• Title/Summary/Keyword: plasticizer ratio

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Study on Strength Development of Concrete for Top-Down Method (역타공법에 적용을 위한 콘크리트 강도성상 연구)

  • 정근호;이종균;김영회;이영도;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.48-53
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    • 1998
  • The purpose of this study to fine the mixture of concrete for Top-Down method. As a result, In fresh concrete, slump value and slump-flow value were increased as fly ash concrete(10% ratio). When plasticizer was added 1.5% by weigh of binder in concrete, no fly ash concrete and fly ash concrete(10% ratio) all occurred segregation. And, no fly ash concrete and fly concrete(10% ratio) all showed compressive strength development close plain concrete as increasing plasticizer quantity. Especially, in case of 1.5% plasticizer of binder showed high compressive strength development.

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Fabrication of Ceramic Heat Exchanger Cores by Doctor Blade Process (Doctor blade 공정에 의한 세라믹스 열교환기 소자의 제조)

  • 김상우;송휴섭;장성도
    • Journal of the Korean Ceramic Society
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    • v.29 no.3
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    • pp.241-251
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    • 1992
  • The effects of slip composition and processing conditions on the fabrication of ceramic heat exchanger cores by doctor blade process were investigated. Since the effects of those two variables were inter-dependent, the effects of binder system, binder plus plasticizer, were extensively studied for a limited range of processing conditions and a pre-determined ceramic composition. The content of binder system and the ratio of binder to plasticizer were identified as main variables to affect densities and mechanical properties of green sheets, compressive properties and bond strengths of laminates, and shrinkages and their anisotropy of sintered laminates. However, sintered densities and water absorptions of laminates were not influenced by either the content of binder system or the ratio of binder to plasticizer, when the debinded laminates had a relatively high density (relative density of >55% in this study).

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Effect of Organic Additive Composition on Isostatic Thermocompression Behavior of Alumina Tapes (유기물 조성에 따른 알루미나 테이프의 열간 가압 거동)

  • 이명현;박일석;김대준;이득용
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.824-831
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    • 2000
  • Alumina tapes, having various ratios of alumina to alumina+binder+plasticizer (a/(a+o)) and binder to binder+plasticizer(b/(b+p)), were prepared by the tape casting method. The tapes were thermocompressed varying the thermocompression parameters such as temperature, pressure, and duration time. Among the parameters, the pressure was the most influential to the tape packing density. The packing density varied in two different ways depending on the a/(a+o) ratio. For the tapes having low a/(a+o) ratio, a saturation density was reached by applying very a low pressure of 1 MPa. For tapes with high a/(a+o), on the contrary, the saturation density was obtained at a relatively high pressure. These different responses to the pressure are attributed to the fact that the rearrangement of alumina particles by the pressure becomes easy as an organic content in the tapes is high.

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Conductivity of PAN/PVDF based Polymer Electrolyte as a Function of Plasticizer Mixed Ratio (가소제 혼합비에 따른 PAN/PVDF계 고분자 전해질의 이온 전도 특성)

  • Lee, Jae-An;Kim, Jong-Uk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.261-264
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PAN/PVDF electrolytes as a function of a mixed ratio. PAN/PVDF based polymer electrolyte films were prepared by thermal gellification method of preweighed PAN/PVDF, plasticizer and Li salt. By adding PVDF and as a function of plasticizer mixed ratio to PAN-LiClO4 electrolyte, its conductivity was higher than that of PAN-$LiClO4_4$ electrolyte. The conductivity of PAN/PVDF electrolytes was $10^{-3}S/cm$. $10PAN10PVDFLiClO_4PC_5EC_5$ electrolyte shows the better conductivity of the others. Steady state current method and ac impedance used for the determination of transference numbers in PAN/PVDF electrolyte film. The transference number of $10PAN10PVDFLiClO_4PC_5EC_5$ electrolyte is 0.45.

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Study on Rheological Properties of Mortar for the Application of 3D Printing Method (3D 프린팅 공법 적용을 위한 모르타르 구성성분 변화에 따른 레올로지 특성 연구)

  • Lee, Hojae;Kim, Won-Woo;Moon, Jae-Heum
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.16-24
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    • 2018
  • In this study, an experiment was conducted to analyze mortar based rheology for 3D printing method application. The tendency of rheological properties due to the change of W/B, binder type, replacement ratio, and super plasticizer which have a great influence on the flow characteristics of concrete was experimentally analyzed. Experiments were carried out by dividing into paste and mortar. In the paste experiment, rheology was analyzed by setting W/B, binder type, replacement ratio, and super plasticizer dosage as main variables. In the mortar experiment, the rheological properties of W/B and sand ratio were analyzed. As a result, as the W/B was increased, the viscosity decreased and the FA ratio to replace FA increased and the viscosity increased. In order to increase the fluidity, substitution of only 5% of SF reduces the shear stress and the viscosity is reduced by about 83%. Mortar rheological evaluation shows that there is a critical section where a large change occurs in the W/B 30 to 40% section. Also, in the same W/B, it is analyzed that there is a critical section where the shear stress increases more than twice in the sand ratio of 50~60%.

Effects of PEG (Polyethylene Glycol) Concentration and Mixing Ratio of PEG/Gly (Glycerol) on the Physical Properties of Silk Fibroin Films (PEG(polyethylene glycol) 농도와 PEG/Gly(glycerol) 흔합비에 따른 견 피브로인 필름의 물성)

  • Ma, Yu-Hyun;Song, Kyung-Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.1
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    • pp.121-125
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    • 2006
  • To study the effects of plasticizer concentration and its ratio on the physical properties of silk fibroin films, polyethylene glycol (PEG) was used at 4 different concentrations; 1, 2, 3, $4.5\%$ (w/v). Tensile strength (TS) and water vapor permeability (WVP) increased with the increase of PEG concentration, while opposite trend was observed for percent elongation of silk fibroin films. WVP of silk fibroin films increased from $2.54\;ng{\cdot}m/m^2spa$ for $1\%$ of PEG to $5.41\;ng{\cdot}m/m^2sPa$ for $4.5\%$. In addition, a mixture of PEG and glycerol (Gly) as a plasticizer was used at the ratio of 100:0, 75:25, 50:50, 25:75, and 0:100 (w/w). Percent elongation of the films was improved to $130.95\%$ when the ratio of 75:25 was used. On the contrary, WVP of silk fibroin films increased with the decrease of the ratio of PEG:Gly. Effect of the plasticizer concentration and its ratio on the color of silk fibroin films was negligible. These results suggest that mixture of PEG and Gly as a plasticizer provide more flexible than PEG alone in silk fibroin films, and the best ratio of PEG to Gly was 75:25.

Mechanical and Barrier Properties of Soybean Curd Residue Protein Films (비지 단백질로 제조한 가식성필름의 기계적 및 물질투과특성)

  • Cho, Seung-Yong;Park, Jang-Woo;Rhee, Chul
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.5 no.2
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    • pp.9-16
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    • 1999
  • Edible films were prepared from proteins extracted from soybean curd residue by alkaline extraction and isoelectric precipitation. Effects of film forming solution pH and plasticizers on mechanical and barrier properties of edible films were studied. films were formed within pH $7{\sim}11$ with tensile strength (TS) of $2.9{\sim}3.3$ MPa. Films produced under pH 10 had the highest TS and Elongation (E) (3.3 MPa and 60.1%) but no significant difference was observed among water vapor permeabilities (WVP) of film. Glycerol, sorbitol and its mixture (1:1, w/w) were added as plasticizers. The concentration and mixing ratio of plasticizers also affected the TS, E and WVP of films. TS of films decreased from 15.0 MPa to 2.9 MPa as plasticizer concentration increased from 0.4 to 0.8 g plasticizer/g protein. At a plasticizer concentration, the highest TS was observed when sorbitol was used whereas the highest E was measured when mixture of glycerol and sorbitol was used as plasticizer WVP of films increased as the plasticizer concentration increased. Films plasticized with glycerol showed the highest WVP among the films with the same plasticizer concentrations. Edible films prepared from soybean curd residue protein showed very low oxygen permeabilities ($29.5{\sim}61.1aL{\cdot}m/m^2{\cdot}s{\cdot}Pa$) and oil resistance at all plasticizer concentration level tested.

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Engineering Characteristics of Plasticizer Lightweight Foamed Concrete according to Changes of Mixing Ratio (가소성 경량기포콘크리트의 배합비 변화에 따른 공학적 특성)

  • Seo, Doowon;Kim, Hyeyang;Kim, Kyungmin;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.4
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    • pp.33-42
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    • 2010
  • The lightweight foamed concrete is used to reduce the weight of the backfill material. When it is applied, the volume is often contracted due to segregation, necessitating re-injection. In this study, it was manufactured a new lightweight foamed concrete by adding plasticizer and tested the engineering properties of the material. The tests included unconfined compressive strength test, unit weight test, flow test, pH test, and permeability test. The plasticizer is shown to have an important influence on the flow. It was shown that 2~2.4% of plasticizer was adequate. The new material was shown to have positive influence on the flow and reduction of weight when applied to the backfill of the structures.

Determination of Triacetin Contents in the Activated Carbon Filter (탄소복합필터의 triacetin 함량 분석)

  • Kim Soo-Ho;Ko Dongkyun;Kim Chung Ryul;Lee Dong-Wook;Shin Chang-Ho;Kim Jong-Yeol
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.68-74
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    • 2005
  • Glycerol triacetate(triacetin) is the currently used common plasticizer in the making filters from cellulose acetate tow. For the mono acetate filter, the determination of triacetin contents is already established by CORESTA recommended method (No. 59). But unfortunately, the analytical method of triacetin in the activated carbon filter have not reported so far. In this study, it was established the analytical method of carbon filter's triacetin contents at various extraction conditions, bath ratio and internal standard materials. The confidential level appeared above $95\%$ when the extraction time, ISTD material and bath ratio was 3 hours, tripropionin and below 500 mg activated carbon / 50 $m\ell$ ethanol, respectively. Also, in the distribution of triacetin with filter materials in activated carbon filters, the triacetin amount was the most contained in activated carbon. Therefore, this method can be applied to the determination of triacetin contents in the activated carbon filter.

Preparation of Coated-Wire Nitrate Ion Selective Electrode and its Application for Environmental Analysis (질산이온 선택성 피복선 전극의 제작 및 환경분석에의 응용)

  • 李龍根;金昌圭;朴廷泰;金京燮;黃圭子
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.99-107
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    • 1985
  • A coated wire ion selective electrode for nitrate (nitrate-CWE_ was constructed using epoxy resin, ion exchanger and plasticizer as a polymer membrane. It's stility, the composition of a polymer membrane, the response characteristics, the selectivity were examined and applied to the environmental analysis. The nitrate-CWE was prepared using a copper wire, wihch was coated with epoxy resin being incorporated with the nitrate ion exchanger and plasticizer. The best composition of the polymer membrane for the nitrate-CWE was obtained by mixing epoxy resin, ion exchanger and plasticizer in the ratio of 2:1:0.4. The potential (56.3$\pm$0.5 mV) of stick form nitrate-CWE in this composition was close to that (59.2 mV) of Nernstian response. The detection limit for nitrate ion were found to the about $6 \times 10^{-5}M$ and the useful pH was 2.5 $\sim$ 10.3. Furthermore, the selectivity of iodide and perchrorate for the nitrage-CWE was also much improved compared with that for a liquid membrane nitrate electrode. The nitrate-CWE was used to determind $NO_x$ in stack gas. The results were in good agreement with those obtained either by electrode method or by the improved NEDA method within a relative error of 4.0%.

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