• Title/Summary/Keyword: pce

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사상분진과 열연슬러지를 이용한 TCE, PCE의 제거

  • 이용재;박규홍;박준범;이재원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.356-359
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    • 2003
  • 영화유기화합물의 제거에 있어서 일반적으로 이용되는 금속분말로는 아연, 주석, 니켈, 납, 철 등이 알려져 있으며, 경제성과 반응성이 좋고, 독성을 야기하지 않는다는 측면에서 영가 철이 가장 많이 연구·실용화되어 적용되고 있는 실정이다. 본 연구에서는 제철부산물들의 비표면적 측정, 화학적 구성성분 분석 및 pH의 변화를 통해 TCE, PCE 제거능력 평가 및 탈염소화반응을 확인하였으며, 제철부산물인 사상분진과 열연슬러지가 TCE 및 PCE의 제거효율적인 측면이나 산업폐기물의 재활용적인 측면에서 순수철보다 우수하다는 것을 확인하였다.

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Oxidative Degradation of PCE/TCE Using $KMnO_4$ in Aqueous Solutions under Steady Flow Conditions (유동조건에서 $KMnO_4$도입에 따른 수용액중 PCE/TCE의 산화분해)

  • Kim, Heon-Ki;Kim, Tae-Yun
    • Economic and Environmental Geology
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    • v.41 no.6
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    • pp.685-693
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    • 2008
  • The rates of oxidative degradation of perchloroethene (PCE) and trichloroethene (TCE) using $KMnO_4$ solution were evaluated under the flow condition using a bench-scale transport experimental setup. Parameters which are considered to affect the reaction rates tested in this study were the contact time (or retention time), and the concentration of oxidizing agent. A glass column packed with coarse sand was used for simulating the aquifer condition. Contact time between reactants was controlled by changing the flow rate of the solution through the column. The inflow concentrations of PCE and TCE were controlled constant within the range of $0.11{\sim}0.21\;mM$ and $1.3{\sim}1.5\;mM$, respectively. And the contact time was $14{\sim}125$ min for PCE and $15{\sim}36$ min for TCE. The $KMnO_4$ concentration was controlled constant during experiment in the range of $0.6{\sim}2.5\;mM$. It was found that the reduction of PCE and TCE concentrations were inversely proportional to the contact time. The exact reaction order for the PCE and TCE degradation reaction could not be determined under the experimental condition used in this study. However, the estimated reaction rate constants assuming pseudo-1st order reaction agree with those reported based on batch studies. TCE degradation rate was proportional to $KMnO_4$ concentration. This was considered to be the result of using high inflow concentrations of reactant, which might be the case at the vicinity of the source zones in aquifer. The results of this study, performed using a dynamic flow system, are expected to provide useful information for designing and implementing a field scale oxidative removal process for PCE/TCE-contaminated sites.

Effects of Direct-fed Microbial and Pine Cone Extract on Carcass Traits and Meat Quality of Hanwoo (Korean Native Cattle)

  • Muhlisin, Muhlisin;Song, Chang Soo;Rhee, Yong Joon;Song, Young Han;Lee, Sung Ki
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.5
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    • pp.722-730
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    • 2016
  • The carcass traits and meat quality of Hanwoo (Korean native cattle) whose diets were supplemented with direct-fed microbial (DFM) and pine cone extract (PCE) were evaluated. Twenty head of Hanwoo steers were divided equally into four groups and for a period of 6 months were given different diets: One group was fed a basal diet as control (CON), the other three groups were fed a basal diet supplemented with DFM-1%, DFM+PCE-1% and DFM+PEC-3%, respectively. DFM+PCE3% diet resulted the lowest carcass quality grade. The loins of DFM-1% contained higher moisture and lower fat than did the loins from the CON group. The crude protein content of DFM+PCE-3% group was significantly higher than that of the other groups. The water holding capacity and Warner-Bratzler shear force of the DFM+PCE-1% and 3% groups were lower than those of the CON and DFM-1% groups. The DFM-1% and 3% groups contained lower saturated fatty acid, higher unsaturated fatty acid, mono-unsaturated fatty acid, and poly-unsaturated fatty acid than did CON and DFM+PCE 1% group. Moreover, the n6:n3 ratios of DFM-1% and DFM+PCE-1% and 3% groups were slightly lower than that of the CON group. Thus we concluded that DFM and PCE supplementation resulted healthier Hanwoo beef with lower fat content and n6:n3 ratio.

The Anti-inflammatory Effects of Golden Apple Snail (Pomacea canaliculata) in Reflux Esophagitis Model (왕우렁이 추출물의 역류성 식도염 억제 효과)

  • Nam, Hyeon Hwa;Ryu, Seung Mok;Yang, Sungyu;Kim, Wook Jin;Moon, Byung Cheol;Seo, Yun-Soo
    • Korean Journal of Organic Agriculture
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    • v.29 no.1
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    • pp.85-96
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    • 2021
  • Reflux esophagitis (RE) is a common gastrointestinal disease observed at all ages, which seriously affects the quality of life. In this study, we investigated the anti-inflammatory effects of Pomacea canaliculata extract (PCE) using the experimental RE rat model. RE was induced by a surgical procedure. The rats were randomly divided into 4 groups: normal group, RE group, PCE group (RE treated with PCE, 100 mg/kg), positive control group (RE treated with ranitidine, 40 mg/kg). We performed the histological examination and measured the expression of tight junction complex and inflammatory mediators using western blot analysis. The phenotypes of RE were attenuated by PCE treatment. PCE administration significantly reduced esophageal mucosal damage and protected tight junction confirmed by claudin-5. Furthermore, PCE treatment reduced inflammatory reaction by inhibiting the expression of COX-2 and TNF-α. PCE treatment, also, reduced translocation of NF-κB into nuclear and IκB-α phosphorylation at the same time. Our findings indicate that PCE has the potential as a novel therapeutic agent to inhibit RE by protecting mucosal damage and regulating inflammatory reactions mediated by NF-κB signaling.

An Analyical Study for Estimating Passenger Car Equivalents of Heavy Vehicles (대형차의 승용차 환산계수의 산정을 위한 해석적 연구)

  • 박창호;윤항묵;전경수
    • Journal of Korean Society of Transportation
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    • v.8 no.2
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    • pp.99-107
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    • 1990
  • This research addresses the effect of heavy vehicles (especially trucks) in terms of passenger car Equivalents from a capacity viewpoint. A formulation that estimate PCE in this paper is derived by introducing appropriate headway measurements into Huber's general equation for PCEs. In this equation, PCE value is expressed in terms of headways for four different kinds of pairs; pairs of leading and following vehicles ; P-P, P-T, P-T, T-T. The mean value of headway for each case is estimated through the regression analysis. Finally, the approach used in this research was compared with macroscopic approach which analyzed a speed-density relationship to evaluate PCE.

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Synergism effect of mixed surfactant solutions in remediation of soil contaminated with PCE

  • Lee, Dal-Heui
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.47-51
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    • 2004
  • The purpose of this research was to evaluate the effect of mixed surfactant solution for removal of perchloroethylene (PCE) in soil. Ten different surfactant solutions were used in column studies. Mixed surfactant solutions (anionic and nonionic) were most effectively worked in the sandy soil for removal of PCE as a result of synergism between the two types of surfactants. The effectiveness of the mixture of surfactants was 35 % greater than that for the anionic or nonionic surfactant alone. The results indicate that mixed surfactant solution leaching is a promising candidate for the remediation of PCE contaminated sandy soil.

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Characteristics of Trichloroethene and Tetrachloroethene Sensing Optical Fiber Biosensor Using Toluene-o-monooxygenase and Fluoresceinamine (Toluene-o-monooxygenase와 Fluoresceinamine을 이용한 Trichloroethene와 Tetrachloroethene 감지용 광섬유 바이오센서의 특성)

  • Ryoo, Doohyun
    • Journal of Soil and Groundwater Environment
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    • v.23 no.4
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    • pp.42-47
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    • 2018
  • E. coli TG1 pBS TOM Green was cultured to produce toluene-o-monooxygenase (TOM). A biosensor system was successfully constructed using purified TOM to effectively detect trichloroethene (TCE) and tetrachloroethene (PCE), which represent some of the major contaminants in groundwater and soil. In order to utilize TOM as a sensor, NADH, a biological oxidizer, was replaced with hydrogen peroxide which is a chemical oxidizing agent. A three-layered sandwich-type sensing tip was fabricated on the outside of the hydrophilic polyvinylidene fluoride membrane. TCE and PCE were applied to the sensor and the hydrogen ions were measured by a fiber optic fluorometer using fluoresceinamine. Calibration curves were obtained for TCE and PCE in the concentration range of 0.2-100 mg/l, and the detection limit of the system was $10{\mu}g/l$ for TCE and PCE.

Toluene Monooxygenase의 Peroxide shuntting에 의한 TCE와 PCE 분해 특성

  • 류두현;김형수;최용욱;김용미;이경애;유재수;조현
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.277-280
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    • 2004
  • TCE and PCE, suspected carcinogens, are the most common groundwater pollutant from extensive use as a solvent and degreaser. Escherichia coli TGI pBSKAN TOM Green and E. coli TGI pBSKAN ToMO, which were used DNA shuffling technique, produce Toluene-o-monooxygenase(TOM) and toluene-o-xylene- monooxygenase(ToMO). These cells and enzymes are degrading TCE and PCE, TOM and ToMO are needed to cofactor, such as NADH, NADPH and other cofactors. Used TCE and PCE degrading microorganisms experiment the contaminated material removal efficiency. A shunting test used NAD and Hydrogen peroxide.

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Dechlorination of PCE Using Zero-Valent Iron and Surfactants (Fe$^{0}$ 과 계면활성제를 이용한 PCE의 탈염소화 반응에 관한 연구)

  • 조현희;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.119-123
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    • 2000
  • In-situ treatment technologies have been proposed to transform or remove pollutants from contaminated groundwater. Zero-valent iron(Fe$^{0}$ ), metallic iron, is being evaluated as a permeable reactive material to retard the transport of wide array of highly mobile contaminants in groundwater. In this research, tetrachloroethylene(PCE) dechlorination by powdered zero-valent iron in buffered aqueous solution was studied with and without the presence of surfactants. The rate of dechlorination of PCE by zero-valent iron with surfactant was much higher than without surfactant. The presence of surfactant increased the apparent rate of dechlorination because the surfactants influenced the dissolution of PCE into the aqueous phase.

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The effect of permeable geobarrier using gravel bean and silty clay for remediation of PCE contaminated groundwater (자연지질매체를 이용한 PCE로 오염된 지하수 정화)

  • Lee Dal-Hui;Jeon Lee-Won;Jang Ho-Wan;Lee Jong-Yeol;Seo Hyeong-Gi
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.110-113
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    • 2005
  • The objective of this study was to examine the effect of proposed permeable eobarrier system for removal of PCE from groundwater. The materials used for the natural geobarrier are gravel bean and silty clay. In addition, the effect of Pyeongtaek soil on PRB assessed in this experiments. It was observed that the adsorption of PCE in natural geobarrier system is eligible for real site. However, natural geobarrier system has various factors based on using materials. Therefore, more laboratory work is needed to study about permeable geobarrier.

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