed. Blue emission peak at 510nm was observed with this cell structure.e.

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The Fabrication of On-chip Spiral Inductors Through 3-D Field Analysis (3-D Field 해석을 통한 온칩 나선형 인덕터 제작)

  • Lee, Han-Young;Lee, Woo-Cheol
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.11
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    • pp.1967-1971
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    • 2007
  • In this paper, we verified basic forms and equivalent circuits of spiral inductors and various kinds of parasitics of equivalent circuits by using HFSS and Nexxim program that were 3-D EM analysis tools, and fabrication on-chip spiral inductors using Hynix's 0.25um 1-poly and 5-metal CMOS process. Comparing with PGS(patterned ground shield) and NPGS(non patterned ground shield) of spiral inductors of 3.5 turn, 4.5 turn and 5.5 turn, etc, the application of PGS could improve maximum Q value by 8-12%.