• Corrosion Science and Technology
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• v.16 no.2
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• pp.49-58
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• 2017

Many research efforts on the effect of nitrogen on the corrosion resistance of stainless steels have been reported, but little research has been conducted on the effect of nitrogen for the weldment of stainless steels by the seal-weld method. Therefore, this work focused on the determining the corrosion resistance of tube/tube sheet mock-up specimen for sea water condensers, and elucidating the effect of shielding nitrogen gas on its resistance. The pitting corrosion of autogenously welded specimen propagated preferentially along the dendritic structure. Regardless of the percent of shielding nitrogen gas, the analyzed nitrogen contents were very much lower than that of the bulk specimen. This can be arisen because the nitrogen in shielding gas may partly dissolve into the weldment, but simultaneously during the welding process, nitrogen in the alloy may escape into the atmosphere. However, the pitting resistance equivalent number (PREN) of the interdendrite area was higher than that of the dendrite arm, regardless of the shielding gas percent; and the PREN of the interdendrite area was higher than that of the base metal; the PREN of the dendrite arm was lower than that of the base metal because of the formation of (Cr, Mo) rich phases by welding.

• Journal of Korea Foundry Society
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• v.43 no.5
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• pp.230-240
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• 2023

The pitting corrosion behavior of 329LD cast lean duplex stainless steel and CF3M cast austenitic stainless steel was investigated in chloride environments. The pitting corrosion resistance of the 329LD alloy was superior to that of the CF3M alloy because the pitting potential, passive region, and critical pitting temperature of the low Ni-low Mo 329LD alloy were higher than those of the high Ni-medium Mo commercial CF3M alloy. There are two main reasons for the enhancement of the pitting corrosion resistance of high Cr-low Momedium N 329LD alloy compared to the low Cr-medium Mo CF3M alloy: First, the pitting resistance equivalent number (PREN_δ+γ) value of the 329LD alloy is higher than that of the CF3M alloy. Second, the passive region of the 329LD alloy is larger than that of the CF3M alloy. It indicates that the synergistic effect of the three elements by adding high Cr and low Mo-medium N to the 329LD alloy enhances the passivity of the passive film, thereby increasing the pitting corrosion resistance. It was verified that based on the PREN_γ of austenite (γ) and PREN_δ of ferrite (δ) values calculated using an N-factor of 16, the pitting corrosion of the 329LD alloy was selectively initiated at the γ-phases because PREN_γ value of austenite (γ) was smaller than that of ferrite (δ), and finally propagated from the γ-phase to the δ-phase.

• Journal of the Korean institute of surface engineering
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• v.37 no.2
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• pp.128-136
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• 2004

Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.21 no.2
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• pp.283-289
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• 2012

Cam rack pinion (CRP) system which consists of cam rack and roller pinion transforms the rotation motion into linear one. The roller pinion has the plurality of rollers and meshes with its conjugated cam rack. The exact tooth profile of the cam rack and the non-undercut condition to satisfy the required performance have been proposed by introducing the profile shift coefficient. The load stress factors are investigated by varying the shape design parameters to predict the gear surface fatigue limit which is strongly related to the gear noise and vibration at the contact patch. The results show that the pitting life can be extended significantly by increasing the profile shift coefficient.

• Tribology and Lubricants
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• v.16 no.1
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• pp.9-14
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• 2000

It has been cleared in previous author's paper that the fatigue life before the pitting on the rolling contact surface with lubricant are influenced by the wear amount. In this study, the wear type has been clarified when wear amount is extremely large such as the case without lubricant. The test of rolling contact fatigue has been conducted under two different of herzian pressures and three different of slide ratios without lubricant. In addition, residual stress and half-value breadth using X-ray diffraction on worn surface have been measured as well as the wear amount. The results show that the pitting type wear by rolling contact fatigue has not been occurred when the wear amount is considerably large. Thus this type of wear has been deduced by the fatigue wear depending on delamination theory.

• Journal of Welding and Joining
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• v.4 no.3
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• pp.58-71
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• 1986

Mechanical and corrosion property of duplex stainless steel weldments made by the GTAW and SMAW process were studied. Fracture toughness, general and local corrosion resistance of GTAW and SMAW weldments were evaluated in terms of Charpy V notch impact test, anodic polarization diagram, pitting corrosion rate, respectively. SMA weld metal showed much lower impact toughness and higher ductile-brittle transition temperature than GTA weld metal. Fractographic and EDX analysis on fracture surface of SMA weld metal demonstrated the existence of (Si, Ti), oxide in large amounts. Potentiodynamic anodic polarization diagram of GMA weld metal showed much lower passive current density than SMA weld metal in 4% $H_2/SO_4$ solution. And pitting corrosion rate test showed the same tendency. Relating the microstructure, chemistry and property, it can be concluded that GTA weld metal gives better toughness due to lower oxygen content, i.e. lower inclusion content, and better corrosion resistance due to higher Pitting Index(PI) than SMA weld metal.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.11
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• pp.1759-1766
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• 2001

Vibration transient generated by developing localized fault in gear can be used as indicators in gear fault detection. In this paper, we propose the zoomed phase map for a fault signal using continuous wavelet transfers to detect this vibration transient. Local fault induces the abrupt fluctuation of load exciting tooth and phase lag in the vibration signal measured on the gearbox. The relatively large fault like "tip breakage" easily can be detected by the clear fluctuation of exciting load. However, minor fault like "initial pitting"cannot be detected using the load fluctuation. To defect this kind of minor fault, the phase map for a fault signal is taken into account. The phase lag by minor fault is observed well in the zoomed phase map.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.23 no.7 s.166
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• pp.1231-1237
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• 1999

Applying the conjugate contact condition, contact lines of a cylindrical worm gear has been calculated. The characteristics of tooth contact were analyzed and the pitting resistance were also assessed. It has been verified that: i) the length of contact is shortest on the 1st tooth of the front region, ii) the contact region is more narrow in the recess side than in the access side, iii) the contact region is more narrow in worm than in worm wheel. Hence, the pitting resistance is weakest in the recess side of the 1st contacting worm tooth.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.1
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• pp.84-94
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• 2007

As a reactor coolant pump(RCP) is operated in the nuclear power system for a long time. so its surface is continuously contaminated by radioactive scales. In order to perform regular or emergency repair about RCP internals a special decontamination process should be used to reduce the radiation from the RCP surface by means of chemical cleaning. In this study, applicable possibility in chemical decontamination for RCP was investigated on the various materials. The STS 304 showed the best electrochemical properties for corrosion resistance than other materials. However, the pitting corrosion was slightly generated in both STS 415 and STS 431 with the increasing numbers of cycle and intergranular corrosion were sporadically observed. The size of their pitting corrosion and intergranular corrosion were also increased with increasing cycle numbers.

• Corrosion Science and Technology
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• v.5 no.6
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• pp.189-195
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• 2006

Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.