• Title/Summary/Keyword: petrochemical complex

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Human Health Risk Assessment of BTEX from Daesan Petrochemical Industrial Complex (대산 석유화학 산업단지 인근 지역에서의 BTEX 인체 위해성 평가)

  • Lee, Jihyeong;Jang, Yong-Chul;Cheon, Kwangsoo;Kim, Bora
    • Journal of Environmental Impact Assessment
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    • v.31 no.5
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    • pp.321-333
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    • 2022
  • In this study, the concentration and distribution characteristics of BTEX (benzene toluene, ethylbenzene, and xylene) emitted from Daesan Petrochemical Industrial Complex were examined to determine their potential hazards to local residents. Residents living nearby the complex areas may be exposed to the chemicals through various media (air, water, and soil), especially by air. This study evaluated human health risks by inhalation using both deterministic and probabilistic risk assessment approaches. As a result of the deterministic risk assessment, the non-cancer risk was much lower than the regulation limit of hazard index (HI 1.0) for all the points. However, in case of cancer risk evaluation, it was found that the risk of excess cancer for benzene at point A located in the industrial complex was 2.28×10-6, which slightly exceeded the standard regulatory limit of 1.0×10-6. In addition, the probabilistic risk assessment revealed that the percentile exceeding the standard of 1.0×10-6was found to be 45.3%. The sensitivity analysis showed that exposure time (ET) had the greatest impact on the results. Based on the risk assessment study, it implied that ethylbenzene, toluene, and xylene had little adverse effects on potential human exposure, but benzene often exceeded the cancer risk standard (1.0×10-6). Further studies on extensive VOCs monitoring are needed to evaluate the potential risks of industrial complex areas.

Exposure Assessment of Heavy Metals using Exposure Biomarkers among Residents Living Near a Chungcheongnam-do Province Industrial Complex Area (충청남도 산업단지 인근지역 주민의 생체시료 중 중금속 농도평가)

  • Joo, Yosub;Roh, Sangchul
    • Journal of Environmental Health Sciences
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    • v.42 no.3
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    • pp.213-223
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    • 2016
  • Objectives: This study was designed to assess the level of physical exposure to heavy metals among residents who live around a Chungcheongnam-do Province industrial complex and to provide baseline data on the effects and harms of heavy metals on the human body by comparing their exposure levels to those of people from control regions. Methods: We measured blood lead and cadmium levels and urine mercury and chromium levels and conducted a survey among 559 residents from the affected area and 347 residents of other areas. Results: Blood lead and cadmium levels and urine mercury levels were significantly higher in the case region than among those in the control region (p=0.013, p<0.001, p<0.001, respectively). In the thermoelectric power plant area, blood cadmium and urine mercury levels were significantly higher than in the control region (p<0.001, p<0.001, respectively). In the steel mill and petrochemical industry areas, blood cadmium level was significantly higher than that in the control region (p<0.001). Dividing groups by the reference level of blood cadmium ($2{\mu}g/L$), the odds ratios between the case and control regions were 2.56 (95% CI=1.83-3.58), 3.11 (95% CI=2.06-4.71) for the thermoelectric power plant area, 1.78 (95% CI=1.19-2.65) for the steel mill area and 4.07 (95% CI=2.40-6.89) for petrochemical industry area. Conclusion: This study showed that the levels of exposure to heavy metals among residents living near a Chungcheongnam-do Province industrial complex were significantly higher than those in the control region. This seems to be attributable to exposure to heavy metals emissions from the industrial complex. Further research and safety measures are required to protect residents' health.

The thermal impedance spectroscopy on Li-ion batteries using heat-pulse response analysis

  • Barsoukov Evgenij;Jang Jee Hwan;Lee Hosull
    • 한국전기화학회:학술대회논문집
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    • 2001.11a
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    • pp.145-161
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    • 2001
  • Novel characterization of thermal properties of a battery has been introduced by defining its frequency-dependent thermal impedance function. Thermal impedance function can be approximated as a thermal impedance spectrum by analyzing experimental temperature transient which is related to the thermal impedance function through Laplace transformation. In order to obtain temperature transient, a process has been devised to generate external heat pulse with heating wire and to measure the response of battery. This process is used to study several commercial Li-ion batteries of cylindrical type. The thermal impedance measurements have been performed using potentionstat/galvanostate controlled digital signal processor, which is more commonly available than flow-meter usually applied for thermal property measurements. Thermal impedance spectra obtained for batteries produced by different manufactures are found to differ considerably. Comparison of spectra at different states of charge indicates independence of thermal impedance on charging state of battery. It is shown that thermal impedance spectrum can be used to obtain simultaneously thermal capacity and thermal conductivity of battery by non-linear complex least-square fit of the spectrum to thermal impedance model. Obtained data is used to simulate a response of the battery to internal heating during discharge. It is found that temperature inside the battery is by one-third larger that on its surface. This observation has to be considered to prevent damage by overheating.

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Smart composite repetitive-control design for nonlinear perturbation

  • ZY Chen;Ruei-Yuan Wang;Yahui Meng;Timothy Chen
    • Steel and Composite Structures
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    • v.51 no.5
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    • pp.473-485
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    • 2024
  • This paper proposes a composite form of fuzzy adaptive control plan based on a robust observer. The fuzzy 2D control gains are regulated by the parameters in the LMIs. Then, control and learning performance indices with weight matrices are constructed as the cost functions, which allows the regulation of the trade-off between the two performance by setting appropriate weight matrices. The design of 2D control gains is equivalent to the LMIs-constrained multi-objective optimization problem under dual performance indices. By using this proposed smart tracking design via fuzzy nonlinear criterion, the data link can be further extended. To evaluate the performance of the controller, the proposed controller was compared with other control technologies. This ensures the execution of the control program used to track position and trajectory in the presence of great model uncertainty and external disturbances. The performance of monitoring and control is verified by quantitative analysis. The goals of this paper are towards access to adequate, safe and affordable housing and basic services, promotion of inclusive and sustainable urbanization and participation, implementation of sustainable and disaster-resilient buildings, sustainable human settlement planning and manage. Therefore, the goal is believed to achieved in the near future by the ongoing development of AI and control theory.

Relationship between residential district and health-related quality of life in Chungnam industrial complex area

  • Kim, Heechan;Roh, Sangchul
    • Environmental Analysis Health and Toxicology
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    • v.31
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    • pp.17.1-17.7
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    • 2016
  • Objectives This study aimed to evaluate the relationship between residential district of people, such as power plant, steel-mill and petrochemical industries, and health-related quality of life (HRQoL). Methods Using a cross-sectional study design, we randomly recruited participants for our study from industrial areas (thermoelectric power plant, steel-mill, petrochemical industry) and rural areas. Logistic regression analysis was used to identify the relationships between Euro quality of life-5 dimension (EQ-5D) scores and living region, while controlling for sociodemographic characteristics. Results In adjusted model, quality of life decreased with increasing category of age and were lower for females than males. EQ-5D scores of people living in the vicinity of thermoelectric power plant were significant lower than those of people living the vicinity of comparison region (odds ratio, 1.59; 95% confidence interval, 1.00 to 2.53). Conclusions Living region of thermoelectric power plant, was strongly associated with scores on the EQ-5D. More research is needed to elucidate the mechanisms which makes the relationship with the living regions and HRQoL.

A Study on the Pollution of Nonylphenol in Surface Sediment in Gwangyang Bay and Yeosu Sound (광양만과 여수해만의 표층퇴적물에서 Nonylphenol의 오염에 관한 연구)

  • Jo, Hyeon Seo;Kim, Yong Ok;Seol, Sun U
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.561-570
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    • 2004
  • This study was carried out to survey the pollution of nonylphenol (NP) in surface sediments around Gwangyang bay and Yeosu sound. NP was suspected chemicals as endocrine disruption. Gwangyang bay is located on the mid south coast of Korea. It is a semi-closed bay which Yeosu petrochemical industrial complex, POSCO (Pohang Steel Company) and Gwangyang container harbor are there. The surface sediments were collected at 15 stations with gravity corer at October, 1999, February, May and August, 2000. Also, the stream and intertidal sediment were collected at 5 sites at August, 2000. Concentrations of NP in surface sediments were in the range of 6.89 to 202.70 ng/g dry wt.. Seasonal range (mean value) of NP is 13.98 to 30.48 (23.46) ng/g dry wt. at October, 10.35 to 54.91 (28.10) ng/g dry wt. at February, 29.05 to 202.70 (82.32) ng/g dry wt. at May and 6.98 to 83.40 (25.37) ng/g dry wt. at August. NP was seasonally fluctuated, and the highest mean value and range was detected at May, 2000. NP was highly distributed in the inner part of Gwangyang bay than Yeosu sound. Concentrations of NP in stream and intertidal sediments showed the highest value in downstream near Yeosu petrochemical industrial complex and Yondung stream. It suggests that the source of NP is industrial wastewater and municipal sewage.

Electrospinning of Asiaticoside/2-Hydroxypropyl-β-cyclodextrin Inclusion Complex-loaded Cellulose Acetate Fiber Mats: Release Characteristics and Potential for Use as Wound Dressing (Asiaticoside/2-Hydroxypropyl-β-cyclodextrin 포접화합물 함유 셀룰로오스 아세테이트 섬유 매트의 전기방사: 창상피복제로서 사용가능성과 방출특성)

  • Panichpakdee, Jate;Pavasant, Prasit;Supaphol, Pitt
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.338-350
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    • 2014
  • Cellulose acetate (CA) fiber mats containing inclusion complexes of asiaticoside (AC) in 2-hydroxypropyl-${\beta}$-cyclodextrin ($HP{\beta}CD$) for potential usage as wound dressings were developed. The AC/$HP{\beta}CD$ complex-loaded CA fibers at various $HP{\beta}CD$ to AC molar ratios of 0.5, 1, and 2 were prepared in 90:10 v/v mixture of 80% (v/v) acetic acid and N,N-dimethylacetamide (DMAc) via electrospinning. The maximum released amounts of AC depended on the $HP{\beta}CD$ content and were much greater than those released from the AC-loaded CA fiber mat. In the in vitro study, indirect cytotoxic evaluation with human dermal fibroblasts (HDFa) showed that these materials released no substances in the levels that were harmful to the cells and the cells appeared to attach and proliferate well on these substrates. However, only the CA fiber mats containing AC/$HP{\beta}CD$ complexes at the $HP{\beta}CD$ to AC molar ratio of 0.5 was effective in upregulating the production of collagen of the cultured cells.