• Title/Summary/Keyword: plasma chemistry

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Inhibitions of $H^+$-ATPases and Ion Channels by Lanthanum

  • Kim, Young-Kee;Cho, Kwang-Hyun;Park, Soo-Jin
    • Proceedings of the Korean Biophysical Society Conference
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    • 2001.06a
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    • pp.39-39
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    • 2001
  • Many physiological processes of plant cells, such as nutrient uptake, salt tolerance, and cell enlargement, are mediated by ion transports across the plasma membrane. H$^{+}$-ATPases on both plasma and vacuolar membranes play major roles on active transports and ion channels mediate passive transports of various ions. It has been known that these proteins involved in cellular osmotic regulation and salt tolerance in the salt-accumulated soils.(omitted)

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Fabrication and Electrochemical Characterization of Carbon Fluoride-based Lithium-Ion Primary Batteries with Improved Rate Performance Using Oxygen Plasma (산소 플라즈마를 이용하여 율속 성능이 개선된 불화탄소 기반 리튬 일차전지의 제조 및 전기 화학적 특성)

  • Seoyeong Cheon;Naeun Ha;Chaehun Lim;Seongjae Myeong;In Woo Lee;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.534-540
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    • 2023
  • The high-rate performance is limited by several factors, such as polarization generation, low electrical conductivity, low surface energy, and low electrolyte permeability of CFX, which is widely used as a cathode active material in the lithium primary battery. Therefore, in this study, we aimed to improve the battery performance by using carbon fluoride modified by surface treatment using oxygen plasma as a cathode for lithium primary batteries. Through XPS and XRD analysis, changes in the surface chemical characteristics and crystal structure of CFX modified by oxygen plasma treatment were analyzed, and accordingly, the electrochemical characteristics of lithium-ion primary batteries were analyzed and discussed. As a result, the highest number of semi-ionic C-F bonds were formed under the oxygen plasma treatment condition (7.5 minutes) with the lowest fluorine to carbon (F/C) ratio. In addition, the primary cell prepared under this condition using carbon fluoride as the active material of the cathode showed the highest 3 F/C(3 C rate-performance) rate-performance and maintained a relatively high capacity (550 mAh/g) even at high rates. In this study, it was possible to produce lithium primary batteries with high-rate performance by adjusting the fluorine contents of carbon fluoride and the type of carbon-fluorine bonding through oxygen plasma treatment.

Effect of Terbufos on the Activity of Acetylcholinesterase in the Chicken (Terbufos가 병아리 중(中) Acetylcholinesterase에 미치는 영향(影響))

  • Hong, Jong-Uck;Kim, Jung-Ho;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.29 no.3
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    • pp.324-330
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    • 1986
  • The responses of brain acetylcholinesterase(Ach-E) and plasma cholinesterase (Ch-E) activities were studied in chicknes given oral doses of Terbufos(S-tert-butyl thiomethyl 0,0-diethyl phosphorodithioate), an organophosphorus insecticide. The acute oral $LD_{50}$ of terbufos was 1.82mg/kg. The activity of plasma Ch-E was inhibited more rapidly than that of brain Ach-E, whereas recovery of plasma Ch-E activity was more rapid than that of brain Ach-E. Recovery of brain Ach-E and plasma Ch-E was followed the model $Y=a+b(log_{10}X)$. Brain Ach-E activity and plasma Ch-E were inhibited 83% and 94%, respectively, at 60min after administered oral $LD_{50}$. Brain Ach-E and plasma Ch-E was inhibited in vitro by Terbufos

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Effects of Transverse Magnetic Field on Laser-produced Carbon Plasma Plume in Nitrogen Atmosphere

  • Nam, Sang-Hwan;Ko, Min-Jung;Lee, Mi-Ae;Park, Hye-Sun;Song, Jae-Kyu;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.28 no.5
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    • pp.767-771
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    • 2007
  • By adopting a time-resolved optical emission spectrometry, we have investigated the effects of transverse magnetic field on C2 and CN molecules produced by laser ablation of a graphite target in nitrogen atmosphere. We found that the spectroscopic temperatures of both species, obtained via simulation of the optical emission spectra, as well as their emission intensities from the electronically excited states increased significantly in the presence of a magnetic field. The cyclotron radii and frequencies for electrons and ions were estimated to explain the increase in the number of collisions in the laser-produced carbon plasma plume under a magnetic field.

Gradual modification of Nanoimprint Patterns by Oxygen Plasma Treatment

  • Kim, Soohyun;Kim, Da Sol;Park, Dae Keun;Yun, Kum-Hee;Jeong, Mira;Lee, Jae Jong;Yun, Wan Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.233-233
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    • 2015
  • We report on a simple method for inducing physical and chemical property-gradient on nanoimprinted patterns by intensity-regulated plasma treatment under caved sample stage. As for the size gradient, a line pattern having a linewidth of 294.9 nm was etched to have gradually varying width from 277.4 nm to 147.9 nm. Modified pattern was proven to be adaptable to replica stamp for reversal patterning. To investigate the wettability gradient, imprinted nanopatterns were coated with fluoroalkylsilane to increase the hydrophobicity, and the surface was modified to have gradually varying wettability from hydrophobic to hydrophilic (contact angle was ${\sim}160^{\circ}$ to ${\sim}5^{\circ}$ on a single chip). This method is expected to be applicable to the selective adsorption of biological entities and hydrodynamic manipulation of liquid droplets for the pumpless microfluidics.

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Effects of Oxygen Functional Groups introduced onto Activated Carbon Fibers on Gas Sensing Property of Chemical Warfare Agent (활성탄소섬유에 도입된 산소작용기가 유독성 화학작용제 감응특성에 미치는 영향)

  • Kim, Su Hyun;Kim, Min-Ji;Song, Eun Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.719-725
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    • 2019
  • In this study, activated carbon fibers were treated with oxygen plasma to investigate gas sensing properties of the dimethyl methylphosphonate (DMMP), which is a simulant gas of the chemical warfare agent, according to oxygen functional group contents. As the flow rate of oxygen plasma treatment increased, oxygen groups were introduced to the surface of activated carbon fibers from 6.90 up to 36.6%, increasing the -OH group which influences the DMMP gas sensing properties. However, as the flow rate of oxygen plasma increases, the specific surface area tends to decrease because etching on the surface of activated carbon fibers occurs due to active species generated during the oxygen plasma treatment. The resistance change rate of the DMMP gas sensor increased from 4.2 up to 25.1% as the oxygen plasma treatment flow rate increased. This is attributed to the hydrogen bonding between DMMP gas and introduced hydroxyl functional group on activated carbon fibers by the oxygen plasma treatment. Therefore, the oxygen plasma is considered to be one of the important surface treatment methods for detecting chemical warfare agents at room temperature.

Cesium Ions Adsorption of Activated Carbon Treated by Oxygen Plasma (산소 플라즈마 처리된 활성탄소의 세슘 이온 흡착)

  • Ha, Seongmin;Kwak, Cheol Hwan;Lim, Chaehun;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.38-43
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    • 2022
  • The effect of introducing oxygen functional groups by oxygen plasma treatment of activated carbon on adsorption properties of cesium ions was investigated. During the oxygen plasma treatment, the frequency, power, and oxygen gas flow rates were fixed at 100 kHz, 80 W, and 60 sccm, respectively, while the reaction time was varied. Under the experimental conditions, the amount of cesium ion adsorption increased as the content of oxygen groups on C-O-C and O=C-O bonds increased when the reaction time with oxygen gas was 10 minutes. However, when the reaction time increased to 15 minutes, the oxygen functional group content decreased resulting in the decrease of the adsorbed cesium ion amount. On the other hand, unlike the oxygen content of the surface-treated activated carbon, the specific surface area and pore properties were hardly affected by the oxygen plasma reaction time. As a result, the oxygen plasma-treated activated carbon improved the cesium ion removal rate by up to 97.3% compared to that of the untreated activated carbon. This is considered to be due to the content of oxygen groups on C-O-C and O=C-O bonds introduced on the surface of the activated carbon through oxygen plasma treatment.

TiB2-Cu Interpenetrating Phase Composites Produced by Spark-plasma Sintering

  • Kwon, Young-Soon;V. Dudina, Dina;I. Lomovsky, Oleg;A. Korchagin, Michail;Kim, Ji-Soon
    • Journal of Powder Materials
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    • v.10 no.3
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    • pp.168-171
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    • 2003
  • Interpenetrating phase composites of $TiB_2$-Cu system were produced via Spark-Plasma Sintering (SPS) oi nanocomposite powders. Under simultaneous action of pressure, temperature and electric current titanium diboride nanoparticles distributed in copper matrix move, agglomerate and form a fine-grained skeleton. Increasing SPS-temperature and he]ding time promote densification due to local melting of copper matrix When copper melting is avoided the compacts contain 17-20% porosity but titanium diboride skeleton is still formed representing the feature of SPS . High degree of densification and formation of titanium diboride network result in increased hardness of high-temperature SPS-compacts.

섬유의 Plasma 가공(I) -plasma 처리화학-

  • 광진민박;조환
    • Textile Coloration and Finishing
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    • v.3 no.3
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    • pp.44-56
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    • 1991
  • 진공하에서 일어나는 glow 방전을 이용해서 행하는 plasma 반응은, 표면 특이적(Surface specific)인, 또는 비파괴적인 처리공정(Non-destructive process) 으로서 주목되고 있는 기술이다. 전반은 plasma chemistry로서, 섬유가공의 기초가 되는 plasma를 이용한 반응에 대하여 정리한다. 또 다음 후반에는 섬유가공에 관한 응용예에 대해서, 특히, 최근 실용화를 이룩하고 있는 일본에 있어서의 plasma 응용의 연구개발들, polyester 섬유염색물의 농색화가공, 양모직물의 방축가공 등의 기술동향 및 실용화를 위한 장치개발 등을 소개코자 한다.

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