• Title/Summary/Keyword: phosphate of ammonium

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Seasonal and Spatial Variations of Nutrient Fluxes in the Intertidal Flat of Keunso Bay, the Yellow Sea (서해 근소만 갯벌에서 영양염 플럭스의 계절 변화)

  • Kim, Kyung-Hee;Kim, Dong-Seon
    • Ocean and Polar Research
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    • v.30 no.3
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    • pp.225-238
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    • 2008
  • In order to investigate the effects of intertidal sediments on the nutrient cycle in coastal environments, the benthic fluxes of ammonium, nitrate, nitrite, phosphate, and silicate at two stations on the intertidal flat of Keunso Bay were determined during each season. The efflux of ammonium was observed at S1 and resulted from the diffusion of remineralized ammonium and acceleration caused by the bioirrigation of macrofauna. The influx of ammonium at S2 was probably due to nitrification in the water column. The influx of nitrate was observed at both stations during all seasons, indicating that the nitrate in the pore water was removed by denitrification. Vigorous bioirrigation led to the efflux of dissolved inorganic nitrogen (DIN) at S1, whereas the influx of DIN at S2 was predominantly caused by denitrification. Contrary to the diffusive and bio-irrigated release of remineralized phosphate from the sediment at S1, the influx of phosphate was observed at S2, which may be attributable to adsorption onto iron oxides in the aerobic sediment layer. Silicate, which is produced by the dissolution of siliceous material, was mostly released from the sediment by molecular diffusion and bioirrigation. However, the influx of silicate was observed at S2 during spring and winter, which was ascribed to adsorption by particulate matter or assimilation by benthic microphytes. The annual fluxes of DIN were 328 mmol $m^{-2}yr^{-1}$ at S1 and -435 mmol $m^{-2}yr^{-1}$ at S2. The annual fluxes of phosphate were negative at both sites (-2.8 mmol $m^{-2}yr^{-1}$ at S1 and -28.9 mmol $m^{-2}yr^{-1}$ at S2), whereas the annual fluxes of silicate were positive at both sites (843 mmol $m^{-2}yr^{-1}$ at S1 and 243 mmol $m^{-2}yr^{-1}$ at S2).

Physical and Mechanical Properties and Fire-endurance Characteristics of Recycled Particleboards

  • Suh, Jin-Suk;Han, Tae-Hyung;Park, Joo-Saeng;Park, Jong-Young
    • Journal of the Korea Furniture Society
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    • v.19 no.6
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    • pp.475-486
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    • 2008
  • In this study, fire-retardant chemicals were melt with mixed composition ratios of dibasic ammonium phosphate and each half of boric acid and borax in hot water, in which hammer-milled chips were immersed to increase swelling of waste particleboards. Also, fire-retardant treated particles from sawn lumber chip and recycled particleboard chip were composed in ratio of 70:30 in core layer to improve boards' properties. Retention ratio of fire-retardant chemicals for the particles for face layer was high due to high specific surface area, and that of sawn lumber chips was somewhat higher than that of recycled particleboard chips. The mixture of particles from sawn lumber chips and recycled PB of 70:30 in weight ratio exceeded bending strength of 100 $kgf/cm^2$. It seemed that the relatively greater portions of dibasic ammonium phosphate affected adversely to dimensional stability, however fire-retardants treatment resulted in distinct effect lowering formaldehyde emission such as $E_0$ type(0.5mg/$\ell$ or less) in KS F 3104. In fire-retardancy, the recycled boards with a mixed ratio of dibasic ammonium phosphate to boric acid borax(50:50 mixture) of 70% to 30% in weight satisfied fire-retardancy 3rd grade in KS F 2271, and also this composition from cone calorimeter test met same standard grade figuring total heat release of 4.6MJ/$m^2$.

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Characterization of Erythropoietin Producing Cell Lines after Introduction of Urea Cycle Enzymes, Carbamoly Phosphate Synthetase and Ornithine Transcarbamoylase

  • Lee, Yun-Jeong;Kim, Na-Young;Kim, Hyung-Jin;Park, Jung-Ho;Kim, Jung-Kwon;Hee, Chang-Kern;Kim, Jung-Hoe;Kim, Hong-Jin
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.170.3-171
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    • 2003
  • An efficient Erythropoietin (EPO)-expression system in mammalian cells is required for massive production for therapeutic use. Ammonium ion is a major problem in the production of valuable recombinant proteins in cultured animal cells. Therefore, it is of importance to devise a system by which a high productivity of human therapeutic recombinant protein can be maintained or enhanced under low ammonium concentration. To reduce the ammonium ion accumulated in EPO producing Chinese Hamster Ovary (CHO) ceels, IBE, we introduced the first two genes of the urea cycle, carbamoyl phosphate synthetase (CPSI) and arnithine transcarbamoylase (OTC), into IBE using a stable transfection method. (omitted)

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Hygroscopic Property, Leaching Resistance and Metal Corrosive Efficacy of Wood Treated with Fire Retardants

  • Son, Dong Won;Kang, Mee Ran;Hwang, Won Joung;Lee, Hyun Mi;Park, Sang Bum
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.2
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    • pp.157-162
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    • 2014
  • This study was conducted to examine the functionality of the fire retardant treated wood. The hygroscopic property, leaching resistance, metal corrosive efficacy and gas toxicity of retardant treated wood were analyzed. Sodium silicate was penetrated to the wood for making fire retardant treated wood. The subsequent treatment agents such as boric acid, ammonium borate, di-ammonium phosphate were treated after sodium silicate treatment due to fixation. As results for the test, the leaching resist was improved by subsequent treatment. The fire retardant combination such as sodium silicate, boric acid and di-ammonium phosphate showed high hygroscopic property, metal corrosive efficacy. The gas toxicity was also satisfied KS standard.

Electrical and Rheological Behavior of the Angydrous ER Fluids Based on Chitosan Derviatives as the Dispersion Phases

  • Choi, Ung-Su
    • KSTLE International Journal
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    • v.5 no.2
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    • pp.49-51
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    • 2004
  • The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.

Studies on the Residual Bending Strength of Burned Wood treated with Fire-retardant Chemicals (내화처리연소목(耐火處理燃燒木)의 잔류(殘留) 휨강도에 관(關)한 연구(硏究))

  • Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.2
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    • pp.10-19
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    • 1984
  • The $3{\times}3{\times}30$ ($cm^3$) sized lumbers of Populus alba-grandulosa L. were treated with four fire-retardant solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate and aluminium chloride for 1, 15, 30, and 60 minutes and 1, 3, and 7 days. Thereafter they were air-dried and burned at high temperature about $1,800^{\circ}C$ and for short time of five minutes. This study estimated the relationship between absorbed chemical amounts and rate of weight loss or residual bending strength of these burned lumbers. The results were as follows: 1) In absorption amount of fire-retardant chemicals, diammonium phosphate showed the largest, aluminium chloride the smallest, but monoammonium phosphate and ammonium sulfate showed similar level. 2) The absorption amount of chemicals was decreased with the increase of specific gravity in the same species except aluminium chloride. 3) The rate of weight loss was decreased as the absorption amount of chemicals increased, especially monoammonium phosphate was most effective. 4) The MOR value of the residual bending strength was increased as the absorption amount of chemicals increased and especially monoammonium phosphate showed the most efficient effect. 5) Aluminium chloride showed more striking increase of MOR value of residual bending strength with the increase of absorption amount than any other chemical, therefore its MOR value was similar to the maximum MOR value of the most effective monoammonium phosphate. 6) The correlation between weight loss and MOR value of the residual bending strength was negative and aluminium chloride showed the most striking negative relation, but the others showed similar trends. 7) The correlation between work to proportional limit and absorption amount of chemicals was positive and the degree of increase in work to proportional limit was most in aluminium chloride, and the next, in monoammonium phosphate and diammonium phosphate in turn. 8) The correlation between work to maximum load and absorption amount of chemicals showed positive and diammonium phosphate revealed the best result and aluminium chloride showed better results than other two chemicals.

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Feeding di-ammonium phosphate as a phosphorous source in finishing lambs reduced excretion of phosphorus in feces without detrimental effects on animal performance

  • Koolivand, Abolfazl;Yari, Mojtaba;Khalaji, Saeed;Jonker, Arjan
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.4
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    • pp.527-532
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    • 2019
  • Objective: Phosphorous (P) sources with greater bioavailability might increase animal production efficiency and decrease environmental pollution. The objective of current study was to determine animal performance, nutrient digestibility, blood metabolites and fecal P concentration in finishing lambs fed a diet with either di-calcium phosphate (DCP) or di-ammonium phosphate (DAP) as a P source. Methods: Twelve 4-month-old male lambs (initial body weight $24.87{\pm}3.4kg$) were randomly allocated to a diet with either DCP or DAP (~261 g/kg of total diet P) fed ad libitum for 93 days. Diets were iso-nitrogenous and iso-energetic and had same calcium (Ca) and P concentrations. Results: The DAP contained 19.7 g/kg of dry matter (DM) Ca, 185.4 g/kg DM P and 14,623 ppm fluorine, while DCP contained 230.3 g/kg DM Ca, 195.2 g/kg DM P and 1,039 ppm fluorine. The diet with DAP contained 60 ppm fluorine while the diet with DCP contained 13 ppm fluorine. Lambs fed the diet with DAP tended to have a greater daily DM intake compared to those fed diet with DCP (p = 0.09). Lambs fed DAP had greater plasma P concentration and alkaline phosphatase activity ($p{\leq}0.01$) compared with lambs fed DCP. Dry matter and organic matter digestibility of the diets were similar between two treatments at days 60 and 90, while they were greater in lambs fed DCP (p<0.05) at day 30 of the trial. Feeding DAP increased P digestibility (58.7% vs 50.2%; p<0.05) and decreased fecal P concentration in lambs compared with feeding DCP (3.1 vs 3.8 g/kg DM; p<0.05). Conclusion: Providing ~261 g/kg of total diet P as DAP in the diet of finishing lambs improved the bioavailability of P in the body and decreased excretion of P in feces without affecting lamb performance.

Nitrogen and Phosphorus Recoveries from Anaerobic Digester Supernatant Using Seawater as Magnesium Source for Struvite Formation (바닷물을 이용한 struvite 형성으로 혐기성 소화액으로부터 질소, 인 회수)

  • Kim, Yong-Beom;Ahn, Johng-Hwa
    • Journal of Korean Society on Water Environment
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    • v.31 no.4
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    • pp.387-391
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    • 2015
  • This study was performed to evaluate the effect of pH (8-12) and molar ratio of magnesium and phosphate ($[Mg^{2+}]/[PO_4{^{3-}}]$) (0.6-1.4) on struvite crystallization of anaerobic digester supernatant using seawater as magnesium source. pH range of 9-10 is favorable for ammonium and phosphate recoveries. The recovery efficiency of ammonium was highest at $[Mg^{2+}]/[PO_4{^{3-}}]$ of 1.0 and pH 10. On the other hand, high phosphate recovery efficiency (> 99%) was achieved at ($[Mg^{2+}]/[PO_4{^{3-}}]$) of 1.4 and pH 10. The results demonstrated that seawater can be considered as low-cost magnesium source to recover phosphorus from anaerobic digester supernatant.

Increasing Cell Concentration by the Automatic Addition of Glucose, Ammonium and Phosphate in the Cultivation of a Baker′s Yeast in Alcohol Distillery Wastewater (알콜증류폐액을 이용한 빵효모배양에서 포도당, 암모늄 및 인산의 자동첨가에 의한 증균)

  • 이형춘
    • KSBB Journal
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    • v.18 no.3
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    • pp.197-201
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    • 2003
  • Automatic addition of glucose, ammonium and phosphate to alcohol distillery wastewater and their control at low concentrations have been carried increase the cell concentration of a baker's yeast cultivated in the wastewater. Glucose was automatically added using dissolved oxygen as the control parameter, and maintained below 300 mg/L. Ammonium was automatically added by a pH-stat method and maintained in the low range of 12.6~17.4 mM. An automated FIA system, which used an ascorbic acid-based method was developed for the automatic analysis nad addition of phosphate. With this system, the phosphate concentration was succesfully analysed and controlled afrer 19.4 hr in the range 23.3~43.4 mg/L. The cell concentration was increased by 33.0-fold by the addition of these three nutrients. The overall specific growth rate of the yeast was 0.19 $hr^{-1}$.

Effect of Nitrogen, Phosphate and Cell Immobilization on Taxol Production from Cell Cultures of Taxus cuspidata (주목 (Taxus cuspidata) 세포배양에서 질소원, 인산, 세포고정화가 Taxol 생산에 미치는 영향)

  • Park, Jong-Hwa;Chung, In-Sik
    • Applied Biological Chemistry
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    • v.38 no.4
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    • pp.308-312
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    • 1995
  • The effects of nitrogen, phosphate in modified B5 medium and cell immobilization on cell growth and taxol production were investigated using cell cultures of Taxus cuspidata. The ratio of nitrate to ammonium was found to be an important parameter. The ratio of 1 increased taxol production 10-fold, compared to the original ratio of 20 in modified B5 medium. Reducing phosphate concentration inhibited cell growth, but increased taxol production noticeably. Immobilized cells produced a taxol concentration of ${\sim}120\;g/l$

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