Journal of Korean Society of Water and Wastewater (상하수도학회지)

The Korean Society of Water and Wastewater (대한상하수도학회)
권호 표지

A Study on the Dye Wastewater Treatment Using TiO2 Photocatalyst/Ozonation

광촉매/오존을 이용한 염색폐수처리에 관한 연구

  • 김창균 (계명대학교 공과대학 토목공학과) ;
  • 정호진 (계명대학교 공과대학 토목공학과) ;
  • 김종석 ((주)이앤비코리아 기술연구소)
  • Received : 2007.05.02
  • Accepted : 2007.10.17
  • Published : 2007.12.15
Download PDF
⟨ Previous Next ⟩

Abstract

This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis and ozonation for the treatment of dye wastewater. The treatability of dye wastewater by $UV/TiO_2$ and $UV/TiO_2/O_3$ advanced oxidation process (AOP) was investigated under various conditions. The experiments were conducted in a batch reactor of 50 liters equipped with twelve UV Lamps of 16W. In $UV/TiO_2$ AOP, the removal efficiency of TCODMn and Color increased to 58% and 67% respectively with increasing UV intensity. Also, The removal efficiency of TCODMn and Color increased to 97% and 99% respectively with increasing $H_2O_2$. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and pH 5 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, TCODMn was removed faster than Color.

Keywords

References

  1. 강준원 (1993) 오존, 과산화수소, UV를 이용한 고급산화처리 공정의 Kinetic에 관한연구(1), 대한환경공학회지, 15(2), pp.501-510
  2. 난분해성 폐수처리 시스템 (2004) DICER Techinfo Part II. pp. 278-290
  3. 김성준 (1999) 광촉매현탁식 $UV/TiO_2O_2$ 시스템을 이용한 Chlorinated Acetaldehydes의 분해, 대한환경공학회지 21(2), pp.263-275
  4. 김현용 (2003) 폐수처리를 위한 공촉매 박막 제조 및 특성에 관한 연구, 서울대학교 박사학위논문
  5. (주) 이앤비코리아 (2004) 환경신기술발표회
  6. 이태규, 주현규 (2000) 광촉매와 환경/에너지, Catalysis, 16(1), pp. 8-21
  7. 임재호, 이정현 (1999) 염색단지 종합폐수처리의 현황과 전망. 섬유기술과 산업. pp. 184-194
  8. 전희동 (1994) $TiO_2$ 광촉매를 이용한 고도산황처리기술. 대한환경공학회지 16(7), pp. 1-10
  9. 조일형, 김현용, 이용규, 박경렬, 이홍근 (2000) 순환식반응기에서 $UV/TiO_2$를 이용한 반응성 염료의 제거에 관한 연구. 한국환경위생학회지. 26(1), pp. 64-70
  10. E. Piera et al. (2000) 2, 4-Dichlorophenoxyacetic acid degradation by catalyze ozonation: $TiO_2/UVA/O_3$ and Fe(II)/UVA/$O_3$ systems. Applied Catalysis B: Environmetal, 27, pp. 169-177 https://doi.org/10.1016/S0926-3373(00)00149-1
  11. Fenglei Zhang, Jincai Zhao, Tao Shen, Hisao Hidaka, Ezio Pelizzetti, and Nick Serpone (1998) TiOrassisted photodegradation of dye pollutants. II. Adsorption and degradation kinetics of eosin in $TiO_2$ dispersions under visible light irradiation, Applie Catalysis B; Environmeental, 15, pp. 147-156 https://doi.org/10.1016/S0926-3373(97)00043-X
  12. Guangwei Wu, Athanasia Koliadima, Yie Shein Her, and Egon Matijevic (1997) Adsorption of Dyes on Nanosize Modified Silica Particle. J' of Colloid and Interface Science, 195, pp. 222-228 https://doi.org/10.1006/jcis.1997.5156
  13. Minguang Dai (1998) Mechanism of Adsorption for Dyes on Activated Carbon. J. of Colloid and lnteriace Science, 198, pp. 610
  14. Michael R. Hoffman, Scot T. Martin, Won-yong Choi, and Detlef W. Bahnemann (1995) Environmental Applcataions of Semiconductor Photocatalysis. Chem Rev., 95, pp. 69-96 https://doi.org/10.1021/cr00033a004
  15. Patrik Kopf, Ernst Gilbert and Siegfried H. Eberle (2000) $TiO_2$ photocatalytic oxidation of monochloroacetic acid and pyridine: influence of ozone. J. of photocbemistry and photobiology A: Cbemistry 136, pp.163-168 https://doi.org/10.1016/S1010-6030(00)00331-2