• Title/Summary/Keyword: physical and chemical effects

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Design and Operation of FBC Based on Characteristics of Solid Waste Fuels (고체 폐기물 연료 특성을 고려한 유동층 연소로의 설계/운전의 고도화)

  • Choi, Jin-Hwan;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2002.06a
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    • pp.212-219
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    • 2002
  • Waste fuels, which originate from different sources, have unique combustion characteristics. The characteristics should be considered in applying FBC(fluidized bed combustor) technology to those fuels. The effects of fuel properties and operating conditions on FBC reactivity were investigated by means of carbon based parameter called mean carbon conversion time, rate of carbon conversion, fraction of carbon conversion and carbon recovery. And the basic physical and chemical mechanisms taking place in a fluidized bed were summarized. Major parameters in designing and operating FBC were evaluated in terms of the fuel properties and the combustion environment.

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Buckling characteristics of multiwalled carbon nanotubes under external pressure

  • Sato, Motohiro;Shima, Hiroyuki
    • Interaction and multiscale mechanics
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    • v.2 no.2
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    • pp.209-222
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    • 2009
  • This article describes recent work on mechanics of carbon nanotubes, one of the most fundamental and amazing man-made nanostructures. The noteworthy point is that "nano"-scale mechanics of carbon nanotubes can be well described by the continuum elastic theories for "macro"-scale thin shells. This provides an efficient means to elucidate mechanical deformation effects of carbon nanotubes on their physical and chemical properties, which is significant to develop new-generation nanomaterials based on nanotubes and their composites. Potential applications of the mechanical deformation of nanotubes in nano-electronics and nano-biology are also commented. In addition, theoretical investigations regarding external pressure buckling is carried out here and we have numerically confirmed that larger N (the number of layers) and a smaller D (the innermost diameter) make "corrugation modes" with a larger mode-index k be energetically favored.

A Study on Anti-Stress Activities of Cholic Acid Derivatives (담츱산류의 항스트레스 효능에 관한 연구)

  • 조태순;이종찬;조성익;이선미
    • Biomolecules & Therapeutics
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    • v.6 no.3
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    • pp.232-241
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    • 1998
  • This study was done to investigate whether cholic acid derivatives have anti-stress activity in various stress models. Two cholic acid derivatives, ursodeoxycholic acid (UDCA) and tauroursodeoxycholic acid (WDCA), were used. physical, psychological, chemical and environmental stress models were performed. Adrenal weight, serum glucose levels and ALP activity were elevated in restraint stress model, but this elevation was prevented by UDCA treatment. Moreover, UDCA and TUDCA inhibited exploratory and spontaneous movements in oscillation stress model. In alcohol-induced stress model, TUDCA improved rotarod performance. UDCA and TUDCA significantly reduced the involution of lymphoid organs and the increment of WBC counts in cold stress model. These findings suggest that choric acid derivatives have antistress effects in various stress models.

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Effects of Plasma Spray Conditions on Photoelectric Properties of Plasma Sprayed $TiO_2$ Semiconductor ($TiO_2$ 반도체 용사피막의 광전극 특성에 미치는 용사조건의 영향)

  • 박정식;박경채
    • Journal of Welding and Joining
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    • v.12 no.1
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    • pp.94-101
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    • 1994
  • In this study, plasma spraying has been used to produce $TiO_2$ polycrystalline coatings from $TiO_2$ powders. The physical and chemical properties of plasma sprayed $TiO_2$ coatings depend greatly on plasma spraying conditions. The electrical resistivity, oxygen concentration, photocurrent and crystal structure of plasma sprayed $TiO_2$ coating has been studied. The results are as follows: 1. The oxygen loss and electrical conductivity of $TiO_2$ plasma sprayed coatings increased by low pressure and high amount of auxiliary gas, hydrogen in plasma spraying. 2. Oxygen loss increase electrical conductivity, and decrease photocurrent of $TiO_2$ plasma sprayed coatings. 3. Photocurrent of $TiO_2$ plasma sprayed coatings manufactured in atmospheric pressure is higher than that of low pressure.

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The Effects of Interlayer on the DLC Coating (중간층이 DLC 코팅에 미치는 영향)

  • Song, Jin-Soo;Nam, Tae-Woon
    • Corrosion Science and Technology
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    • v.10 no.2
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    • pp.65-70
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    • 2011
  • DLC is considered as the candidate material for application of moving parts in automotive components relatively in high pressure and temperature operating conditions for its high hardness with self lubrication and chemical inertness. The properties of interlayer between the substrate and the DLC film were studied. Arc ion plating method have been employed to deposit onto substrate and sputtering method was used for synthesizing DLC onto interlayer. Among these six types of interlayer, deposited DLC film onto TiCN showed excellent value for characteristics. From the results of analysis for physical properties of DLC films, it seems that the adhesion forces were more important factors than intrinsic mechanical properties such as hardness, roughness and wear resistance of DLC films. AFM(Atomic Force Microscope) was used for understanding roughness of DLC films. Hardnesses of the coating layers were identified by nano-indentation method and adhesions were checked by scratch method.

Outlook for Wood Plastic Composite in aspect of Market and Technology (신 목질 복합재료인 합성목재의 전망 - 시장과 기술의 측면에서 -)

  • Han, You-Soo
    • Composites Research
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    • v.19 no.6
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    • pp.38-42
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    • 2006
  • Wood Plastic Composite(WPC) has been introduced as a new constructional material in Europe and North America. The maintenance-free durability against weather was accepted by customers and the environment-friendly merits ignited the abrupt increase of market size. Domestic major companies have kicked off the WPC business at the market of outdoor constructional materials. Due to the high contents of natural wood fiber, the production equipments should be modified to remove the moisture, to prevent thermal degradation and to promote output rates. Materials including functional fillers play a critical role in rheological properties, which affects the physical and mechanical properties of the last products. More research might be performed for synergy effects combined by various academic fields from mechanical and chemical engineering to polymer process and material science.

Methane carbon dioxide reforming for hydrogen production in a compact reformer - a modeling study

  • Ni, Meng
    • Advances in Energy Research
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    • v.1 no.1
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    • pp.53-78
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    • 2013
  • Methane carbon dioxide reforming (MCDR) is a promising way of utilizing greenhouse gas for hydrogen-rich fuel production. Compared with other types of reactors, Compact Reformers (CRs) are efficient for fuel processing. In a CR, a thin solid plate is placed between two porous catalyst layers to enable efficient heat transfer between the two catalyst layers. In this study, the physical and chemical processes of MCDR in a CR are studied numerically with a 2D numerical model. The model considers the multi-component gas transport and heat transfer in the fuel channel and the porous catalyst layer, and the MCDR reaction kinetics in the catalyst layer. The finite volume method (FVM) is used for discretizing the governing equations. The SIMPLEC algorithm is used to couple the pressure and the velocity. Parametrical simulations are conducted to analyze in detail the effects of various operating/structural parameters on the fuel processing behavior.

Recycling of Casts as an Adsorbent for Phosphorous Removal (인제거를 위한 흡착제로써 분변토 재활용)

  • 손희정;김은호;이용희
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.76-81
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    • 1998
  • The technology of removing phosphorous, considered as one of the most important control nutrients causing eutrophication in various water bodies, have been investigated by many researchers. In this study, casts which can be obtained from the vermicomposting of mixing sewage sludge and cow manure, were used as an adsorbent, and their effects of several physical/chemical factors on the efficiencies of phosphorous adsorption were examined by batch tests. Generally, it could be showed that the efficiencies of phosphorous adsorption were very influenced by cast dosage, temperature and agitation speed. If we reflected the adsorption capacity(k) and adsorption intensity(1/n) of Freundlich isotherm, we couldn't consider casts as a good adsorbent for removing phosphorous. But, because casts were relatively excellent in cation exchange, in point of waste recycling, we could know that they were capable of removing phosphorous. The SEM observation revealed that the evident variations were hardly seen, but particle sizes of cast were relatively bigger and showed forms of smaller plate than before.

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A Study of Deposition Properties and Characteristics of $SiO_2$T film Grown by Remote Plasma-Enhanced Chemical Vapor Deposition (Remote PECVD 산화막의 증착특성 및 박막 특성 연구)

  • 정윤권;정문식;김흥락;권영규;강봉구
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.8
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    • pp.63-70
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    • 1992
  • Deposition properties and film characteristics of Remote PECVD silicon dioxide were investigated. Using $N_{2}O/SiH_{4}$, the effects of changing the process conditions` the pressure, the substrate temperature, and the gas mixing ration, on the film quality were observed. A comparison of film qualites of the Remote PECVD SiO$_2$ with that of a Direct PECVD SiO$_2$ was made. The experimental results show that the Remote PECVD SiO$_2$ has better electrical, physical, and annealing properties than the Direct PECVD oxide.

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Selected Strains of Ginseng with Ge-organic Compounds and ik Effects.

  • Larisa, Slepyan
    • Proceedings of the Ginseng society Conference
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    • 1998.06a
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    • pp.71-82
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    • 1998
  • The first original inducer of interferon had been synthesized in Russia in 1965-1967. It was 2-car-boxiethyl-germanysesquioxan (Lx-13) and other-1 hydroxigermanytrans-monohydral (Lx-5), These compounds have very high induct$\circledcirc$on of interferon. The strain of Panax ginseng C. A. Meyer was recultivated on medium with different concentiation of (Lx-13) and (Lx-5) many times. The strain was stabilized when biomass of cells contain of the Ge form 10${\times}$10-3mg% to 2.3x10-3mg% to ashes, Biomass are hard physical work (swimming test) and also had stress-protective, immunomodulating action and anticarcinogenic effect hampered the sarcoma-180 by 33-80% and suppressed quantity of metanes on 43-46%.

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