• Bulletin of the Korean Chemical Society
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• v.9 no.6
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• pp.384-388
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• 1988

New methods of the reduction of carboxylic acid salts to aldehydes with 2 equiv of thexylbromoborane-dimethyl sulfide (ThxBHBr${\cdot}SMe_2$) or 9-borabicyclo[3.3.1]nonane (9-BBN) are described. Both these reagents provide the corresponding aldehydes from various as sodium and lithium salts of carboxylic acids in high yields both at room temperature. Such facile reductions are explained as the simple substitution for the bromo group of ThxBHBr by a carboxylate to form thexyl(acyloxty)borane followed by reduction with excess reagent and the formation of an ate complex followed by reduction with excess 9-BBN.

• Journal of Information Processing Systems
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• v.17 no.2
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• pp.242-252
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• 2021

Following the intuition that the local information in time instances is hardly incorporated into the posterior sequence in long short-term memory (LSTM), this paper proposes an attention augmented mechanism for fault diagnosis of the complex chemical process data. Unlike conventional fault diagnosis and classification methods, an attention mechanism layer architecture is introduced to detect and focus on local temporal information. The augmented deep network results preserve each local instance's importance and contribution and allow the interpretable feature representation and classification simultaneously. The comprehensive comparative analyses demonstrate that the developed model has a high-quality fault classification rate of 95.49%, on average. The results are comparable to those obtained using various other techniques for the Tennessee Eastman benchmark process.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.604-609
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• 2020

The purpose of this study is to check the priority control status of the current operation process alarm by comparing the priority of the alarm set up in PV high trip point, which is being installed and operated in the domestic petrochemical industry, with the criteria presented in ISA 18.2 International Standard or EEMUA 191 Guidelines. In the event of a process problem, excessively set high alarm is provided to the driver in a short period of time, making it difficult to identify the alarm that needs to be handled first. As a result, it is likely that the operator will not be able to carry out appropriate actions within the specified time frame, and many cases have been reported leading to unexpected process shutdowns or process accidents. Therefore, this study aims to introduce international standards related to alarm management and identify the level of alarm control used at the domestic petrochemical industry site to inform potential risks that may occur in the petrochemical process of the national industrial complex in the future and suggest ways to reduce risk factors. This paper was submitted to Professor Lee Inbeom's retirement anniversary issue.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.2
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• pp.104-110
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• 2004

This study was carried out to survey the pollution of bisphenol A(BPA) and total organic carbon(TOC) in surface sediments around Gwangyang bay. BPA is suspected chemicals as endocrine disruption. Gwangyang bay Is located on the mid south coast of Korea. It is a semi-closed bay which Yeosu petrochemical industrial complex, POSCO(Pohang Steel Company) and Gwangyang container harbor are located. The surface sediments were collected at 15 stations with gravity corer at October, 1999, February, May and August, 2000. Also, the stream and intertidal sediment were collected at 5 sites at August, 2000. Concentrations of BPA in surface sediments were in the range of 0.46 to 24.59 ng/g dry wt.. Seasonal range(mean value) of BPA are 0.59 to 9.00(1.88) ng/g dry wt. at October, 0.99 to 2.97(1.57) ng/g dry wt. at February, 0.46 to 24.59(2.53)ng/g dry wt. at May and 0.54 to 2.46 (1.29)ng/g dry wt. at August. BPA was seasonally fluctuated, and the highest mean value and range were detected at May, 2000. BPA was highly distributed in the inner part of Kwangyang bay than Yosu sound. Concentrations of BPA in stream and intertidal sediments showed the highest value in downstream near Yochon petrochemical industrial complex and Yondung stream. It suggests that the source of BPA are industrial wastewater and municipal sewage. TOC in surface sediments were in the range of 0.09∼1.22%. There was no any correlation between the BPA and TOC.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.603-612
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• 2014

Lots of networks are constructed in a large scale industrial complex. Each network meet their demands through production or transportation of materials which are needed to companies in a network. Network directly produces materials for satisfying demands in a company or purchase form outside due to demand uncertainty, financial factor, and so on. Especially utility network and hydrogen network are typical and major networks in a large scale industrial complex. Many studies have been done mainly with focusing on minimizing the total cost or optimizing the network structure. But, few research tries to make an integrated network model by connecting utility network and hydrogen network In this study, deterministic mixed integer linear programming model is developed for integrating utility network and hydrogen network. Steam Methane Reforming process is necessary for combining two networks. After producing hydrogen from Steam-Methane Reforming process whose raw material is steam vents from utility network, produced hydrogen go into hydrogen network and fulfill own needs. Proposed model can suggest optimized case in integrated network model, optimized blueprint, and calculate optimal total cost. The capability of the proposed model is tested by applying it to Yeosu industrial complex in Korea. Yeosu industrial complex has the one of the biggest petrochemical complex and various papers are based in data of Yeosu industrial complex. From a case study, the integrated network model suggests more optimal conclusions compared with previous results obtained by individually researching utility network and hydrogen network.

• Korean Chemical Engineering Research
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• v.45 no.2
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• pp.109-116
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• 2007

As conventional light oil resources deplete, it is becoming necessary to develop unconventional resources. To meet the demand for petrochemical industry, heavier sources such as heavy oil and bitumen are being utilized. Bitumens, a complex hydrocarbon made up of a long chain of molecules, are found in oil sand. It is estimated that 830 billion barrels of oil are located in the oil sand in Alberta, Canada. This paper will review briefly (1) the basic concept of oil sand, bitumen, and heavy oil, (2) methods how to extract oil from oil sand, (3) methods how to upgrade to synthetic crude oil, and (4) economic evaluation of technology.

• Economic and Environmental Geology
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• v.21 no.4
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• pp.335-348
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• 1988

The author aimed to describe the volcano-stratigraphy and petrology of the volcanic mass in the Koheung peninsula, South Cheolla province. The volcanic mass is composed of the volcanics and intrusives of late Cretaceous which extruded the Pre-cambrian metamorphic(Jirisan gneiss complex) and the early Cretaceous sedimentary(Duwon Formation) basement. The volcanic pile consists of, in ascending order, Bibongsan andesite, Koheung tuff and breccia, and Palyeongsan welded tuff, and are intruded by ring intrusives( intrusive breccia, andesite porphyry, intrusive rhyolite and fine-grained quartz-diorite) and central pluton(diorite, quartz monzodiorite, biotite granite and micrographic granite). Bibongsan andesite mainly consists of andesite tuff and lava. Koheung tuff consists of alternation of fine tuff, coarse tuff and lapilli tuff, and Palyeongsan welded tuff which overlies Koheung tuff, comprises K-feldspar and quartz phenocrysts, elongated brown fiamme, lithic fragments in matrix of devitrified brown glass shards, and mainly consists of rhyodacite to rhyolite vitric ash-flow tuff. The results of petrochemical studies of the igneous rocks suggest that the rocks were a serial differentiational products of fractional crystallization of calc-alkaline magma series. This study reveals that the volcanic mass in this area is inferred to the remnant of the resurgent cauldron, measuring 30 by 25 km in diameter. The cauldron block was lowered at least 1,000 m by ring fault displacement.

• Advances in Energy Research
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• v.4 no.2
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• pp.147-161
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• 2016

To start with, finding a sustainable method to produce sweet water and electricity by using renewable energies is one of the most important issues at this time. So, experimental and theoretical analysis of the performance of a closed solar powered still, which is jointed to photovoltaic cells and vacuum pump and equipped by nano plate, as the principle stage of zero discharge desalination process is investigated in this project. Major goal of this work is to reuse the concentrated brine of the Mobin petrochemical complex in order to produce potable, sweet water from effluent saline wastewater and generating electricity in the same time by using solar energy instead of discharging them to the environment. It is observed the increase in brackish water temperature increases the average daily production of solar desalination still considerably. Therefore, the nano plate and vacuum pump are added to augment the evaporation rate. The insolation rate, evaporation rate, the average brackish temperature, ambient temperature, density are investigated during a year 2013. In addition to obtain the capacity of solar powered still, the highest and lowest amount of water and electricity generation are reported during a twelvemonth (2013). Results indicate the average daily production is increased 16%, which represents 7.78 kW.h energy saving comparing with traditional solar still.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.598-603
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• 2008

In petrochemical complex, Hydrogen Network optimization is surveying the extra Hydrogen and needed Hydrogen of each company and calculating the optimized distribution. This paper compares the case of using the existing pipeline and the case of not using the existing pipeline to show the effect quantitatively and clearly by modeling the both cases and using mathematical programming. As a result, using the existing pipeline can save the pipe cost over 20% and increase the whole network benefit by thirteen billion won.

• Membrane Journal
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• v.22 no.6
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• pp.381-394
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• 2012

Recently, a variety of chemical and physical methods are employed to separate ionic materials from complex aqueous. Most of all, membrane pertraction using contactor has been considered as alternative recovery and separation system in field of chemical, petrochemical and medicines because heavy metals, hydrocarbon based materials in contaminants like wastewater can be recovered by pertraction system. Also, pertraction process has characteristics such as ease of operation, lower energy consumption and operational cost, higher selectivity. This work investigates some example of developed membrane and their performance for the application of pertraction process.