• Title/Summary/Keyword: photocatalyst efficiency

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Study on the Decomposition of Some Volatile Organic Compounds by Photocatalyst Plasma Reaction (광촉매 플라즈마 반응에 의한 몇가지 VOCs의 제거에 관한 연구)

  • 허경욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.373-380
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    • 2000
  • A new type of photocatalyst plasma air purification filter for decomposition of some VOCs has been developed. The photocatalyst plasma air purification filter employs the pulsed discharge plasma as an energy source of TiO2. photocatalyst instead of UV light. In closed room(2m3) test removal efficiency of some VOCs was 80∼100% in 15∼24 hours. In the initial step of phptocatalyst plasma reaction. Acetone and Nitromethane etc were detected. But they were completely oxidized to CO2 and H2O.

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A Compact Pulse Corona Plasma System with Photocatalyst for an Air Conditioner (광촉매와 조합된 코로나 방전 플라즈마 필터의 유해 가스 및 입자 제거 특성)

  • Shin, Soo-Youn;Moon, Jae-Duk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.151-155
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    • 2007
  • A compact discharge plasma system with a photocatalyst has been proposed and investigated experimentally for application to air conditioners. It was found that there was intense ultra violet radiation with high energy of 3.2 eV from the corona discharge due to the DC-biased pulse voltage applied on a wire. An electrophotochemical reaction took place apparently on the surfaces of the photocatalyst of $TiO_2$ irradiated ultra violet front the discharge plasma in the proposed plasma system. The proposed discharge plasma system with the photocatalyst of $TiO_2$ showed very high removal efficiency of VOCs by tile additional electrophotochemical reactions on the photocatalyst. The proposed discharge plasma system also showed very high removal efficiency of particles such as smokes, suspended bacteria, and pollen and mite allergens by the electrostatic precipitation part. This type of corona discharge plasma system with a photocatalyst can be used as an effective means of removing both indoor pollutant gases and particles including suspended allergens.

A Study on Sterilization Characteristics of Elliptical Reactor by Using Xenon Flashlamp and Photocatalyst (Xenon flashlamp와 광촉매를 이용한 타원형 반응기의 살균 특성에 관한 연구)

  • Lee, Dong-Gil;Hong, Ji-Tae;Choi, Kyoung-Hwa;Cha, Jae-Ho;Kim, Hong-Ju;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.3
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    • pp.559-565
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    • 2009
  • In this paper, we invented a new and unique technique for the sterilization of Escherichia coli(E. coli) in polluted water. We applied a rich ultra-violet(UV) light from pulsed xenon flashlamp and photocatalyst(TiO2) to sterilize E. coli in polluted water. This method based on the use of UV light and photocatalyst is eco-friendly and does not cause secondary pollution. The proposed elliptical reactor is able to concentrate on quartz sleeve coated TiO2 or general quartz sleeve. The primary objective of our research was to determine the important parameters such as pulse repetition rate and input voltage and to know on the sterilizing efficiency of quartz sleeve coated TiO2 and general quartz sleeve. We obtained to achieve 99.999% sterilization in as little as 6 pulses at 800V in case of quartz sleeve coated Ti02, and 10 pulses at 800V in case of general quartz sleeve for 5 minutes. Although transmitted light of quartz sleeve coated TiO2 is deceased, the sterilizing efficiency is increased by 40% than general quartz sleeve. The reason of high sterilizing efficiency is that generated hydroxyl radical(OH) by photocatalyst and is able to concentrate light at a focus by using elliptical reactor.

Study of Inorganic Photocatalyst Media for Reused Wastewater (폐수 재이용을 위한 무기계 광촉매 담체 연구)

  • Lee, Gyuyoung;Kim, Jungchul;Lim, Jihyun;Lee, Junwoo;Park, Jeongmi;Lee, Seunghun;Nam, Jukyung;Lee, Yong-Woo
    • Journal of Korean Society on Water Environment
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    • v.31 no.1
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    • pp.42-48
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    • 2015
  • This study focused on effective decomposition methods for low concentrated organic compounds from the reuse of industrial wastewater, and confirmed the possibility through photocatalyst media. Photocatalyst immobilized media was developed to carry on this experiment which confirmed the removal possibility of low concentrated organic compounds. Considering the stability and efficiency of photocatalyst immobilization, inorganic support, hollow bead, and $TiO_2$ nano powder were used. As a result of the removal experiment, the removal efficiencies of acetonitrile, ethanol, IPA(Isopropyl alcohol), methanol were above 75% after 15 minutes while those of acetone, acetaldehyde, urea were 10%, 45%, 20%, respectively after 60 minutes. If further studies were made to increase the surface area of the photocatalyst immobilized media, the efficiency of the removal of low concentrated organic compounds can be improved and this solution can also be used in an actual treatment process.

A study on the photocatalyst filter design using UV-C (UV-C를 이용한 광촉매 필터 디자인에 관한 연구)

  • Han, Sang Yun;Kang, Seung Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.276-282
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    • 2019
  • The purpose of this study was to analyze the structure of general filter using ultrafine filter (Profilter), dust collector filter, HEPA (HAPA-High Efficiency Particulate Air) filter, deodorized filters, etc. of air purifiers and to study new types of purified filters that can improve ultrafine dust, harmful gases, and sterilization cleanup performance. The study was also conducted by adding photocatalyst filters to the existing step-by-step filtration filter types, which were proposed in the design three coupling structure filters of the left and right UV-LED installation frames and the photocatalyst coating honeycomb frame. Future research is needed on the effect of photocatalyst filters. This study was to investigate the application and structure of photocatalyst filters to air purifiers.

A Study on the Dye Wastewater Treatment Using TiO2 Photocatalyst/Ozonation (광촉매/오존을 이용한 염색폐수처리에 관한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin;Kim, Jong-Suk
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.663-670
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    • 2007
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis and ozonation for the treatment of dye wastewater. The treatability of dye wastewater by $UV/TiO_2$ and $UV/TiO_2/O_3$ advanced oxidation process (AOP) was investigated under various conditions. The experiments were conducted in a batch reactor of 50 liters equipped with twelve UV Lamps of 16W. In $UV/TiO_2$ AOP, the removal efficiency of TCODMn and Color increased to 58% and 67% respectively with increasing UV intensity. Also, The removal efficiency of TCODMn and Color increased to 97% and 99% respectively with increasing $H_2O_2$. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and pH 5 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, TCODMn was removed faster than Color.

A Development of Polyester-based Non-woven Fabric Filter for Air Purifier Treated with Self-actuated Photocatalyst

  • Choi, Sei Young
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.226-232
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    • 2016
  • We studied the photocatalytic functionality such as deodorant, antibacterial, fine dust collection efficiency of polyester-based non-woven fabric filter treated with self-actuated photocatalyst. According to UV/visible result, the UV-visible peak of visible-light responsive photocatalyst was found to be red shift at 420 nm sensitive in the visible light region. The deodorizing performance was shown to be reduced more than 80% even without dark conditions. Fine dust particles collection efficiency was shown to be excellent at the size of not only $2.5{\mu}m{\sim}10.0{\mu}m$ but also less than $2.5{\mu}m$. Also antimicrobial and antifungus was shown to be reduced more than 99.9%.

Synthesis and Characteristics of Pd/r-TiO2 Nanotube Arrays Hetrojunction Photocatalyst (Pd/r-TiO2 나노튜브 이종결합 광촉매의 합성과 특성)

  • Lee, Jong-Ho;Lee, Young-Ki;Kim, Young-Jig;Jang, Kyung-Wook;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.32 no.1
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    • pp.14-22
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    • 2022
  • To improve light absorption ability in the visible light region and the efficiency of the charge transfer reaction, Pd nanoparticles decorated with reduced TiO2 nanotube photocatalyst were synthesized. The reduced TiO2 nanotube photocatalyst was fabricated by anodic oxidation of Ti plate, followed by an electrochemical reduction process using applied cathodic potential. For TiO2 photocatalyst electrochemically reduced using an applied voltage of -1.3 V for 10 min, 38% of Ti4+ ions on TiO2 surface were converted to Ti3+ ion. The formation of Ti3+ species leads to the decrease in the band gap energy, resulting in an increase in the light absorption ability in the visible range. To obtain better photocatalytic efficiency, Pd nanoparticles were decorated through photoreduction process on the surface of reduced TiO2 nanotube photocatalyst (r10-TNT). The Pd nanoparticles decorated with reduced TiO2 nanotube photocatalyst exhibited enhanced photocurrent response, and high efficiency and rate constant for aniline blue degradation; these were ascribed to the synergistic effect of the new electronic state of the TiO2 band gap energy induced by formation of Ti3+ species on TiO2, and by improvement of the charge transfer reaction.

Air Cleaning Unit using Combination of $TiO_2$ Photocatalyst and Pulsed Discharge Plasma (산화티타늄 광촉매와 펄스 방전 플라즈마 조합에 의한 공기정화장치)

  • Hong, Yeong-Gi;Sin, Su-Yeon;Gang, Jeong-Hun;Lee, Seong-Hwa;Jo, Jeong-Su;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.10
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    • pp.710-715
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    • 1999
  • The purpose of this work is to develop a high-efficiency air cleaning system for air pollutants such as particulate and gaseous state in indoor environments. In order to enhance a removal efficiency of gaseous state pollutants, we suggested that pulsed discharge plasma be combined with $TiO_2$ photocatalyst (photocatalytic plasma air cleaning unit). We investigated experimentally the basic characteristics of photocatalytic plasma air cleaning unit and measured air pollutants removal efficiency. The wavelength of light radiated from pulsed discharge plasma under the atmospheric condition was 310~380nm. Its energy is enough to excite the $TiO_2$ photocatalyst and it makes a photochemical reaction in the surface of $TiO_2$ photocatalyst. The removal quantity of trimethylamine$((CH_3)_3N)\; was\; 130mg/m^34 which is twice quantity of pulsed discharge plasma without $TiO_2$ phtocatalyst unit. From the result of gas analysis using FT-IR, nitric oxide was not detected and trimethylamine was decomposed to $H_2O\; and \;CO_2$. And trimethylamine removal efficiency was 95%. These experimental results indicate that photocatalytic plasma air cleaning unit is a potential method in removing the pollutants.

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Improvement of Carbon Dioxide Reduction Efficiency of Titanium Dioxide Photocatalyst Using 1-propanol (1-propanol 첨가에 따른 이산화타이타늄(TiO2) 광 촉매의 비표면적 향상 및 이산화탄소 환원 효율 향상)

  • Ha, Yuntae;Kwon, JinBeom;An, Heekyung;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.31 no.5
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    • pp.343-347
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    • 2022
  • Recently, the problem of global warming caused by greenhouse gases is getting serious due to the development of industry and the increase in transportation means. Accordingly, the need for a technology to reduce carbon dioxide, which accounts for most of the greenhouse gas, is increasing. Among them, a catalyst for converting carbon dioxide into fuel is being actively studied. Catalysts for reducing carbon dioxide are classified into thermal catalysts and photocatalysts. In particular, the photocatalyst has the advantage that carbon dioxide can be reduced only by irradiating ultraviolet rays at room temperature without high temperature or additional gas. TiO2 is widely used as a photocatalyst because it is non-toxic and has high stability, but has a disadvantage of low carbon dioxide reduction efficiency. To increase the reduction efficiency, 1-propanol was used in the synthesis process. This prevents agglomeration of the catalyst and increases the specific surface area and pores of TiO2, thereby increasing the surface area in contact with carbon dioxide. As a result of measuring the CO2 reduction efficiency, it was confirmed that the efficiency of TiO2 with 1-propanol and TiO2 without 1-propanol was 19% and 12.3%, respectively, and the former showed a 1.5 times improved efficiency.