• 한국환경과학회지
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• 제9권4호
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• pp.351-367
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• 2000

Air-lift biofilm reactor should be an admirable process substituting conventional activated sludge process, because of its small area requirement as well as high volumetric loading capacity and stability against loading and chemical shocks. However most of the past research on the performance of ABR was focused on the sewage treatment. This research studied the applicability of ABR to treat high strength wastewater. A bench-scale ABR was operated to treat high strength synthetic wastewater, tannery wastewater and petrochemical wastewater, and its applicability was conclusive In case of synthetic wastewater, ABR showed good performance in which the substarate removal efficiency was higher that 80% even under short HRT(1.4 hr) and high volumetric loading rate(9.3 kgCODcr/$m^3$.day). When ABR was applied to treat tannery wastewater, it was suggested that the maximum volumetric loading rate and F/M ratio should be 7.7kgCODcr/$m^3$.day, 0.76 $day^{-1}$, respectively. And high substrate removal efficiency over than 90 % was observed with 4,000 mgCODcr/L of petrochemical wastewater. Even though effluent concentration was quite high, ABR should be applicable to treat the high strength wastewater, because of its high loading capacity.

• 한국물환경학회지
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• 제22권1호
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• pp.59-65
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• 2006

The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for petrochemical basic compound manufacturing (PBCM) and plastics and synthetic resins manufacturing (PSRM) industry. Wastewater discharged from the each category contains high concentration of COD and toluene. Eighteen sites were surveyed and wastewater qualities were analyzed. Six and two different technologies were applied to the PBCM and PSRM industry for the end-of-pipe treatment process, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options: typical activated-sludge process + sand filtration + activated carbon adsorption (PBCM) and wet oxidation + chemical precipitation + typical activated-sludge process + chemical precipitation (PSRM) were selected as the BAT for each industry.

• 한국환경과학회지
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• 제24권2호
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• pp.237-244
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• 2015

This objectives of research are to figure out combustion characteristics with increasing temperature with petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and sawdust, and to exam heating value and ignition temperature for using refused derived fuels(RDFs). After analyzing TGA/DTG, petrochemical sludge shows a rapid weight reduction by vaporing of inner moisture after $170^{\circ}C$. Gross weight reduction rate, ignition temperature and combustion rates represent 68.6%, $221.9^{\circ}C$ and 54.1%, respectively. In order to assess the validity of the RDFs, the petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and waste sawdust. The materials are mixed with 7:3(petrochemical sludge : organic matters)(wt%), and it analyzes after below 10% of moisture content. The ignition temperatures and combustion rates of the waste electric wire, anthracite coal and waste sawdust are $410.6^{\circ}C$, $596.1^{\circ}C$ and $284.1^{\circ}C$, and 85.6%, 30.7% and 88.8% respectively. In heating values, petrochemical sludge is 3,600 kcal/kg. And the heating values of mixed sludge (adding 30% of the waste electric wire, anthracite coal and waste sawdust) each increase up to 4,600 kcal/kg, 4,100 kcal/kg and 4,300 kcal/kg. It improves the ignition temperatures and combustion rates by mixing petrochemical sludge and organic matters. It is considered that the production of RDFs is sufficiently possible by using of petrochemical sludge by mixing wasted organic matters.

• 대한환경공학회지
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• 제28권5호
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• pp.573-576
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• 2006

The efficacy of integrated ozone oxidation-biodegradation treatment was examined in the treatment of petrochemical wastewater with a special focus on the overall treatment time. When raw wastewater with chemical oxygen demand(COD) of 70-80 mg/L was oxidized by ozone, approximately 20% of initial COD was removed in less than 1.5 min at a dosing rate of 400 mg $O_3/L{\cdot}h $. No further decrease in COD was observed for the extended ozone treatment up to 30 min. Biological treatment alone showed a rapid reduction of COD to 40-50 mg/L, subsequently resulting in the decreased rate of COD removal. Pre-treatment by ozone before biological treatment did not significantly affect the specific rate of COD removal in a biological treatment. When ozone oxidation followed biological treatment, the extent of COD removal by ozone oxidation was greater compared to that of biologically-treated wastewater for a shorter time. Taken together, it was decided that the biological treatment time could be reduced if the treatment processes of concern will be properly arranged.

• 청정기술
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• 제17권2호
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• pp.175-180
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• 2011

생태산업단지의 산업 공생망 구성을 위한 다중척도 의사결정 전략을 개발하고 이를 여수산업단지의 산/염기성 폐수 중화망 설계에 적용하였다. 산(또는 염기)성 폐수는 화학산업에서 공통적으로 나오며, 다른 곳에서 나온 염기(또는 산)성 폐수를 자체적으로 중화할 수 있는 원료가 될 수 있다. 따라서 산/염기성 폐수가 대량으로 발생되는 석유화학산업단지에서 대규모의 산업 공생망을 구축할 수 있는 가능성을 지나고 있다. 본 연구에서는 산/염기성 폐수의 상호 중화를 위한 물질 흐름 모델을 구성하고, 여기에 다중척도의사결정 전략을 적용하여 최적이며 대등한 다수의 산업 공생망 후보를 설계하고 이들의 성능을 비교 분석하였다.

• Advances in environmental research
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• 제2권3호
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• pp.229-243
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• 2013

Coagulation-flocculation (CF) was tested coupled with an aerobic biofilter to reduce total petroleum hydrocarbon (TPHs) concentration and toxicity from petrochemical wastewater. The efficiency of the process was followed using turbidity and chemical oxygen demand (COD). The biofilter was packed with a basaltic waste (tezontle) and inoculated with a bacterial consortium. Toxicity test were carried out using Lactuca sativa var. capitata seeds. Best results for turbidity removal were obtained using alum. Considerable turbidity removal was obtained when using Opuntia spp. COD removal with alum was 25%, for Opuntia powder it was 36%. The application of the biofilter allowed the removal of 70% of the remaining TPHs after 30 days with a biodegradation rate (BDR) value 47 $mgL^{-1}d^{-1}$. COD removal was slightly higher with BDR value 63 $mgL^{-1}d^{-1}$. TPH kinetics allowed a degradation rate constant equal to $4.05{\times}10^{-2}d^{-1}$. COD removal showed similar trend with $k=4.23{\times}10^{-2}d^{-1}$. Toxicity reduction was also successfully achieved by the combined treatment process.

• 한국대기환경학회지
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• 제21권3호
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• pp.315-327
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• 2005

The total of 35 target VOCs (volatile organic compounds), which were included in the TO-14, was selected to develop a VOCs' source profile matrix of the Yeosu Petrochemical Complex and to test its collinearity by singular value decomposition(SVD) technique. The VOCs collected in canisters were sampled from 12 different sources such as 8 direct emission sources (refinery, painting, wastewater treatment plant, incinerator, petrochemical processing, oil storage, fertilizer plant, and iron mill) and 4 general area sources (gasoline vapor emission, graphic art activity, vehicle emission, and asphalt paving activity) in this study area, and then those samples were analyzed by GC/MS. Initially the resulting raw data for each profile were scaled and normalized through several data treatment steps, and then specific VOCs showing major weight fractions were intensively reviewed and compared by introducing many other related studies. Next, all of the source profiles were tested in terms of degree of collinearity by SVD technique. The study finally could provide a proper VOCs' source profile in the study area, which can give opportunities to apply various receptor models properly including chemical mass balance (CMB).

• 한국환경과학회지
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• 제5권1호
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• pp.51-59
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• 1996

The purpose of this study was to evaluate the partial oxidation of the biological treatment plant effluents using Fenton's reagent as a pretreatment step prior to a tertiary biological oxidation of these effluents. Fenton's reagent was evaluated as a pretreatment process for inhibitory or refractory organics. Based on the Fenton oxidation system, the petrochemical wastewater treatment plant effluent was shown to have significant improvement in toxicity after oxidation with hydrogen peroxide. For example, at ranee of 42 ∼ 184 mg/L COD of petrochemical plant effluents, the COD removal efficiencies were from 38.2% to 60.1% after reaction with hydrogen peroxide 200 mg/L and Fe2+ 100 mg/L and reaction time was 30 minutes. The total TOC reduction were about 15.8∼22.4% with same test condition and difference between the overall removal rate and BOD/COD ratio after Fenton's oxidation estabilished in the biodegradation and otherwise meets the discharge standard or reuse for cooling tower make-up water.

• Membrane and Water Treatment
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• 제13권5호
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• pp.219-225
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• 2022

5th Assessment Report of the Intergovernmental Panel on Climate Change Weather (AR5) predicts that recent severe hydrological events will affect the quality of water and increase water pollution. To analyze changes in water quality due to future climate change, input data (precipitation, average temperature, relative humidity, average wind speed, and solar radiation) were compiled into a representative concentration curve (RC), defined using 8.5. AR5 and future use are calculated based on land use. Semi-distributed emission model Calculate emissions for each target period. Meteorological factors affecting water quality (precipitation, temperature, and flow) were input into a multiple linear regression (MLR) model and an artificial neural network (ANN) to analyze the data. Extensive experimental studies of flow properties have been carried out. In addition, an Acoustic Doppler Velocity (ADV) device was used to monitor the flow of a large open channel connection in a wastewater treatment plant in Ho Chi Minh City. Observations were made along different streams at different locations and at different depths. Analysis of measurement data shows average speed profile, aspect ratio, vertical position Measure, and ratio the vertical to bottom distance for maximum speed and water depth. This result indicates that the transport effect of the compound was considered when preparing the hazard analysis.

• 한국환경보건학회지
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• 제20권3호
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• pp.1-12
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• 1994

Wastewaters being treated and final effluents were collected from 3 wastewater treatment plants of petrochemical industries, from August 31 to October 4, 1993 in an interval of 10 days, and further analysed by GC/FID to investigate discharge situation and removal efficiency on polycyclic aromatic hydrocarbons. The results were as follows: 1. The PAHs 294.57 $\mu$g/l were discharged in primary treatment effluent of plant A to manufacture vinyl acetate resin and acryl, and removed 54.51% by aeration and totally 84.71%. 2. The PAHs of the highest concentration were discharged in primary treatment effluent of plant B to manufacture PS resin and ABS resin, but removed 91.65% by activated sludge process and 98.19% by activated carbon to discharge PAHs of the lowest concentration comparing to another treatment operations. 3. The PAHs 99.96 $\mu$g/l of the lowest concentration were discharged in wastewater of plant C to manufacture epoxy resin, and removed 80.48% by activated sludge process. 4. B treatment system including activated carbon showed up the best removal efficiency of PAHs. Activated carbon therefore, seems to be effective as tertiary treatment. 5. Correlation coefficient of components to total PAHs was generally low, and correlation coefficients of phenanthrene, pyrene and acenaphthylene to total PAHs were each 0.98, 0.97 and 0.80, respectively. Correlation coefficient of the sum of phenanthrene, pyrene and acenaphthylene to total PAHs was 0.99, so that the sum of phenanthrene, pyrene and acenaphthylene was available as index to estimated total PAHs. 6. Phenanthrene and Chrysene were very well treated biologically and acenaphthylene and fluoranthene were untreated biologically. 7. Considering EPA standards, it seems that the concentration of phenanthrene, pyrene, fluoranthene, and benzo(k)fluoranthene is high level.