• Journal of the Korea Organic Resources Recycling Association
• /
• v.20 no.4
• /
• pp.61-74
• /
• 2012

Industrial complexes in Korea have been vigorously established by economic development plan and development policy of industry in 1960s. Recently, Korean government has promoted Eco Industrial Park (EIP) project to recycle by-products and wastes in industrial park In this study, we analyzed the physical and chemical properties for the sludges discharged from A industrial complex. And we investigated the economic feasibility and environmental impact of sludge to energy facilities. The analysis results indicated that the petrochemical industry were 92% in sludge production, the highest treatment amount was landfill, followed by incineration and recycling and then ocean disposal. Wastewater sludge and process sludge samples are collected and analyzed to use as basic data on economic feasibility and environmental impact. Weighted average heating value of sludge samples was 3,891kcal/kg. Based on this data, installation and operation costs, operation returns of operating the drying facility are estimated, compared with cogeneration facility. And this study examines how the payback period of each simulation(total 8 case) with the important parameter changes. As a result, it was found that what needs the shortest payback period is 3years with connection of drying facility and cogeneration facility based on the government's financial subsidy system.

• Journal of Korean Society for Atmospheric Environment
• /
• v.32 no.4
• /
• pp.394-407
• /
• 2016

The spatial air pollution distribution of the Ulsan metropolitan region (UMR) was analyzed using monitoring data and high-resolution numerical simulations. A three-year (2011~2014) analysis for the average concentrations from the 13 air quality monitoring sites in the UMR showed that $SO_2$ and $PM_{10}$ levels in industrial regions were much higher than those in other regions, whereas spatial differences of $NO_2$ and CO concentrations were not significant. In particular, elevated $O_3$ concentrations were clearly found at urban sites near petrochemical complex area. Results from high-resolution simulations by CMAQ model performed for four months of 2012 showed large spatial variations in grid-average pollutant concentrations between industrial areas and other areas in the UMR, which displayed significant changes with wind pattern by season. It was noted that the increases of $SO_2$ and $PM_{10}$ levels were limited in costal industrial areas or over the area nearby the sea in all seasons. Modeled $O_3$ concentrations were quite low in industrial areas and main urban roads with large $NO_x$ emissions. However, the model presented that all pollutant concentrations were significantly increased in the urban residential areas near the industrial complexes in summer season with increase of southerly wind.

• The Journal of the Korea institute of electronic communication sciences
• /
• v.8 no.7
• /
• pp.1033-1038
• /
• 2013

Petrochemical complex has been a lot of research for the development of a more mature product and analysis for mid-process and finished products is essential in these process. But these analyzes are still by hand work samples being manufactured in many parts. Moreover they are exposed to hazardous chemical and such as the analysis is being made in a very poor working conditions. In this paper, in order to solve such problems the multi control system has been developed for the automated analysis. In addition, the organic behavior of these systems and the development of a program for the automated applied, and throughout the experiment to verify the reliability of this device for the accuracy of the dosing pumps for the standard solution prepared with a range of error of ${\pm}0.01m{\ell}$ was able to get a very good experimental results.

• Journal of the Korean Society of Safety
• /
• v.18 no.3
• /
• pp.88-93
• /
• 2003

The Process Safety Management (PSM) by the Law of Industry, Safety and Health has been performed for preventing major accidents of chemical plants since 1996. In terms of preventing chemical accidents more precisely, it is essential to develop a tool for quantitative risk assessment. For this, KOSHA (Korea Occupational Safety and Health Agency) developed an Integrated Risk Management System (IRMS). The system is designed to assimilate data on chemical plant hazards from external database, to integrate these data with location information(topographic and demographic), and to make them user-friendly accessible. The system consists of several main functions: display of five major Korean petrochemical complex layout display of equipment layout with its information utilizing the external database, zonation of the hazard effected area with consequence analyses, the most probable accident scenario generation, accident/incident database and calculation of frequency of accident using equipment reliability database, etc. The highlight of IRMS is to provide the risk contours using GIS(Geographical Information System) technology. IRMS is intended to manage hazardous installation more systematically and effectively, to reduce the number of accident remarkably, further minimizing production loss in the plant. The system is now under application to about 500 PSM sites as well as and emergency authorities in Korea by KOSHA (Korea Occupational Safety and Health Agency)

• Economic and Environmental Geology
• /
• v.32 no.6
• /
• pp.669-688
• /
• 1999

The Yeongju granitoid batholith is a plutonic complex of huge area (1180km2) intruding the metamorphic rocks of the Yeongnam massif. The batholith, which is divided into fivelithofacies, consists of three separate plutons. The oldest Buseok pluton comprises four lithofacies: hornblende biotite tonalite, porphyrotoc biotite granodiorite, equigranular biotite grandiorite and biotite granite. The middle Chunyang pluton has been called as Chunyang granite that ranges in compostion from granodiorite to granite. The youngest Jangsu pluton is intrusions that has lithofacies of two mica granite. The contact between Buseok pluton and the rest two plutons shows obvious intrusive relations, but relation between the Chunyang and the Jangsu pluton is far away, so gives no indication of relative ages. Changes in nextures and micristructures, as well as in the mineral contents, take place between rock types og the plutons. only the Buseok pluton shows faliations of two type: magmatic foliation and regional mylonal foliation. K-Ar age deteminations fall into 171.7$\pm$3.2~162.3$\pm$3.1 Ma in the Buseok pluton, 153.9$\pm$2.9 Ma in the Chunyang pluton and 145.3$\pm$2.7 Ma in the jangsu Pluton. The batholith presents three separate intrusive phases which range in composition from tonalite to granite to granite. Each intrusive phase apperars to have been intruded in a pulse from an underlying, differentiating magma. The petrochemical data showthat three plutons are within the diagnostic range for continental arc orogenic tectonic setting, whereas Jangsu pluton approaches postorogenic setting. The data suggest that three plutons are calc-aclkalline series, and that temporal compositional variations change progerssively from tonalite through grandiorite to granite between the intrusive phases. so we consider that the magmas for all the phases were probably derived from a differentiation by fractional crystallization of a parental magma. The tonalite magma of the Buseok phase was tapped was tapped from a chamber deep in the crust, and then would have to rise at a rapid rate to its final level of emplacement. The tonalite magma in the chamber was gradually enolved through granodiorite magma into granite magma by fractional crystallization. The magmas of the younger phases were respectively tapped with temporal interval from a evolved magma of the chamber that rose into a shallower lever in the crust, and rose to their present level of emplacement.

• Korean Journal of Chemical Engineering
• /
• v.35 no.12
• /
• pp.2327-2335
• /
• 2018

Fluid catalytic cracking (FCC) is an important chemical process that is widely used to produce valuable petrochemical products by cracking heavier components. However, many difficulties exist in modeling the FCC process due to its complexity. In this study, a dynamic process model of a FCC process is suggested and its structural observability is analyzed. In the process modeling, yield function for the kinetic model of the riser reactor was applied to explain the product distribution. Hydrodynamics, mass balance and energy balance equations of the riser reactor and the regenerator were used to complete the modeling. The process model was tested in steady-state simulation and dynamic simulation, which gives dynamic responses to the change of process variables. The result was compared with the measured data from operating plaint. In the structural analysis, the system was analyzed using the process model and the process design to identify the structural observability of the system. The reactor and regenerator unit in the system were divided into six nodes based on their functions and modeling relationship equations were built based on nodes and edges of the directed graph of the system. Output-set assignment algorithm was demonstrated on the occurrence matrix to find observable nodes and variables. Optimal locations for minimal addition of measurements could be found by completing the whole output-set assignment algorithm of the system. The result of this study can help predict the state more accurately and improve observability of a complex chemical process with minimal cost.

• Particle and aerosol research
• /
• v.17 no.3
• /
• pp.55-69
• /
• 2021

Chungnam region accounts for the largest SO_X (22.8%) emission with the second-largest NO_X (10.8%) emission in Korea due to the integration of many large industrial sources including a steel mill, coal-fired power plants, and petrochemical complex. Air pollutants emitted by large industrial sources can cause harmful problems to humans and the environment. Thus, it is necessary to understand dispersion patterns of air pollutants from large industrial sources in Chungnam to characterize atmospheric contamination in Chungnam and the surrounding area. In this study, seasonal atmospheric dispersion characteristics for SO_X, NO_X, and PM2.5 from ten major point sources in Chungnam were evaluated using HYSPLIT 4 model, and their contributions to SO₂, NO₂ concentrations in the regions near the source areas were estimated. The predictions of the HYSPLIT 4 model show a seasonal different dispersion pattern, in which air pollutants were dispersed toward the southeast in winter while, northeast in summer. In summer, due to weaker wind speed, air pollutants concentrations were higher than in winter, and they were dispersed to the metropolitan area. The local emissions of air pollutants in Taean area had a greater influence on the ambient SO₂ and NO₂ concentrations at Taean, whereas SO_X and NO_X emissions from large sources located at Seosan showed relatevely little effect on the ambient ambient SO₂ and NO₂ concentrations at Seosan.

• Korean Chemical Engineering Research
• /
• v.60 no.4
• /
• pp.512-518
• /
• 2022

In this study, safety devices for ammonia tanks of a company in Ulsan petrochemical industrial complex were studied. The type of a tank is cylindrical and this tank was originally designed to store propylene in 1972. Due to the changes of the production schedule according to market environments, the usage of this tank has been changed to store ammonia. Despite of the changes of materials, there is no scientific information or reviews for guaranteeing the safety. Therefore, in this study, the current status of this tank is investigated to confirm that the operational conditions are complying with safety conditions. Moreover, the safety devices such as an ammonia absorbing system and water curtains are analyzed how they mitigate the impact of an accident. In addition, consequence analysis is performed to provide a proper emergency response plan. Throughout these analysis, it is confirmed that installed safety devices effectively mitigate the impact of accidents, and the necessary time for an emergency response plan is suggested when ammonia release.

• Journal of Environmental Health Sciences
• /
• v.48 no.3
• /
• pp.151-158
• /
• 2022

Background: Chemical emissions in the environment have rapidly increased with the accelerated industrialization taking place in recent decades. Residents of industrial complexes are concerned about the health risks posed by chemical exposure. Objectives: This study was performed to suggest modeling methods that take into account multimedia and multi-pathways in human exposure and risk assessment. Methods: The concentration of benzene emitted at industrial complexes in Daesan, South Korea and the exposure of local residents was estimated using the Caltox model. The amount of human exposure based on inhalation rate was stochastically predicted for various activity stages such as resting, normal walking, and fast walking. Results: The coefficient of determination (R²) for the CalTOX model efficiency was 0.9676 and the root-mean-square error (RMSE) was 0.0035, indicating good agreement between predictions and measurements. However, the efficiency index (EI) appeared to be a negative value at -1094.4997. This can be explained as the atmospheric concentration being calculated only from the emissions from industrial facilities in the study area. In the human exposure assessment, the higher the inhalation rate percentile value, the higher the inhalation rate and lifetime average daily dose (LADD) at each activity step. Conclusions: Prediction using the Caltox model might be appropriate for comparing with actual measurements. The LADD of females was higher ratio with an increase in inhalation rate than those of males. This finding would imply that females may be more susceptible to benzene as their inhalation rate increases.

• Spatial Information Research
• /
• v.10 no.2
• /
• pp.247-261
• /
• 2002

There are much damage of people and property because of heavy rain every year. Especially, there are problem to major facility such as dam, bridge, road, tunnel, and industrial complex in the ground stability. So the counter plan for landslide or ground failure must be necessary In the study, the technique of regional landslide susceptibility assessment near the Ulsan petrochemical complex and Kumgang railway bridge was developed and applied using GIS. For the assessment, the geological structures such as bedding and fault were surveyed and the geological structure, topographic, soil, forest, and land use spatial database were constructed using CIS. Using the spatial database, the factors that influence landslide occurrence, such as slope, aspect, curvature and type of topography, texture, material, drainage and effective thickness of soil, type, age, diameter and density of forest, and land use were calculated or extracted from the spatial database. For application of geological structure, the geological structure line and fault density were calculated. Landslide susceptibility was analyzed using the landslide-occurrence factors by probability method that is summation of landslide occurrence probability values per each factors range or type. The landslide susceptibility map can be used to assess ground stability to protect major facility.