• 제목/요약/키워드: physical and chemical effects

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Multiple Exposures and Coexposures to Occupational Hazards Among Agricultural Workers: A Systematic Review of Observational Studies

  • Nguyen, Thi-Hai-Yen;Bertin, Melanie;Bodin, Julie;Fouquet, Natacha;Bonvallot, Nathalie;Roquelaure, Yves
    • Safety and Health at Work
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    • 제9권3호
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    • pp.239-248
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    • 2018
  • Background: Workers may be exposed to various types of occupational hazards at the same time, potentially increasing the risk of adverse health outcomes. The aim of this review was to analyze the effects of multiple occupational exposures and coexposures to chemical, biomechanical, and physical hazards on adverse health outcomes among agricultural workers. Methods: Articles published in English between 1990 and 2015 were identified using five popular databases and two complementary sources. The quality of the included publications was assessed using the methodology developed by the Effective Public Health Practice Project assessment tool for quantitative studies. Results: Fifteen articles were included in the review. Multiple chemical exposures were significantly associated with an increased risk of respiratory diseases, cancer, and DNA and cytogenetic damage. Multiple physical exposures seemed to increase the risk of hearing loss, whereas coexposures to physical and biomechanical hazards were associated with an increased risk of musculoskeletal disorders among agricultural workers. Conclusion: Few studies have explored the impact of multiple occupational exposures on the health of agricultural workers. A very limited number of studies have investigated the effect of coexposures among biomechanical, physical, and chemical hazards on occupational health, which indicates a need for further research in this area.

과열증기처리에 의한 Burley종 각초의 물리성 및 연기성분 변화에 관한 연구 (Effect of Super Heated Steam Treatment on Physical Property and Smoke Component of Burley Cut Tobacco)

  • 김천석;안기영
    • 한국연초학회지
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    • 제17권2호
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    • pp.139-148
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    • 1995
  • This study was carried out to investigate the effects of super heated steam on the physical and chemical changes of burley cut tobacco. Total sugar, total alkaloid, ether extracts, crude ash, total nitrogen and pH for leaf chemical constituents were analyzed. Filling power and fineness index for physical properties, and carbonyl compounds, phenol compounds, amonia, pH, hydrogen cyanide nicotine, carbon monoxide, total volatile base and tar for smoke components were also analyzed. The cut tobacco treated with super heated steam showed significant decrease in total sugar and total alkaloid. The filling power of the sample treated with the super heated steam system was increased abruptly when heated at over 250℃. The fineness index showed similar tendency to that of common toast method. Super heated steam treatment slightly decreased carbonyl compounds, phenol compounds, hydrogen cyanide, nicotine, carbon monoxide and tar in the tobacco. Especially the decrease of ammonia was the most remarkable. The pH of smoke was a little different compared with that in the common toast. The sensory test results showed that, compared to the common conveyer moving system, the tobacco treated with super heated steam system brought out more roasted flavor, lowered impact, irritation, and sting, further improved aftertaste, and lowered bitterness. The super heated steam treatment method used in the studies is expected to give better filling power, mild taste and toasted odor of tobacco than that of the common method for toast treatment. Key words : burley tobacco, super heated steam, expansion, toast.

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암모니아 흡수식 열펌프의 Falling Film Type 흡수기에 대한 수학적 모델링 및 수치모사에 관한 연구 (Mathematical modeling and numerical simulation studies for falling film type absorber in ammonia absorption heat pump)

  • 이찬호;김성현;현재천
    • 청정기술
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    • 제7권2호
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    • pp.151-159
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    • 2001
  • 암모니아 흡수식 열펌프의 falling film type 흡수기에 대한 수학적 모델링 및 수치모사 연구를 수행하였다. 기존의 수학적 모델에 열역학적 물성을 온도의 함수로 적용하여 수치모사를 수행하였고 이로부터 얻은 결과를 실험결과와 비교함으로써 모델의 성능이 향상되는 것을 확인하였다. 그리고 개발된 모델을 이용하여 냉각수의 유량과 온도가 흡수기내에서 일어나는 열 및 물질전달에 미치는 영향을 평가하였다. 수치모사 결과로부터 냉각수 온도가 낮을수록 유량이 증가할수록 열 및 물질전달 효율이 증가하는 것을 알 수 있었다.

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벼 2모작 논에서 보릿짚 시용이 토양이화학성 및 양분흡수에 미치는 영향 (Effects of Barley Straw Application on Soil Physico-Chemical Properties and Nutrient Uptake in Rice Paddy Field of Double Cropping)

  • 류철현;양창휴;강승원;한상수;김성조
    • 한국토양비료학회지
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    • 제34권2호
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    • pp.110-116
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    • 2001
  • 벼 2모작 재배시 보릿짚시용후 질소시용량별 토양의 이화학적 변화와 수도체의 양분흡수량, 질소이용효율을 조사하기 위하여 2년간('97~'98) 전북통에서 시험한 결과는 다음과 같다. 보릿짚시용으로 경도, 용적밀도, 고상율이 낮아졌고 공극율과 기상율이 증가하여 토양의 물리성이 개선되었다. 보릿짚시용으로 벼 재배후 토양의 pH, OM, T-C, $SiO_2$, K, CEC가 증가한 반면 $P_2O_5$이 감소되었다. 보릿짚시용후 벼 재배시 토양중 $Fe^{+{+}}$함량은 분얼기~유수형성기까지 높은 함량을 보였으나 출수기에는 낮아졌고 $Mn^{+{+}}$함량은 증가되었다. 보릿짚시용시 수도체로의 시비질소 흡수량은 질소시용량 $126kg\;ha^{-1}$ 시용구까지는 증가하였으나 질소 $144kg\;ha^{-1}$ 시용구에서는 감소되었다. 또 질소시용량이 적을수록 보릿짚시용구에서 무시용구보다 시비질소 흡수기간이 길었다. 수도체로의 질소이용율은 분얼기에는 1% 전후였지만 최고분얼기부터 크게 증가하였고 보릿짚시용구에서 낮았다. 수도체로의 인산흡수량은 보릿짚시용구에서 질소시용량에 관계없이 모두 높았으나 칼리함량은 낮았다.

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Effects of Electron Beam Irradiation on Tribological and Physico-chemical Properties of Polyoxymethylene (POM-C) copolymer

  • ;;;;김민석
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.153-153
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    • 2016
  • Polyoxymethylene copolymer (POM-C) is an attractive and widely used engineering thermoplastic across many industrial sectors owing to outstanding physical, mechanical, self-lubricating and chemical properties. In this research work, the POM-C blocks were irradiated with 1 MeV electron beam energy in five doses (100, 200, 300, 500 and 700 KGy) in vacuum condition at room temperature. The tribological and physico-chemical properties of electron beam irradiated POM-C blocks have been analyzed using Pin on disk tribometer, Raman spectroscopy, SEM-EDS, Optical microscopy, 3D Nano surface profiler system and Contact angle analyzer. Electron beam irradiation at a dose of 100 kGy resulted in a decrease of the friction coefficient and wear loss of POM-C block due to well suited cross-linking, carbonization, free radicals formation and energetic electrons-atoms collisions (physical interaction). It also shows lowest surface roughness and highest water contact angle among all unirradiated and irradiated POM-C blocks. The irradiation doses at 200, 300, 500 and 700 kGy resulted in increase of the friction coefficient as compared to unirradiated POM-C block due to severe chain scission, chemical and physical structural degradation. The electron beam irradiation transferred the wear of unirradiated POM-C block from the abrasive wear, adhesive wear and scraping to mild scraping for the 1 MeV, 100 kGy irradiated POM-C block which is concluded from SEM-EDS and Optical microscopic observations. The degree of improvement for tribological attribute relies on the electron beam irradiation condition (energy and dose rate).

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폴리아크릴로니트릴/셀룰로오스 아세테이트/N,N-디메틸포름아미드 용액의 유연학적 특성 (The Rheological Properties of Poly(acrylonitrile)/Cellulose Acetate Blend Solutions in N,N-Dimethyl Formamide)

  • 박승한;송인규;김병철
    • 폴리머
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    • 제33권4호
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    • pp.384-388
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    • 2009
  • 폴리아크릴로니트릴(PAN)과 셀룰로오스 아세테이트(CA) 블렌드/디메틸포름아미드(DMF) 용액의 유변학적 특성을 온도와 블렌드 조성비에 대하여 조사하였다. 모든 고분자 용액이 온도 변화에 따라 매우 특징적인 유변학적 거동을 보였다. 8 wt% 용액의 경우 $20{\sim}60^{\circ}C$ 온도범위에서 온도의 증가와 더불어 용액의 점도가 증가하고 손실탄젠트값이 감소하였다. $20^{\circ}C$에서는 용액의 물성이 블렌드의 조성에 영향을 받았으나 40 및 $60^{\circ}C$에서는 조성비가 용액 물성에 미치는 영향이 크게 감소하였다. 더 높은 온도에서의 더 긴 분자 이완시간으로부터 온도가 증가함에 따라 분자간력에 의한 물리적 구조 형성이 촉진된다는 것을 알 수 있었다. 이러한 유변학적 특성에 대한 원인은 묽은 용액의 특성으로부터 유추할 수 있었다. 고분자 용액의 고유점도가 온도가 증가함에 따라 감소하였다.

A Review of Withering in the Processing of Black Tea

  • Deb, Saptashish;Jolvis Pou, K.R.
    • Journal of Biosystems Engineering
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    • 제41권4호
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    • pp.365-372
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    • 2016
  • Purpose: Tea is the most frequently consumed drink worldwide, next to water. About 75% of the total world tea production includes black tea, and withering is one of the major processing steps critical for the quality of black tea. There are two types of tea withering methods: physical and chemical withering. Withering can be achieved by using tat, tunnel, drum, and trough withering systems. Of these, the trough withering system is the most commonly used. This study focuses on the different types of withering, their effect on the various quality attributes of tea, and other aspects of withering methods that affect superior quality tea. Results: During physical withering, tea shoots loose moisture content that drops from approximately 70-80% to 60-70% (wet basis). This leads to increased sap concentration in tea leaf cells, and turgid leaves become flaccid. It also prevents tea shoots from damage during maceration or rolling. During chemical withering, complex chemical compounds break down into simpler ones volatile flavor compounds, amino acids, and simple sugars are formed. Withering increases enzymatic activities as well as the concentration of caffeine. Research indicates that about 15% of chlorophyll degradation occurs during withering. It is also reported that during withering lipids break down into simpler compounds and catechin levels decrease. Improper withering can cause adverse effects on subsequent manufacturing operations, such as maceration, rolling, fermentation, drying, and tea storage. Conclusion: Freshly harvested leaves are conditioned physically and chemically for subsequent processing. There is no specified withering duration, but 14-18 h is generally considered the optimum period. Proper and even withering of tea shoots greatly depends on the standards of plucking, handling, transportation, environmental conditions, time, and temperature. Thus, to ensure consumption of high quality tea, the withering step must be monitored carefully.

pH Effects of Electroless Ni Plating on ABS Plastics

  • Song, T.H.;Lee, J.K.;Ryoo, K.K.;Lee, Y.B.
    • Corrosion Science and Technology
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    • 제3권1호
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    • pp.26-29
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    • 2004
  • Metal plated plastics are becoming more prevalent in materials of communication parts. A new technique MmSH is a process of injecting plastics to produce innovated physical properties compared to the conventional injection process. This study involves two ways of coating plastics Ni by electroless plating and varying bath and plasma treatment for improved adhesion strength between plating layer and surface. MmSH injection processed ASS with plasma treated after neutralization showed a superior adhesion force and a gloss and rate of deposition when it was in pH 7.5. On the other hand, conventional injection processed ASS was in pH 6.5.

Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings

  • Yoo, Gyu-Yeol;Kim, Ji-Hyun;Park, Hong-Soo;Kim, Young-Geun;Kim, Seong-Kil
    • 한국응용과학기술학회지
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    • 제25권1호
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    • pp.1-14
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    • 2008
  • To prepare weather-resistant modified silane acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The composition of monomers was adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects on weatherability were examined. The presence of MPTS in modified silane acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the modified silane acrylic resins containing 30 wt% of MPTS had superior weathering properties.

시멘트의 특성과 사용 온도가 모르터의 물성에 미치는 영향 (Effects of Portland Cement Characters and Working Temperature on the Physical Properties of Cement Mortars)

  • 김원기;김창은
    • 한국세라믹학회지
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    • 제37권5호
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    • pp.410-417
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    • 2000
  • In this study the effects of specifics surface area of cement, addition amount of gypsum and substitution ratio of gypsum anhydrite ont he physical properties of cement mortars were investigated by measruements of setting time, flow, compressive strength and hydration heat evolution rate. The results showed that fluidity of mortars was increased by 40 wt.% of maximum flow change with the decreasing specific surface area of cement from 3,500$\textrm{cm}^2$/g to 3,300${\pm}$50$\textrm{cm}^2$/g and affected by the relationship between the cement and balancing between the chemical activityof cement and solubility of calcium sulfate are desirable to prevent the fluidity of concrete from decreasing by high temperature in summer season.

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