• 제목/요약/키워드: physical and chemical effects

검색결과 856건 처리시간 0.025초

Convection in the growth of zinc telluride single crystal by physical vapor transport

  • Kim, Geug-Tae
    • 한국결정성장학회지
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    • 제13권4호
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    • pp.187-198
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    • 2003
  • Zinc selenide (ZnSe) single crystals hold promise for many electro-optics, acousto-optic and green laser generation applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method based on the dissociative sublimation. We investigate the effects of diffusive-convection on the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration. Our results show that for the ratios of partial pressures, s=0.2 and 2.9, the growth rate increases with the Peclet number and the temperature differences between the source and crystal. As the ratio of partial pressures approaches the stoichiometric value of 2, the rate increases. The mass fluk based on one dimensional (1D model) flow for low vapor pressure system fall within the range of the predictions (2D model) obtained by solving the coupled set of conservation equations, which indicates the flow fields would be advective-diffusive. Therefore, the rate and the flow fields are independent of gravity acceleration levels.

Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A.;Aprilia, S.;Suha, T.A.;Fitri, Z.
    • 대한화학회지
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    • 제61권3호
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    • pp.89-96
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    • 2017
  • This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

추나(推拿)치료의 특성에 관한 연구 (A Study on the Characteristic of Tuina Treatment)

  • 권오현
    • 대한물리의학회지
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    • 제2권1호
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    • pp.61-63
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    • 2007
  • Purpose : This purpose of this study is to research basic principles, treatment and kinds of manual therapy of Tuina. Methods : This is a literature study with books and articles. Results : Tuina as a treatment technique with a long history was called by various names. As a term Tuina appears, the technical books and widespread treatments were performed. In modern times, safety was emphasized from chemical and biological side effects of medications, according to this tendency alternative medicine was on the rise. Conclusion : Tuina has a sufficient clinical treatment history and comes into the spotlight as an excellent treatment based on the academic system of oriental medicine.

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Effects of thermal boundary conditions and microgravity environments on physical vapor transport of $Hg_2Cl_2-Xe$ system

  • Kim, Geug-Tae;Kwon, Moo-Hyun;Lee, Kyong-Hwan
    • 한국결정성장학회지
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    • 제19권4호
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    • pp.172-183
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    • 2009
  • For the effects of the nonlinear temperature profiles and reduced-gravity conditions we conduct a two-dimensional numerical modeling and simulations on the physical vapor transport processes of $Hg_2Cl_2-Xe$ system in the horizontal orientation position. Our results reveal that: (1) A decrease in aspect ratio from 5 to 2 leads to an increasingly nonuniform interfacial distribution and enhances the growth rate by one-order magnitude for normal gravity and linear wall temperature conditions. (2) Increasing the molecular weight of component B, Xenon results in a reduction in the effect of solutal convection. (3) The effect of aspect ratio affects the interfacial growth rates significantly under normal gravity condition rather than under reduced gravitational environments. (4) The transition from the convection-dominated regime to the diffusion-dominated regime ranges arises near at 0.1g$_0$ for operation conditions under consideration in this study.

The Effects of Liquid Butadiene Rubber and Resins as Processing Aids on the Physical Properties of SSBR/Silica Compounds

  • Iz, Muhammet;Kim, Donghyuk;Hwang, Kiwon;Kim, Woong;Ryu, Gyeongchan;Song, Sanghoon;Kim, Wonho
    • Elastomers and Composites
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    • 제55권4호
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    • pp.289-299
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    • 2020
  • Highly aromatic (HA) oils are common processing aids used in tire tread compounds. However, they often bleed and evaporate from the vulcanizates during tire use. Thus, the mechanical and dynamical properties of the tire decrease. To overcome this problem, we investigated nonfunctionalized liquid butadiene rubber (LBR-305, Kuraray) and center-functionalized liquid butadiene rubber (C-LqBR), polymerized by anionic polymerization. In addition to the liquid butadiene rubbers, p-tert-octylphenol (P-Resin) and C5 hydrocarbon (H-Resin) tackifier resins, which can induce entanglement of rubber compounds, were researched as a processing aid to solve the bleeding problem. Liquid butadiene rubbers have significantly reduced extraction loss by crosslinking with the main rubber chain. They have also increased the abrasion resistance and showed similar or better mechanical and dynamical properties against HA oils. However, resin compounds did not show differences in extraction loss compared to HA oil compounds; instead, they showed increased wet traction.

First-principles investigation of the monoclinic NaMnO2 cathode material for rechargeable Na-ion batteries

  • Zhang, Renhui;Lu, Zhibin;Yang, Yingchang;Shi, Wei
    • Current Applied Physics
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    • 제18권11호
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    • pp.1431-1435
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    • 2018
  • Using first-principles calculations, we successfully investigate the electrochemical performance of the monoclinic $NaMnO_2$ for the sodium ion batteries. $NaMnO_2$ possesses a voltage window of 3.54-2.52 V and theoretical reversible capacity of $136mAh\;g^{-1}$. Besides, we find that the metallicity of the monoclinic $NaMnO_2$ gradually increases during Na extraction. Moreover, the computational Na migration energy barrier in the monoclinic $NaMnO_2$ is 0.18 eV, ensuring ideal conductivity and reversible capacity. Although the Jahn-Teller distortion effects limit the enhancement of the reversible capacity of the monoclinic $NaMnO_2$, it is still a right cathode material for the sodium ion batteries. The computational results are well in consistent with the experimental investigations.

연도별 가습기 살균제 피해자 분포 고찰 - 폐 손상 중심 - (Distribution of Health Problems Associated with Humidifier Disinfectant by Year)

  • 박동욱;류승훈;노현석
    • 한국환경보건학회지
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    • 제42권6호
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    • pp.365-374
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    • 2016
  • Objectives: Studies are needed to examine the characteristics of health effects reported by people who used humidifier disinfectant (HD), including the distribution of victims. Methods: We analyzed the distribution of health effects including lung injury that were asserted by a total of 699 individuals who registered with the first through third national programs to determine health effects associated with the use of HD. Results: We found that HD-associated lung injury (HDLI) occurred every year from 2002 through 2011, and in 2011 for 37.2% (n=96) of the total of 258 clinically evaluated HDLI victims. More than half of the victims responded that they were victimized between 2010 and 2011. This was consistent among all classifications by sex, age, HD brand and HD chemical ingredient. Conclusion: This study assumed that the major reason for the outbreak of the health effect between 2010 and 2011 could be the variations in concentrations and physical properties related to polyhexamethylene guanidine (PHMG). Further studies are necessary to examine if some factors related to the chemical disinfectants contained in HD brands may have caused the massive outbreak of health effects including HDLI.

Doping된 Si 반도체 세계에서 pH 효과 (pH Effects at Doped Si Semiconductor Interfaces)

  • 천장호;라극환
    • 대한전자공학회논문지
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    • 제27권12호
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    • pp.1859-1864
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    • 1990
  • The effect of H+ and OH- ion concentrations at doped Si semiconductor/pH buffer solution interfaces were investigated in terms of cyclic current-voltage characteristics. The effects of space charge on oppositely doped Si semiconductors, i.e., p-and n-Si semiconductors, can be effectively applied to study the pH effects and the slow surface states at the interfaces. The adsorptions of H+ and OH- inons on the doped Si semiconductor surfaces are physical adsorption rather than chemical adsorption. Adsorptive processes and charging effects of the slow surface states can be explained as the potential barrier variations and the related current-voltage characteristics at the interfaces. Under forward bias, the charged slow surface states on the p-and n-si semiconductor surface are donor and acceptor slow surface states, respectively. The effects of minority carriers on the slow surface states can be neglected at the doped Si semiconductor interfaces.

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화학, 생물, 방사능 사고의 정신적 영향 (The Psychological Impacts of Chemical, Biological and Radiological Disasters)

  • 이다영;심민영
    • 대한불안의학회지
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    • 제13권1호
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    • pp.1-9
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    • 2017
  • We reviewed the scientific literature on psychological effects of Chemical, Biological, Radiological, Nuclear, Explosive (CBRNE) disaster, which is one of the biggest threat to modern society. CBRNE disaster has the potential to cause specific physical symptoms and psychological distress in victims ; moreover, various toxic symptoms and carcinogenesis/mutation would be an important issue. Bioterrorism can cause localized outbreaks of infectious disease or pandemic disaster. Somatization as well as posttraumatic stress symptoms and depression are the characteristic psychological symptoms in CBRNE disaster's victims. CBRNE disasters could lead to large-scale public fear and social chaos due to the difficulties involved in verifying the extent of exposure and unfamiliar area to the common people. In the evacuation process, problems associated with adjustment and conflict between victims and residents should be considered.

빠르게 안정화된 레이온직물의 특성에 미치는 초음파세척 및 화학전처리 영향 (Effects of Ultrasonic Cleaning and Chemical Pre-treatment on the Characteristics of Fast-stabilized Rayon Fabrics)

  • 조채욱;조동환
    • 접착 및 계면
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    • 제14권3호
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    • pp.146-159
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    • 2013
  • 본 연구에서는 $350^{\circ}C$에서 4 min 이내로 빠르게 등온 안정화공정을 통해 얻어진 레이온직물의 화학조성, 물리적 특성, X-선 회절 패턴, 열안정성 그리고 직물 형상에 미치는 초음파세척 및 화학전처리의 영향을 조사하였다. 안정화공정 동안 레이온직물에서 발생하는 중량감소와 열수축을 줄이고 안정화반응을 촉진시키기 위하여 안정화공정 전에 레이온직물을 먼저 초음파 세척하고 $NH_4Cl$, $Na_3PO_4$, $H_3PO_4$$ZnCl_2$로 화학전처리 공정을 수행하였다. 결과는 초음파세척 및 화학전처리가 안정화된 레이온직물의 중량감소, 열수축, 미세구조 변화, 탄소함량, 열안정성, 및 직물 형상에 영향을 주었으며, 사용한 안정화시간과 화학전처리제의 종류에 의존하였다.