• Title/Summary/Keyword: physical and chemical changes

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A model for calculating the irradiation swelling of AgInCd absorber in nuclear control rods

  • Hongsheng Chen;Hongxing Xiao;Chongsheng Long;Xuesong Leng
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.552-557
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    • 2024
  • The actual swelling of AgInCd absorber might exceed the predicted swelling value after years of service in pressurized water reactors, and the chemical and microstructural changes of AgInCd absorber induced by transmutation reactions are the main reason for the swelling acceleration of AgInCd absorber. In the present study, a model for calculating the irradiation swelling of AgInCd absorber in nuclear control rods is developed according to chemical and microstructural changes of AgInCd absorber. In this model, the chemical compositions of AgInCd absorber as a function of the thermal neutron fluence are firstly calculated, and then the volume of AgInCd absorber after irradiation is obtained on the basis of the crystallographic parameters of phases in the AgInCd absorber, and the irradiation swelling of AgInCd absorber is finally calculated. The crystallographic parameters can be obtained by preparing the simulated AgInCd alloys and fitting the experimental data. The model calculating results of irradiation swelling are in good agreement with the actual swelling data in literature. More importantly, the present model can well explain the EPRI results of the acceleration in the diametral swelling rate above 6-8 × 1020 n/cm2 and the decrease in the diametral swelling rate above about 2 × 1021 n/cm2.

Process operation improvement methodology based on statistical data analysis (통계적 분석기법을 이용한 공정 운전 향상의 방법)

  • Hwang, Dae-Hee;Ahn, Tae-Jin;Han, Chonghun
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.1516-1519
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    • 1997
  • With disseminationof Distributed Control Systems(DCS), the huge amounts of process operation data could have been available and led to figure out process behaviors better on the statistical basis. Until now, the statistical modeling technology has been susally applied to process monitoring and fault diagnosis. however, it has been also thought that these process information, extracted from statistical analysis, might serve a great opportunity for process operation improvements and process improvements. This paper proposed a general methodolgy for process operation improvements including data analysis, backing up the result of analysis based on the methodology, and the mapping physical physical phenomena to the Principal Components(PC) which is the most distinguished feature in the methodology form traditional statistical analyses. The application of the proposed methodology to the Balst Furnace(BF) process has been presented for details. The BF process is one of the complicated processes, due to the highly nonlinear and correlated behaviors, and so the analysis for the process based on the mathematical modeling has been very difficult. So the statisitical analysis has come forward as a alternative way for the useful analysis. Using the proposed methodology, we could interpret the complicated process, the BF, better than any other mathematical methods and find the direction for process operation improvement. The direction of process operationimprovement, in the BF case, is to increase the fludization and the permeability, while decreasing the effect of tapping operation. These guide directions, with those physical meanings, could save fuel cost and process operator's pressure for proper actions, the better set point changes, in addition to the assistance with the better knowledge of the process. Open to set point change, the BF has a variety of steady state modes. In usual almost chemical processes are under the same situation with the BF in the point of multimode steady states. The proposed methodology focused on the application to the multimode steady state process such as the BF, consequently can be applied to any chemical processes set point changing whether operator intervened or not.

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A Review of Withering in the Processing of Black Tea

  • Deb, Saptashish;Jolvis Pou, K.R.
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.365-372
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    • 2016
  • Purpose: Tea is the most frequently consumed drink worldwide, next to water. About 75% of the total world tea production includes black tea, and withering is one of the major processing steps critical for the quality of black tea. There are two types of tea withering methods: physical and chemical withering. Withering can be achieved by using tat, tunnel, drum, and trough withering systems. Of these, the trough withering system is the most commonly used. This study focuses on the different types of withering, their effect on the various quality attributes of tea, and other aspects of withering methods that affect superior quality tea. Results: During physical withering, tea shoots loose moisture content that drops from approximately 70-80% to 60-70% (wet basis). This leads to increased sap concentration in tea leaf cells, and turgid leaves become flaccid. It also prevents tea shoots from damage during maceration or rolling. During chemical withering, complex chemical compounds break down into simpler ones volatile flavor compounds, amino acids, and simple sugars are formed. Withering increases enzymatic activities as well as the concentration of caffeine. Research indicates that about 15% of chlorophyll degradation occurs during withering. It is also reported that during withering lipids break down into simpler compounds and catechin levels decrease. Improper withering can cause adverse effects on subsequent manufacturing operations, such as maceration, rolling, fermentation, drying, and tea storage. Conclusion: Freshly harvested leaves are conditioned physically and chemically for subsequent processing. There is no specified withering duration, but 14-18 h is generally considered the optimum period. Proper and even withering of tea shoots greatly depends on the standards of plucking, handling, transportation, environmental conditions, time, and temperature. Thus, to ensure consumption of high quality tea, the withering step must be monitored carefully.

Physical Methods for the Identification of Irradiated Food

  • Yang, Jae-Seung;Lee, Hae-Jung
    • Preventive Nutrition and Food Science
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    • v.3 no.2
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    • pp.203-209
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    • 1998
  • The development of methods for the identification of irradiated foods helps enforce national and international regulations on labelling to ensure the consumer's free choice to buy irradiated or unirradiated foods. and the availabilityof such methods may assist the promotion of international trade in irradiated food products and help prevent abuse of the technology. A number of approaches to determine the physical , chemical, microbiological and biological changes that occur in foods treated with ionizing radiation have been studied. However no single method is universally applicable. Among physical measurements, the leading methods of indentification are electron spin resonance (ESR) spectroscopy and thermoluminescence(TL). ESR is an established non-destructive method for the analysis of free radicals from their traps and TL is the emission of light from irradiated mineral extracts by heating. Viscosity of carbohydrate polymers by causing chain breaks by irradiation, measuring the impedance of potatoes and detection of gases produced radiolytically are promising techniques for identification purposes. Irradiated water-containing foods show significant supercooling when monitored with a differential scanning calorimeter (DSC), which can be applied to identifying irradiated ones.

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Appropriateness Assessment of Dike Height of a Chemical Plant through Development of a Hazardous Chemical Leakage Trajectory Evaluation Module (유해화학물질 누출궤적 평가모듈 개발을 통한 화학공장 방류벽 높이의 적정성 평가)

  • Yoo, Byungtae;Kim, Hyeonggi
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.121-129
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    • 2019
  • The Chemical Control Act of 2015 was enhanced to ensure the safe management of hazardous chemicals. In particular, there have been substantial changes in the standards for the installation and management of handling facilities for manufacturing and storing hazardous chemicals. However, some standards for handling facilities are difficult to implement due to a lack of physical space or because of safety accidents during facility improvements. Therefore, the Safety assessment system (SAS) has been operating for such facilities since 2018. This study developed a leakage trajectory evaluation module that can easily evaluate the outside of a dike for safety evaluation. We analyzed two case studies on a dike for hydrochloric acid and sulfuric acid storage tanks with this module and suggest a reasonable plan for the facility. We believe that it will be possible to more easily submit SAS reports at chemical plants by using this evaluation module. This study is expected to contribute to the improvement of the safety design of hazardous chemical handling facilities.

Accelerated Laboratory Experiments Investigating Weathering of Volcanic Rocks from Yuchon Group Exposed to Seawater and Acidified Distilled Water (실내인공풍화가속실험을 통한 해수와 산성증류수에 대한 유천층군 화산암의 풍화 특성 연구)

  • Ik Woo
    • The Journal of Engineering Geology
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    • v.34 no.1
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    • pp.25-38
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    • 2024
  • Laboratory tests of accelerated artificial weathering compared the effects of seawater and acidified distilled water on rock weathering. The experiments simulated chemical and physical weathering of five different types of volcanic rock by applying 45 freeze-thaw cycles using seawater and acidified distilled water (pH 3), both at 70℃. The physical properties and uniaxial compressive strength (UCS) of the rocks were measured after 15 and 45 cycles of artificial weathering. Most of degradation of physical properties appeared within the first 15 cycles, and acidified distilled water had a greater effect than seawater. Analysis of variance (ANOVA) statistically evaluated the differences in UCS of the different rock types during the tests. The rate of UCS reduction after 45 cycles was similar across the samples, being independent of the rock type and the trend of changes in physical properties. In contrast to the changes in the physical properties, the UCS was more affected by seawater than by acidified distilled water.

Anti-corrosion impact of green synthesis of Silica nanoparticles for the sports structures in physical exercise activities

  • Zhixin Zhang;Zhiqiang Cai;Khidhair Jasim Mohammed;H. Elhosiny Ali
    • Advances in concrete construction
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    • v.15 no.1
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    • pp.41-46
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    • 2023
  • Sport has no age limit and can be done anywhere and in any condition with minimal equipment. The existence of sports spaces in all parts of the world is considered a citizen's right. One of the activities carried out in this field is installing sports equipment and structures in parks and encouraging citizens to use this equipment for physical health with the least cost and facilities. Installing sports structures in open spaces such as parks is a practical step for developing citizens' sports. Although using devices in parks is acceptable, it is more critical to meet scientific and technical standards. The components of these structures must have high strength and endurance against changes in environmental conditions such as humidity, temperature difference, and corrosion. Among the various causes of material degradation, corrosion has always been one of several fundamental causes of metal equipment failure. Sports structures in open spaces are not safe from corrosion. Uniform corrosion is the most common type of corrosion. This corrosion usually occurs uniformly through a chemical or electrochemical reaction across the surface exposed to the corrosive environment. Rust and corrosion of outdoor sports structures are examples of this corrosion. For this reason, in this research, with the green synthesis of silica nanoparticles and its application in outdoor sports structures, the life span of these structures can be increased for the use of physical exercises as well as their quality.

Responses of Low-Quality Soil Microbial Community Structure and Activities to Application of a Mixed Material of Humic Acid, Biochar, and Super Absorbent Polymer

  • Li, Fangze;Men, Shuhui;Zhang, Shiwei;Huang, Juan;Puyang, Xuehua;Wu, Zhenqing;Huang, Zhanbin
    • Journal of Microbiology and Biotechnology
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    • v.30 no.9
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    • pp.1310-1320
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    • 2020
  • Low-quality soil for land reuse is a crucial problem in vegetation quality and especially to waste disposal sites in mining areas. It is necessary to find suitable materials to improve the soil quality and especially to increase soil microbial diversity and activity. In this study, pot experiments were conducted to investigate the effect of a mixed material of humic acid, super absorbent polymer and biochar on low-quality soil indexes and the microbial community response. The indexes included soil physicochemical properties and the corresponding plant growth. The results showed that the mixed material could improve chemical properties and physical structure of soil by increasing the bulk density, porosity, macro aggregate, and promote the mineralization of nutrient elements in soil. The best performance was achieved by adding 3 g·kg-1 super absorbent polymer, 3 g·kg-1 humic acid, and 10 g·kg-1 biochar to soil with plant total nitrogen, dry weight and height increased by 85.18%, 266.41% and 74.06%, respectively. Physicochemical properties caused changes in soil microbial diversity. Acidobacteria, Bacteroidetes, Chloroflexi, Cyanobacteria, Firmicutes, Nitrospirae, Planctomycetes, and Proteobacteria were significantly positively correlated with most of the physical, chemical and plant indicators. Actinobacteria and Armatimonadetes were significantly negatively correlated with most measurement factors. Therefore, this study can contribute to improving the understanding of low-quality soil and how it affects soil microbial functions and sustainability.

Relationship of Somatic Cell Count and Mastitis: An Overview

  • Sharma, N.;Singh, N.K.;Bhadwal, M.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.3
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    • pp.429-438
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    • 2011
  • Mastitis is characterized by physical, chemical and bacteriological changes in the milk and pathological changes in the glandular tissue of the udder and affects the quality and quantity of milk. The bacterial contamination of milk from the affected cows render it unfit for human consumption and provides a mechanism of spread of diseases like tuberculosis, sore-throat, Q-fever, brucellosis, leptospirosis etc. and has zoonotic importance. Somatic cell count (SCC) is a useful predictor of intramammary infection (IMI) that includes leucocytes (75%) i.e. neutrophils, macrophages, lymphocytes, erythrocytes and epithelial cells (25%). Leucocytes increase in response to bacterial infection, tissue injury and stress. Somatic cells are protective for the animal body and fight infectious organisms. An elevated SCC in milk has a negative influence on the quality of raw milk. Subclinical mastitis is always related to low milk production, changes to milk consistency (density), reduced possibility of adequate milk processing, low protein and high risk for milk hygiene since it may even contain pathogenic organisms. This review collects and collates relevant publications on the subject.

Characterization of Graphite Oxide Reduced by Thermal and/or Chemical Treatments

  • Kim, Jungsoo;Nam, Dae-Geun;Yeum, Jeong Hyun;Suh, Sungbu;Oh, Weontae
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.274-279
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    • 2015
  • Reduced graphite oxides (rGOs) were prepared by the common graphite oxidation method and the subsequent reductions. The reduction of graphite oxides (GOs) was conducted chemically and/or thermally. To further reduce the as-prepared rGOs, GOs were treated with chemical/thermal reductions or thermal/chemical reductions, in which the reduction sequence was also considered. The structural changes of as-prepared rGOs, depending on reduction methods, were investigated by X-ray diffraction analyses, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. In addition, we discuss the structural change of the rGOs and their closely related physical and electrical properties, such as thermogravimetry, nitrogen adsorption isotherm, and sheet resistance.