• 제목/요약/키워드: photo-effect

검색결과 712건 처리시간 0.031초

광-펜톤 산화반응을 이용한 Rhodamine B의 탈색 (Decolorization of Rhodamine B by Photo-Fenton Oxidation)

  • 박영식
    • 한국물환경학회지
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    • 제23권2호
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    • pp.274-280
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    • 2007
  • The photochemical decolorization of Rhodamine B (RhB) in water has been carried out by photo-Fenton process. The effect of applied $H_2O_2$, $Fe^{2+}$ dose, solution pH and UV dose have been studied. The influence of constituent processes of photo-Fenton such as UV, $H_2O_2$ and Fenton has been investigated. Comparison of RhB removal was made between the photo-Fenton and $UV/H_2O_2$ process. The results obtained showed that the optimum dosage of $Fe^{2+}$ and $H_2O_2$ were 0.0031 mmol and 0.625 mol, respectively. pH 3 is found to be the optimum pH of for photo-Fenton process. pH and UV dose strongly influenced the decolorization of RhB in photo-Fenton process. The photo-Fenton and $UV/H_2O_2$ processes showed similar decolorization and seem to be appropriate for the decolorization of dye wastewater.

The Effect of H content in Si Precursor on the Performance of Poly-Si Crystallized by Pulsed YAG2${\omega}$ Laser on Soft Substrate

  • Li, Juan;Ying, Yao;Meng, Zhiguo;Chunya, Wu;Xiong, Shaozhen;Kwok, Hoi-Sing
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1604-1607
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    • 2009
  • YAG laser crystallization of Si-based thin film deposited on plastic substrate has been studied. The Si-based thin films as crystallization precursor are with varied hydrogen (H) content. The effect of the H content on the crystallinity of the resulted poly-Si film has been investigated. The experimental results of the poly-Si crystallized by doublefrequency YAG laser shows that the initial dehydrogenation process could be left out if ${\mu}c$-Si was adopted as the crystallization precursor. The YAG laser annealing condition on plastic substrate and the crystallization results have been discussed in the paper.

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광염색체이상시험의 광발암성 예측능력에 대한 평가 (Assessment of Sensitivity of Photo-Chromosomal Assay in the Prediction of Photo-carcinogenicity)

  • 홍미영;김지영;이영미;이미가엘
    • Toxicological Research
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    • 제21권2호
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    • pp.99-105
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    • 2005
  • Photo-mutagenic compounds have been known to alter skin cancer rates by acting as initiators or by affecting subsequent steps in carcinogenesis. The objectives of this study are to investigate the utility of photo-chromosomal aberration (photo-CA) assay for detecting photo-clastogens, and to evaluate its ability to predict rodent photocarcinogenicity. Photo-CA assay was performed with five test substances that demonstrated positive results in photo-carcinogenicity tests: 8-Methoxypsoralen (photoactive substance that forms DNA adducts in the presence of ultraviolet A irradiation), chlorpromazine (an aliphatic phenothiazine an alpha-adrenergic blocking agent), lomefloxacin (an antibiotic in a class of drugs called fluoroquinolones), anthracene (a tricyclic aromatic hydrocarbon a basic substance for production of anthraquinone, dyes, pigments, insecticides, wood preservatives and coating materials) and Retinoic acid (a retinoid compound closely related to vitamin A). For the best discrimination between the test substance-mediated genotoxicity and the undesirable genotoxicity caused by direct DNA absorption, a UV dose-response of the cells in the absence of the test substances was firstly analyzed. All 5 test substances showed a positive outcome in photo-CA assay, indicating that the photo-CA test is very sensitive to the photo-genotoxic effect of UV irradiation. With this limited data-set, an investigation into the predictive value of this photo-CA test for determining the photo-carcinogenicity showed that photo-CA assay has the high ability of a test to predict carcinogenicity. Therefore, the photo-CA test using mammalian cells seems to be a sensitive method to evaluate the photo-carcinogenic potential of new compounds.

Cruciform Thiophene-based Molecules as Organic Semiconductors for Field Effect Transistor Applications

  • Choi, Dong-Hoon;Kim, Dae-Chul;Kim, Kyung-Hwan;Cho, Min-Ju;Jin, Jung-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.170-173
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    • 2007
  • Cruciform conjugated molecule, 4(DP3T)-benzene bearing terthiophene moieties has been synthesized through Horner-Emmons Reaction using 5-dodecyl-5"-aldehyde-[2,2';5',2"] terthiophene as dendrons and octaethyl benzene- 1,2,4,5-tetrayltetrakis(methylene)tetraphosphonate as the core unit; this molecule has been fully characterized. The terthiophene-based molecule exhibits good solubility in common organic solvents and good self-film forming property. They are intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from uniform orientations of molecules. Thus, intermolecular interaction can be enhanced to affect the carrier transport phenomena after annealing at $148^{\circ}C$. The semiconducting property of 4(DP3T)-benzene have been evaluated in organic field-effect transistors. 4(DP3T)-benzene exhibit carrier mobility as high as $(6.6{\pm}0.5)$ ${\times}$ $10^{-6}cm^2V^{-1}s^{-1}$.

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Determinants of SNS Photo Sharing Behavior of Teenagers at an Outdoor Music Festival in China

  • Zhu, Zong-yi;Kim, Hyeon-Cheol
    • International journal of advanced smart convergence
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    • 제9권2호
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    • pp.129-139
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    • 2020
  • This study aims to understand the determinants and effects of SNS photo sharing on festival satisfaction among teenage festivalgoers, to derive strategies that festival organizers could employ to maintain long-term relationships with their audience. In this paper, we followed the festival attribute and SNS photo sharing behavior approaches for developing measurement constructs, by investigating previous related studies. Statistical analyses revealed that festival attributes positively impact consumer perceptions of festival value, which in turn influences SNS photo sharing behavior and festival satisfaction. In addition, SNS photo sharing behavior has a significant mediation effect on the process. Moreover, the differing intensities of SNS usage among the festivalgoers resulted in consumers presenting significantly different SNS photo sharing behavior. Our findings offer insights for marketers in the festival business who are interested in gaining a better understanding of the behavior of teenage festivalgoers.

In-situ 광배향법을 이용한 액정 배향 및 프리틸트의 발생 (Liquid crystal alignment and generation of pretilt angle using an in-situ photo-alignment method)

  • 서대식;김형규
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.336-339
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    • 2000
  • Effects of liquid crystal (LC) alignment using an in-situ photo-alignment method by linearly polarized UV exposure during imidization of polyirnide (PI) on the two kinds of PI surfaces with side chain were investigated. The generated pretilt angle in nematic (N) LC using an in-situ photo-alignment method was smaller than that of a conventional photo-alignment method for short UV exposure time. Also, the pretilt angle of the NLC using an in-situ photo-alignment method increases with increasing UV exposure time on the two kinds of the PI surfaces. Finally, the pretilt angle of NLC can be improved by annealing treatment.

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Effect of Liquid Crystal Alignment for Photo-Aligned VA-LCD on the Photo-Dimerized Polymer Surface

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Journal of the Optical Society of Korea
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    • 제5권1호
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    • pp.16-19
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    • 2001
  • A photopolymer, copoly (M4Ch-ChMA), copoly ((4-methacryloyloxy) chalcone-cholesteryl methacrylate), was synthesized in this study. The electro-optical (EO) characteristics for the photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) were investigated. Excellent voltage-transmittance curves for the VA-LCD photo-aligned by polarized UV exposure on the copoly (M4Ch-ChMA) surface were observed. The response time for the photo-aligned VA-LCD decrease with increasing UV exposure time. consequently, the photo-dimerized chalcone moiety increased with increasing UV exposure time, which then contributed to a low response time for the VA-LCD photo-aligned.

Facile Preparation of Ag2S-CNT Nanocomposites with Enhanced Photo-catalytic Activity

  • Meng, Ze-Da;Sarkar, Sourav;Zhu, Lei;Ullah, Kefayat;Ye, Shu;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제51권1호
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    • pp.1-6
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    • 2014
  • Here we report improved photo-catalytic effect of $Ag_2S$ under visible light using carbon nano-tubes (CNT) modified with $Ag_2S$ nanoparticles. The optical properties, structural properties and compositional analysis, as well as the photo-electrochemical properties of the prepared composites were investigated. It was found that the photocurrent density, and the photo-catalytic effect, was increased by modification of CNT in this way. Compared with the separate effects of $Ag_2S$ and CNT nanoparticles, the photocatalytic effect of CNT-modified-with-$Ag_2S$ composites, increased significantly due to a synergistic effect between the CNT and the $Ag_2S$ nanoparticles.

박막 광전에너지 변환소자의 개발에 관한 연구 (A Study of Fabrication Techniques of Thin film Photo-Electric Energy Conversion Elements)

  • 성영권;민남기;성만영;김승배
    • 전기의세계
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    • 제25권5호
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    • pp.63-69
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    • 1976
  • Among various types of photo-electric energy conversion element which can transfer solar energy into electric energy through the photo voltaic effect, Si solar cells were investigated on photoelectric characteristics, improvements of its efficiency and economical evaluation for its production cost. To study the above subjects, we decided best conditions on fabricating of thin film Si solar cell by epitaxial growth and knew that the thin solar cell by epitaxial growth was more efficient than that by diffusion process. And also higher photo voltaic output was obtained as a effect of SiO as antireflection coating by several methods, i.e. vacuum evaporating techniques of electrode to decrease the contact resistance and to form best ohmic contact, and concentration techniques of sun's ray by lenz or both-sided illumination through special structure for reflection using mirrors.

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Macroscopic Nonlinear Optical Properties of Tricyanopyrrolidene Chromophore Containing Amorphous Polycarbonate: Effect of Molecular Lateral Moiety in the Conjugative Structure

  • Cho, Min-Ju;Lee, Sang-Kyu;Jin, Jung-Il;Choi, Dong-Hoon
    • Macromolecular Research
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    • 제14권6호
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    • pp.603-609
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    • 2006
  • Tricyanopyrrolidene chromophores were prepared in order to compare their macroscopic nonlinear optical (NLO) properties with a conjugated structure through the long molecular axis. A thiophene or phenyl ring was tethered to an ethylenic bond; it may act as a lateral moiety to disrupt the planarity of a chromophore and lessen the electrostatic interaction. Thin film composites of these chromophores dissolved in amorphous polycarbonate (APC) were fabricated. Real time pole and probe method was employed to investigate the change of electro-optic (EO) signal during poling. The EO properties and their relaxation behaviors of the guest-host systems containing newly synthesized chromophores were investigated in detail.