• 제목/요약/키워드: phosphates

검색결과 304건 처리시간 0.023초

이산화탄소 지중 격리용 인산염 혼입 시멘트 페이스트에 관한 기초물성 평가 (Evaluation on the Basic Properties of Phosphate Modified Portland Cement Paste for Potential Application of Geologic CO2 Sequestration)

  • 윤주한;김성근;김지현;이재용;정철우
    • 한국건축시공학회지
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    • 제17권3호
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    • pp.253-260
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    • 2017
  • 지구온난화가 세계적으로 이슈가 되면서 이산화탄소 포집 및 저장기술의 개발에 관한 많은 노력이 집중되고 있다. 이중 이산화탄소 지중저장은 포집된 이산화탄소를 초임계 상태로 지하의 암반층에 안정적으로 저장하여 대기로의 유출을 방지하는 기술이다. 이와 같이 저장된 이산화탄소의 유출을 막기 위해 콘크리트를 사용하는데, 이 때 콘크리트는 매우 공격적인 형태의 중성화로 인해 내구성이 열화될 수 있다. 그러므로 본 연구에서는 이에 대한 안정성을 높이기 위해 포틀랜드 시멘트에 인산칼슘을 혼입하여 지구상에서 가장 안정적인 물질중 하나인 수산화인회석을 생성시키고자 하였다. 따라서 본 연구에서는 인산칼슘을 혼입한 포틀랜드 시멘트 페이스트의 수화온도, 점성, 응결 및 경화, 압축강도 변화를 분석하였다. 그 결과, 인산칼슘이 혼입되면 페이스트의 점도를 증가되나 최대수화온도는 낮아지고, 28일 압축강도 또한 저하되는 것으로 나타났다. 특히 인산이수소칼슘은 포틀랜드 시멘트와 함께 사용하기는 어려운 것으로 나타났으며, 인산수소칼슘 및 인산삼칼슘을 혼입한 경우에는 장기강도 성상을 확인한 후 활용가능성을 타진할 필요가 있는 것으로 나타났다.

생화광물(生化鑛物)과 우리 생활 (Biominerals and Our Livings)

  • 박정봉
    • 기술사
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    • 제34권3호
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    • pp.16-21
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    • 2001
  • Biominerals are mean of biochemical mineralization and forming for ore depesits of limestone, iron, phosphate and energy minerals, etc . Our Country need in large quantity of biominerals, for example, about a hundred million ton of limestones, fifty million tons of iron ores, three million tons of phosphates, seven hundred million brrels of crude oil, eleven million ton of LNG and sixty million ton of coals per year.

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Environmental Control of Chemical Composition of the Secondary Hydroxyapatite from Japan

  • Kashima, Naruhiko;Tazaki, Kazue;Fyfe, W.S.
    • 동굴
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    • 제8호
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    • pp.11-18
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    • 1998
  • The mineral hydroxyapatite is very common species in secondary phosphates originating from guanos(HILL et at., 1997). Several mineralogical analyses of spelean hydroxyapatite exist(e.g., KASHIMA, 1968, 1979 ; MAKI et at., 1977 ; SUH et at., 1978 ; WANG, 1982 a, b), whereas detailedeochemical composition of secondary hydroxy apatites has not been reported in Japan.(omitted)

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담수산 미세조류로부터 생리활성물질의 탐색 (Screening of Bioactive Materials from Freshwater Microalgae)

  • 이완석;최애란;안치용;오현철;안종석;오희목
    • ALGAE
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    • 제19권3호
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    • pp.271-276
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    • 2004
  • One hundred and fifty four micro algal strains, newly isolated from nationwide freshwaters in Korea, were screened for their anticancer, ant diabetic, and antibiotic activities. The micro algal strains were cultured with different nutritional conditions that were divided into 4 groups as follows; a normal Allen medium, nitrogen (N)-limited medium, phosphorus (P)-limited medium, and N and P-limited medium. Algal biomass was extracted with a mixture of acetone:H₂O (1:1, v:v) and the extracts were used for the screening of bioactive materials. Anticancer, ant diabetic, and antibiotic materials were screened by the methods of vaccinia Hl-related protein tyrosine phosphates (VHR DS-PTPase) inhibition, protein tyrosine phosphates 1B (PTP1B) inhibition, and paper disk. The inhibition activity of VHR DS-PTPase was observed in 18 strains, having a maximum 79% inhibition from Anabaena affinis and the inhibition activity of PTP1B was observed in 9 strains, having a maximum 97% from Sphaerocystis schroeteri. Microcystis aeruginosa incubated in an N and P-limited medium showed antibiotic activity in 8 species out of 13 pathogenic bacteria. As a whole, it seemed that the stressed condition such as N and/or P limitation increased the production of bioactive materials in micro algae.

Formation of Hydroxyapatite in Portland Cement Paste

  • Chung, Chul-Woo;Lee, Jae-Yong;Kim, Ji-Hyun
    • 한국건축시공학회지
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    • 제14권1호
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    • pp.68-75
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    • 2014
  • In order to increase the integrity of the wellbore which is used to prevent the leakage of supercritical $CO_2$, it is necessary to develop a concrete that is strongly resistant to carbonation. In an environment where the concentration of $CO_2$ is exceptionally high, $Ca^{2+}$ ion concentration in pore solution of Portland cement concrete will drop significantly due to the rapid consumption of calcium hydroxide, which decreases the stability of the calcium silicate hydrate. In this research, calcium phosphates were used to modify Portland cement system in order to produce hydroxyapatite, a hydration product that is strongly resistant to carbonation under such an environment. According to the experimental results, calcium phosphates reacted with Portland cement to form hydroxyapatite. The formation of hydroxyapatite was verified using X-ray diffraction analyses with selective extraction techniques. When using dicalcium phosphate dihydrate and tricalcium phosphate, the 28-day compressive strength was lower than that of plain cement paste. However, the specimen with monocalcium phosphate monohydrate showed equivalent strength to that of plain cement paste.

Effects of Jerusalem Artichoke Powder and Sodium Carbonate as Phosphate Replacers on the Quality Characteristics of Emulsified Chicken Meatballs

  • Ozturk, Burcu;Serdaroglu, Meltem
    • 한국축산식품학회지
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    • 제38권1호
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    • pp.26-42
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    • 2018
  • Today incorporation of natural ingredients as inorganic phosphate replacers has come into prominence as a novel research topic due to health concerns about phosphates. In this study, we aimed to investigate the quality of emulsified chicken meatballs produced with Jerusalem artichoke powder (JAP), either alone or in combination with sodium carbonate (SC) as sodium tripolyphosphate (STPP) replacers. The results showed that naturally dried JAP showed favorable technological properties in terms of water-oil binding and gelling. Emulsion batters formulated with JAP-SC mixture showed lower jelly and fat separation, higher water-holding capacity and higher emulsion stability than control samples with STPP. In final product, incorporation of JAP-SC mixture increased moisture and reduced lipid and energy values, and kept the pH value similar to control. Added JAP lead to increments in $b^*$ values whereas decreases $L^*$ values. Cook yield was similar to control in phosphate-free samples formulated with JAP-SC mix. Either low or medium ratios of JAP in combination with SC managed to protect most of the sensory parameters, while sensory scores tend to decrease in samples containing high levels of JAP. Addition of JAP to formulations presented samples that have equivalent behavior to phosphates in terms of lipid oxidation. In conclusion, our study confirms that utilization of JAP in combination with SC had promising effects as phosphate replacers by presenting natural solutions and providing equivalent quality to standard phosphate containing products.