• Title/Summary/Keyword: physicochemical factor

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Air-Soil Partitioning of PCBs in Rural Area

  • Yeo, Hyun-Gu;Park, Min-Kyu;Chun, Man-Young;Young, Sun-Woo
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E1
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    • pp.1-9
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    • 2003
  • The soil concentrations of polychlorinated biphenyls (PCBs) were measured at 12 sites in Ansung, Kyonggi province, Korea. Correlation coefficient (r) between total PCBs and organic matter content (OM) was significant (r=0.562, p< 0.05). It suggests that organic matter may be a key factor of soil absorption of PCBs. The PCB concentrations of low chlorinated congeners with high vapor pressure were relatively abundant in air but high chlorinated congeners with low vapor pressure were mainly dominated by soil. The results indicated the influence of physicochemical properties of PCBs such as vapor pressure, octanol - air partition coefficient ( $K_{OA}$ ). The calculated soil/air fugacity quotients suggested that the soil may be a source of heavier molecular PCBs (>penta-CBs) to the atmosphere, where lighter molecular PCBs appear to be affected by a movement from air to soil, especially tetra-CBs. Therefore, PCB homologs with low vapor pressure might have been influenced by revolatilization from soil.

A Theoretical Study for the Formulation Design of PBX(I) (복합화약 조성설계에서의 이론적 연구(I))

  • Shim, Jung-Seob;Kim, Hyoun-Soo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.2
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    • pp.109-115
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    • 2008
  • A Plastic Bonded Explosive(PBX) is mainly composed of nitramine explosive and polymer binder. The great number of serious applications of PBX requires the good adhesion between nitramine crystals and binder, which depends on the surface characteristics of a filler and binder. In the pursuit of the better design to achieve the enhanced adhesion, profound knowledge of the surface and interfacial characteristics of explosive and binder should be exploited. In this study, the influences of physicochemical properties between RDX and binders such as interfacial tension($\gamma_{SL}$), latent heat($Q_m$), and density($\rho$) on impact sensitivity of PBX were investigated. As experimental results, the major contribution factor to impact sensitivity of PBX was the interfacial tension, compare with other surface properties. The correlation coefficient of $H_{50}$ versus $\gamma_{SL}$ is 0.9932 when a polynomial regression method was used.

Changes on the Physicochemical Factor of Stream Water by Medium and Small type Fish Farm in Mt. Baegun Area (백운산 지역내 중소형 양어장에 의한 계류수의 이화학적 요인의 변화)

  • Park, Jae-Hyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.8 no.3
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    • pp.43-52
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    • 2005
  • Evaluations of the fish farm influences on stream water quality may provide basic informations on watershed management to reduce environmental impact due to fish farm development and to conserve stream water quality in forested watershed area. In this research influent, effluent water in the fish farm and stream water qualities around Mt. Baegun area were monitored seasonally for six years and the following results were obtained. Due to the increase of pH in effluent water from the fish farm it was believed that alkalization of stream water can be accelerated by large scale development of fish farms in the forested watershed area. Also, effluent water from the fish farm increase of EC higher than influent and stream water. As a result of regression analyses, pH, EC, DO, water temperature, total amount of cation and anion in influent and effluent water of fish farm show high significance.

Physicochemical properties on the quality evaluation of Citrus unshiu produced in Cheju (제주산 보통온주의 품질특성)

  • Go, Jeong-Sam;Yang, Yeong-Taek;Song, Eun-Yeong
    • Food Science and Preservation
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    • v.2 no.2
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    • pp.251-257
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    • 1995
  • In order to determine the quality of Citrus unshiu(medium cultivar of satsuma mandarin) produced in Cheju, citrus fruits sampled at sorting places and harvested directly on citrus tree in south and north area of Cheju were analyzed. The fruits were grown in size till early of November, and soluble solids were increased continuously after that. Compared with the quality of citrus fruits as a factor of soluble solids, firmness, total sugar, pH, and color index, the optimum harvest periods were supposed to be reasonable from early of December for C. unshiu Marc. var. yonezawa and C. unshiu Marc. var. hayashi, Fruit weights and peel thickness had a linear correlation with increasing fruit size, but soluble solids and acid contents had not a correlation. The selection of C. unshiu variety was needed to determine by the properties of storage.

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Absorption of Methyl Mercaptan into Aqueous Diethanolamine Solutions (Diethanolamine 수용액에서의 Methyl Mercaptan의 흡수)

  • Park Moon-Ki
    • Journal of Environmental Science International
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    • v.14 no.12
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    • pp.1177-1183
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    • 2005
  • The kinetics of the reaction of methyl mercaptan into aqueous diethanolamine were studied over a range in temperature ($20^\~60{\circ}C$) and amine concentrations (0-40 $wt\%$) using a wetted-sphere absorber. The physicochemical properties needed to interpret the data are the solubility and diffusivity of methyl mercaptan in the aqueous diethanolamine solution. The density and the viscosity were obtained and correlated in the experimental range. The Wilke Chang equation was applied to estimate the diffusion coefficient. The enhancement factor was found to be high temperature is below than low temperature. It means the absorption rate with chemical reaction is lower than the physical absorption rate.

Morphological and Physicochemical Changes of NBKP by Alkali Pretreatment (알카리 전처리에 의한 NBKP의 형태학적 및 이화학적 변화)

  • Mun, Sung-Phil;Jang, Min-Hwan
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.4
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    • pp.58-64
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    • 2009
  • This study was carried out to prepare high porosity pulp for oil and air filter media from commercial grade NBKP with 6 - 20% NaOH treatment. The fiber width of NBKP remarkably decreased by NaOH pretreatment. The air permeability of the test sheet prepared from alkali-pretreated NBKP increased with increasing NaOH concentration up to 15%. The burst factor was greatly decreased by alkali pretreatment. By 15 - 20% NaOH pretreatment of NBKP, it could be possible to prepare a high porosity pulp. It seems that the high porosity of the pulp was due to a strong swelling and a great change of the cellulose crystalline lattice from cellulose I to cellulose II with NaOH treatment of NBKP. The study suggested that alkali- pretreated NBKP could be used for manufacturing oil and air filter media.

Status of Water Pollution of Gyeongan River, Korea (경안천의 오염현황)

  • Yi, Dong-Seok;Park, Kap-Song
    • Journal of Korean Society on Water Environment
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    • v.20 no.6
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    • pp.698-702
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    • 2004
  • At five stations in Gyeongan River, a tributary of Lake Paldang, physicochemical and biological environmental factors of water, particulate matters, and sediments were investigated biweekly from April 11 to December 22 in 2001. The studied area was characterized as a stream-lake system. The system is primarily referred to a place where the environmental factors had considerably changed depending on the amount of precipitation. As a result, the river turned out to be strongly eutrophicated. Also, some characteristics of the water and the particulate matters at midstream such as average concentrations of conductivity, nutrients, and chlorophyll $\alpha$ were higher than the characteristics of up and down-stream. However, the concentrations of organic matters and ratio of clay and silt of the midstream were determined to be higher than up and down-stream sediments. As the result of the factor analysis, 4 major different patterns for environmental factors are found from samples of water, particulate matters, and sediments.

Quality Attributes of Cookies Prepared with Tomato Powder

  • Chung, Hai-Jung
    • Preventive Nutrition and Food Science
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    • v.12 no.4
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    • pp.229-233
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    • 2007
  • This study was conducted to investigate the quality characteristics of cookies added with different levels of tomato powder. Cookies were prepared with five different levels of tomato powder (0, 2.5, 5.0, 7.5, and 10.0%) and the physicochemical properties were examined. The pH of cookie dough decreased significantly by the addition of tomato powder (p<0.05). Crude protein and ash content of the cookies containing 5.0, 7.5 and 10.0% tomato powder were significantly higher than those of control and those with 2.5% (p<0.05). The spread factor of control cookie was lower than that of cookies containing 5.0, 7.5, and 10.0% tomato powder. The incorporation of tomato powder in cookies lowered the lightness values but increased redness and yellowness values. Rheology testing showed that cookies with 5.0, 7.5, and 10.0% tomato powder had significantly lower hardness value than control. Sensory evaluation revealed that overall desirability scores were not significantly different between control and tomato powder added groups. Therefore, cookies with up to 10.0% added tomato powder would be as acceptable as control cookies without depressing cookie quality.

Quantitative Structure-Activity Relationship (QSAR) Study by Use of Theoretical Descriptors : Quinolone and Naphthyridine

  • Lee Keun Woo;Kim Hojing
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1070-1079
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    • 1994
  • Quantitative Structure-Activity Relationship (QSAR) studies are performed for the sets of 40 quinolones and 47 naphthyridines. Net charge, van der Waals volume, polarizability, and dipole moment are empolyed as theoretical descriptors(independent variables) to find the relationship between activity and physicochemical properties such as electrostatic effect, steric effect, and transferability. The results are analyzed by the regression and the factor analysis. It is found that for Gram-negative bacteria, the QSAR of quinolone and naphthyridine are substantially different: to describe the activity, the electrostatic effect is the most important for quinolone, and the steric effect and the transferability for naphthyridine.

Optimization of ${\beta}$-Glucanase-assisted Extraction of Starch from Domestic Waxy Barley and Its Physicochemical Properties (${\beta}$-Glucanase를 이용한 국내산 찰보리 전분 추출공정의 최적화 및 추출 전분의 주요 이화학적 특성에 관한 연구)

  • Jeong, Yong-Seon;Bae, Jae-Seok;Kim, Jeong-Won;Lee, Eui-Seok;Lee, Ki-Teak;Lee, Mi-Ja;Hong, Soon-Taek
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.6
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    • pp.789-798
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    • 2013
  • In the present study, optimization on ${\beta}$-glucanase-assisted extraction was made in order to isolate waxy barley starch from domestic cultivar using the D-optimal design suitable for response surface methodology (RSM). The results demonstrated that the amount of enzyme was found to be a major influencing factor on the extraction yield, which was substantially increased by increasing the amount of enzyme. It was also influenced by the reaction time and amount of water addition; however, the two factors were less influential than the amount of enzyme. The optimized condition by RSM for the reaction time was found to be 2.63 hours and amount of enzyme 1.7%, and amount of water addition 4.38 times the weight of raw material. With the enzyme treatment, the starch content in residues (R), particularly in R1 and R5, was reduced considerably, resulting in an increase in the extraction yield and therefore primarily and effectively releasing B-type starch small granule confirmed by scanning electronic microscopy. In addition, the study determined the physicochemical properties of isolated waxy starch (i.e., purity, water adsorption capacity, thermal properties, rheology and starch morphology) and compared them with those from the enzyme-not treated sample. It was found that they were almost similar to each other, except for the purity of starch, which was lower in the enzyme-treated sample than in the enzyme-not treated one.