• Macromolecular Research
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• v.17 no.8
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• pp.616-622
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• 2009

In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{\circ}C$ and 394 $^{\circ}C$)were higher than those of o-TPU (342 $^{\circ}C$ and 391 $^{\circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{\circ}C$ and 381 $^{\circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.5
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• pp.355-374
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• 2022

Soil conditioning improves the performance of EPB (earth pressure balance) shield TBMs (tunnel boring machines) by reducing shear strength, enhancing workability of the excavated soil, and supporting the tunnel face during EPB tunnelling. The mechanical and rheological behavior of the excavated muck mixed with additives should be properly evaluated to determine the optimal additive injection condition corresponding to each ground type. In this study, the laboratory pressurized vane test apparatus equipped with a vane-shaped rheometer was developed to reproduce the pressurized condition in the TBM chamber and quantitively evaluate rheological properties of the soil specimens. A series of the pressurized vane tests were performed for an artificial sand soil by changing foam injection ratio (FIR) and polymer injection ratio (PIR), which are the injection parameters of the foam and the polymer, respectively. In addition, the workability of the conditioned soil was evaluated through the slump test. The peak and yield stresses of the conditioned soil with respect to the injection parameters were evaluated through the rheogram, which was derived from the measured torque data in the pressurized vane test. As FIR increased or PIR decreased, the workability of the conditioned soil increased, and the maximum torque, peak stress, and yield stress decreased. The peak stress and yield stress of the specimen from the laboratory pressurized vane test correspond to the workability evaluated by the slump tests, which implies the applicability of the proposed test for evaluating the rheological properties of excavated soil.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.568-573
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• 2010

Adhesive strength was evaluated for the polyester fabric treated with various concentration of polymeric isocyanate to introduce functional group on the surface. Also experiments were performed to find out the type of latex, F/R mole ratio, and FR resin/latex weight ratio for the RFL solution to optimize adhesion between HNBR compound and the treated polyester fabric. Optimum adhesion strength was obtained when 7 wt% of the concentration of polymeric isocyanate, NBR latex because of the compatibility of HNBR compound, 1/1 of F/R mole ratio, and 20 wt% of FR resin/latex were applied. Optimum cure temperature for the RFL solution was $200^{\circ}C$ according to the results of peel test and the reason was determined by analyzing the ATR FTIR spectra of the RF resin according to the curing temperature.

• Journal of the Korean Ceramic Society
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• v.42 no.6 s.277
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• pp.377-383
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• 2005

Generally, the strength achieved of glass-ceramics is higher as is the fracture toughness, as compared with the original glass. This improvement is due to the microstructure consisting of very small crystals. In this study, Ag-doped $45SiO_2-24CaO-24Na_2O-4P_2O_5$ glasses were irradiated to strengthen by the crystallization using Femto second laser Pulses. Through the UV/VIS spectroscope, XRD, Nano-indenter and SEM etc., heat-treated and irradiation of laser pulses without heat-treated samples were analyzed. Two kinds of samples, heat-treated and laser irradiated without heat-treated samples, showed the peaks in the same wavelength near 360 nm. Especially, samples irradiated by 140 mW laser with XYZ stage having at the rate of 100$\~$l000 $\mu$m/s had the largest absorption peak among them, and heat-treated samples was shown lower absorption range than over 90 mW laser irradiated samples. Moreover, samples irradiated by laser had higher values ($4.4\~4.56{\times}10^{-3}(Pa)$) of elastic modulus which related with strength of glass than values of heat-treated samples and these are 1.2$\~$1 .5 times higher values than them of mother glass.

• Fashion & Textile Research Journal
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• v.14 no.6
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• pp.1024-1031
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• 2012

The thermal bonding PET fabrics were produced through high temperature steaming (HTS) of low melting PET yarn as warp and composite fancy yarn containing low melting PET yarn as weft. The low melting PET yarn of sheath-core structure consisted of a regular PET in core portion and low melting PET in sheath portion. The composite fancy yarn consisted of regular PET yarn as inner part and effect part and low melting PET yarn as binding part. This study was carried out to investigate the melting behavior of thermal bonded PET fabric, the effect of HTS on the thermal bonding, mechanical properties, and dyeing properties. The melting peak of low melting PET yarn showed two melting peaks caused by sheath-core structure. Almost the entire thermal bonding of the fancy PET fabrics containing low melting PET yarn has formed at $200^{\circ}C{\times}3min$ of HTS. The tensile strength in warp and weft direction of the fancy PET fabrics slightly decreased as temperature of HTS increased. The total K/S value of the fancy PET fabrics decreased slightly to $180^{\circ}C{\times}3min$ of HTS, while increased slightly above $200^{\circ}C{\times}3min$ of HTS. The changes in the hue angle ($H^{\circ}$) of the thermal bonded fancy PET fabrics dyed with disperse dyes hardly ever happened.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.1
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• pp.64-73
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• 2010

This study was conducted to modify the surface properties of papers by formation of hydrophobic self-assembled monolayer(SAM) on paper surface with silanes. A base paper I(0.5% AKD) and base paper II(1.0-1.5% AKD) were reacted with silanes(PFDTES, DMDCS, MODDCS) by immersion method and vapor deposition method. Hydrophobic SAMs(contact angle value>$120^{\circ}C$) were obtained on all papers after treatment with $10^{\mu}l$ PFDTES for 15min, with $50^{\mu}l$ DMDCS for 30min, with $50^{\mu}l$ MODDCS for 300min. When applying PFDTES to paper surface, lower silane concentration and shorter reaction time were required, whereas MODDCS with long alkyl chain required the longest reaction time of 300min. The st$\ddot{o}$ckight sizing degree of silane treated papers were increased between 105sec(base paper I) and 130sec(base paper II). The wet tensile strength of PFDTES-treated base papers(I, II) increased by 10-34% after SAM formation. However, the wet tensile strength of the DMDCS-treated base paper(I) was found to decrease from 0.067kN/m to 0.038kN/m; this may due to the cellulose degrading as a result of generated hydrogen chloride when hydroxyl group of cellulose were reacted with DMDCS. No apparent changes of PPS roughness on silane-treated papers are observed. The ATR-IR spectrum showed absorption peak located at 465 and 1200cm-1 which can be assigned to the Si-O-C asymmetric stretching and Si-O-C bonds, respectively.

• Korean Journal of Materials Research
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• v.22 no.9
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• pp.454-458
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• 2012

Various adhesive materials are used in flip chip packaging for electrical interconnection and structural reinforcement. In cases of COF(chip on film) packages, low temperature bonding adhesive is currently needed for the utilization of low thermal resistance substrate films, such as PEN(polyethylene naphthalate) and PET(polyethylene terephthalate). In this study, the effects of anhydride and dihydrazide hardeners on the low-temperature snap cure behavior of epoxy based non-conductive pastes(NCPs) were investigated to reduce flip chip bonding temperature. Dynamic DSC(differential scanning calorimetry) and isothermal DEA(dielectric analysis) results showed that the curing rate of MHHPA(hexahydro-4-methylphthalic anhydride) at $160^{\circ}C$ was faster than that of ADH(adipic dihydrazide) when considering the onset and peak curing temperatures. In a die shear test performed after flip chip bonding, however, ADH-containing formulations indicated faster trends in reaching saturated bond strength values due to the post curing effect. More enhanced HAST(highly accelerated stress test) reliability could be achieved in an assembly having a higher initial bond strength and, thus, MHHPA is considered to be a more effective hardener than ADH for low temperature snap cure NCPs.

• Tunnel and Underground Space
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• v.9 no.4
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• pp.350-363
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• 1999

The precision cyclic shear test system was established to investigate the mechanical characteristics of rough rock joints under cyclic loading conditions. Laboratory cyclic shear tests were conducted for saw-cut joints and artificial rough rock joints using Hwangdeung granite and Yeosan marble. Surface roughness and aperture characteristics of specimens were examined by measuring surface topography using the laser profilometer. Peak shear strength, phase difference during loading and unloading, and anisotropic shear behavior were investigated throughout the cyclic shear test results. These features and their subsequent variations in each loading cycle are significantly dependent upon the second order asperities and the strength of intact rock. It was observed that degradation of asperities for rough rock joints under cyclic shear loading followed the exponential degradation laws of asperity angle and that the mechanism for asperity degradation would be different depending upon the normal stress level, roughness of joint surface and the loading stage.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.4
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• pp.95-106
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• 1992

This paper presents a comparative evaluation of five different types of steel fibers used as reinforcing material in concrete beams. Two types of plain and RC beams were prepared to compare the relative flexural behavior. The fibers used were dog bone (paddled), both ends hooked. コ-type straight. crimped and wavy type with aspect ratio of 43 to 75. Fiber volume fraction of 1 to 2% were used while shear span to depth ratio (aid) and steel ratio p were fixed. Fiber reinforcement effect index Ef and effective toughness index Te were adopted to evaluate fiber reinforcing effects. The effect of fiber reinforcement on flexural strength is higher in plain beams than in RC beams. Hooked and dog bone type fibers were found to be more effective than the other type ones in enhancing the flexural strength and post-peak energy absorption capacity of concrete beams.

• Applied Chemistry for Engineering
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• v.5 no.6
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• pp.981-989
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• 1994

For the development of new material used bentonite in ceramic/organic material composite, ABS(acrylonitrile-butadiene-styrene) material was used as a matrix polymer and a series of bentonite was blended together. This bentonite, filler like talc or mica for plastic material, was used since natural bentonite(Ca type) is easily obtainable in Korea, Na-bentonite changed from natural bentonite by $Na_2CO_3$ based on the specified compositions, changes in the static and dynamic mechanical properties. It was discovered that the increased content of natural and Na- bentonite results in higher modulus with reduced impact strength. And Rockwell hardness was constant. And Na- bentonite filled polymer showed improvement in impact strength and lower in modulus as the natural bentonite filled polymer. The storage modulus(E') of Na- bentonite filled ABS resin was higher than that of Ca- bentonite filled ABS resin, while higher temperature, storage modulus(E') decreased. At higher frequency, tan ${\delta}$ peak was shifted at high temperature.