• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.297.2-297.2
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• 2013

Scavenging electricity from wasteful energy resources is currently an important issue and piezoelectric nanogenerators (NGs) based on zinc oxide (ZnO) are promising energy harvesters that can be adapted to various portable, wearable, self-powered electronic devices. Although ZnO has several advantages for NGs, the piezoelectric semiconductor material ZnO generate an intrinsic piezoelectric potential of a few volts as a result of its mechanical deformation. As grown, ZnO is usually n-type, a property that was historically ascribed to native defects. Oxygen vacancies (Vo) that work as donors exist in ZnO thin film and usually screen some parts of the piezoelectric potential. Consequently, the ZnO NGs' piezoelectric power cannot reach to its theoretical value, and thus decreasing the effect from Vo is essential. In the present study, c-axis oriented insulator-like sputtered ZnO thin films were grown in various temperatures to fabricate an optimized nanogenerator (NGs). The purity and crystalinity of ZnO were investigated with photoluminescence (PL). Moreover, by introducing a p-type polymer usually used in organic solar cell, it was discussed how piezoelectric passivation effect works in ZnO thin films having different types of defects. Prepared ZnO thin films have both Zn vacancies (accepter like) and oxygen vacancies (donor like). It generates output voltage 20 time lager than n-type dominant semiconducting ZnO thin film without p-type polymer conjugating. The enhancement is due to the internal accepter like point defects, zinc vacancies (VZn). When the more VZn concentration increases, the more chances to prevent piezoelectric potential screening effects are occurred, consequently, the output voltage is enhanced. Moreover, by passivating remained effective oxygen vacancies by p-type polymers, we demonstrated further power enhancement.

• Proceedings of the KSME Conference
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• 2000.11a
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• pp.426-431
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• 2000

A decoupled thermo-piezoelectric-mechanical model of composite laminates with surface bonded piezoelectric actuators, subjected to externally applied load, temperature change load, electric field load is developed. The governing differential equations are obtained by applying the principle of free energy and variational techniques. A higher order zigzag theory displacement field is employed to accurately capture the transverse shear and normal effects in laminated composite plates of arbitrary thickness.

• Smart Structures and Systems
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• v.20 no.5
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• pp.573-581
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• 2017

A vibrating double-layered nanoscale piezoelectric plate is developed accounting for the flexoelectricity and surface effects. The flexoelectricity is due to the coupling between electrical polarization and strain gradient. Applying Hamilton's principle, the governing equations and related boundary conditions are derived. Assuming suitable approximate functions, the governing equations are numerically solved for simply-supported and clamped boundary conditions. Obtained results indicate that both the flexoelectricity and surface effects possess notable impact on the vibration frequencies of the system. Only flexoelectricity yields a considerable difference between the present model and previous investigations on conventional piezoelectric nanoplates. Generally, a parametric study has been performed to examine the effects of surface elasticity, flexoelectricity, applied electric voltage, interlayer stiffness, geometrical parameters and boundary conditions on vibration frequencies of piezoelectric nanoplates.

• Korean Journal of Materials Research
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• v.14 no.5
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• pp.334-337
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• 2004

Perovskite PMN-PZT-based ceramics were prepared and the$ MnO_2$ doping effects on their piezoelectric properties were investigated. Grain size decreased with increasing the $MnO_2$ content, and the pyrochlore phase was not identified in the sintered PMN-PZT ceramics with 0.01～1.0wt% $MnO_2$. Piezoelectric voltage and charge constants were reduced and mechanical quality factor increased with increasing the $MnO_2$ content. However, electromechanical coupling coefficient slightly decreased with increasing the MnO$_2$ content without regard to the grain size.

• Structural Engineering and Mechanics
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• v.69 no.2
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• pp.121-129
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• 2019

The present study investigates the propagation of shear waves in a composite structure comprised of imperfectly bonded piezoelectric layer with a micropolar half space. Piezoelectric layer is considered to be initially stressed. Micropolar theory of elasticity has been employed which is most suitable to explain the size effects on small length scale. The general dispersion equations for the existence of waves in the coupled structure are obtained analytically in the closed form. Some particular cases have been discussed and in one particular case the dispersion relation is in well agreement to the classical-Love wave equation. The effects of various parameters viz. initial stress, interfacial imperfection and micropolarity on the phase velocity are obtained for electrically open and mechanically free system. Numerical computations are carried out and results are depicted graphically to illustrate the utility of the problem. The phase velocity of the shear waves is found to be influenced by initial stress, interface imperfection and the presence of micropolarity in the elastic half space. The theoretical results obtained are useful for the design of high performance surface acoustic devices.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.34 no.6
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• pp.487-494
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• 2021

Piezoelectric generators use direct piezoelectric effects that convert mechanical energy into electrical energy. Many studies were attempted to fabricate piezoelectric generators using piezoelectrics such as ZnO, PZT, PVDF. However, these various inorganic/organic piezoelectric materials are not suitable for bio-implantable devices due to problems such as brittleness, toxicity, bio-incompatibility, bio-degradation. Thus, in this paper, piezoelectric generators were prepared using a silk fibroin film which is bio-compatible by dip-coating method. The silk fibroin films are a mixed state of silk I and silk II having stable β-sheet type structures and shows the d₃₃ value of 8~10 pC/N. There was a difference in output voltages according to the thickness. The silk fibroin generators, coated 10 times and 20 times, revealed the power density of 16.07 μW/cm² and 35.31 μW/cm² using pushing tester, respectively. The silk fibroin generators are sensitive to various pressure levels, which may arise from body motions such as finger tapping, foot pressing, wrist shaking, etc. The silk fibroin piezoelectric generators with bio-compatibility shows the applicability as a low-power implantable piezoelectric generator, healthcare monitoring service, and biotherapy devices.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.3
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• pp.289-293
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• 2004

PNW-PMN-PZT ceramics were fabricated with the variations of Nb$_2$O$_{5}$ addition and their microstructural and piezoelectric characteristics were investigated. When the amount of Nb$_2$O$_{5}$ increased, grain size decreased gradually. At 0.3wt％ Nb$_2$O$_{5}$ which is the same weight percent with Fe$_2$O$_3$, maximum tetragonality(c/a) and density were shown due to the complexed doping effects. Also, this composition that showed Qm of 2,041, kp of 0.55, grain size of 2.5${\mu}{\textrm}{m}$ and $\varepsilon$r of 1704 were proper for high power application. Using this composition, Rosen-type piezoelectric transformer was fabricated as the size of 1 ${\times}$ 16 ${\times}$ 5㎣ and its electrical characteristics were investigated with the variations of load resistance and driving frequency. At the resistance of 200㏀, maximum step-up ratio of 13.68 was shown. After driving PDA CCFL for 25 min using the inverter circuit, at driving frequency of 214.4KHz, input voltage of 31.78 V and input current of 21.1mA were measured at the input part of piezoelectric transformer. And then, output voltage of 293.2 V and output current of 2.2mA were shown at the output part of piezoelectric transformer. At the same time, efficiency of 96.2％ and temperature rise of 3.5$^{\circ}C$ were appeared at the piezoelectric transformer.ormer.

• Korean Journal of Materials Research
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• v.15 no.12
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• pp.756-759
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• 2005

A lead free piezoelectric material, bismuth sodium barium titanate $(Bi_{0.5}Na_{0.5})_{0.94}Ba_{0.06}TiO_3$ (BNBT), was considered as an environment-friendly alternatives for the current PZT system. A perovskite BNBT was synthesized by conventional bulk ceramic processing technique. In order to improve piezoelectric properties, $La_2O_3$ as a dopant was incorporated into the BNBT system up to 0.025 moi, ana the effects on subsequent the piezoelectric ana dielectric properties were systematically investigated. With increasing $La_2O_3$ contents, the equilibrium grain shape was remarkably evidenced and sintered density was increased. Piezoelectric and dielectric properties were s]town to have maximum values at the $La_2O_3$ contents of 0.02 mol. $La^{3+}$ ions seemed to act as a softener in the BNBT system and to enhance dielectric and piezoelectric properties in this study.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.4
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• pp.289-296
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• 2001

The piezoelectric transformers of 2.0x10x48 ㎣ size were fabricated with PSN-PMN-PZT(T10 and PNW-PMN-PZT(T2) composition ceramics. Effects of micro structural and piezoelectric properties on the electrical characteristics of the piezoelectric transformers were investigated. Under the fixed output power of 6 W, temperature rise of T1 transformer at the optimum load was smaller than T2 one because of fine grain size effect. Voltage step-up ratio of T1 transformer showed higher value than T2 one T1 transformer showed an excellent properties with voltage step-up ratio of 12.41, efficiency of 95.23% and temperature rise of 7.2$^{\circ}C$ at 200㏀ load resistance. And also, T2 transformer showed an excellent properties with voltage step up ratio of 9.81, efficiency of 95.51% and temperature rise of 9$^{\circ}C$ at 150㏀ load resistance.

• Journal of KSNVE
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• v.8 no.2
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• pp.267-273
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• 1998

This study aims at performing sensitivity analysis of piezoelectric smart structure for minimizing radiated noise from the structure, The structure consists of a flat plate on which disk shaped piezoelectric actuator is mounted, and finite element modeling is used for the structure. The finite element modeling uses a combination of three dimensional piezoelectric, flat shell and transition elements so thus it can take into account the coupling effects of the piezoelectric device precisely and it can also reduce the degrees of freedom of the finite element model. Electric potential on the piezoelectric actuator is taken as a design variable and total radiated power of the structure is chosen as an objective function. The objective function can be represented as Rayleigh's integral equation and is a function of normal displacements of the structure. For the convenience of computation, all degrees of freedom of the finite element equation is condensed out except the normal displacements of the structure. To perform the design sensitivity analysis, the derivative of the objective function with respect to the normal displacements is found, and the derivative of the norma displacements with respect to the design variable is calculated from the finite element equation by using so called the adjoint variable method. The analysis results are compared with those of the finite difference method, and shows a good agreement. This sensitivity analysis is faster and more accurate than the finite difference method. Once the sensitivity analysis program is used for gradient-based optimizations, one could achieve a better convergence rate than non-derivative methods for optimal design of piezoelectric smart structures.