• Title/Summary/Keyword: pcbs

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Evaluation of Polychlorinated Biphenyls(PCBs) and Organochlorine Insecticide Residues in Irrigation Waters in the Periphery of Suwon (수원근교(水原近郊) 관개수중(灌漑水中)의 PCBs 및 유기염소계(有機鹽素系) 살충제(殺蟲劑)의 잔류평가(殘留評價))

  • Lee, Youn-Hyung;Hwang, Eul-Chul;Park, Chang-Kyu
    • Korean Journal of Environmental Agriculture
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    • v.4 no.2
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    • pp.95-101
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    • 1985
  • Water samples collected monthly between November 1982 and October 1983 from seven reserviors and a river in the periphery of Suwon, Korea were subjected to gas chromatographic analysis for PCBs and organochlorine insecticide residues. PCBs were positively detected in the most samples. The average residue levels of PCBs were found in the range of 0.009${\sim}$0.5 ppb while those of organochlorine insecticides were in the range of "not detected"${\sim}$0.008 ppb. The ratio of average residue levels of PCBs to those of total DDT was found to vary with sampling sites. The highest ratio of 500 was found in the water samples of Han River and the lowest in water of Won-chun Reservior. Both industrial and urban waste appear to be responsible for PCBs in the irrigation waters.

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Congener Specific Characteristics of PCBs and PCDD/Fs and Risk Assesment for Human Milk of Korea (국내 모유에서의 PCBs 및 PCDD/Fs 분포 특성과 위해성 평가)

  • Yang, Yoon-Hee;Chang, Yoon-Seok;Kim, Byung-Hoon;Yang, Ji-Yoen;Shin, Dong-Chun
    • Analytical Science and Technology
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    • v.13 no.4
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    • pp.520-533
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    • 2000
  • We analyzed the PCDD/Fs and PCBs in human milk samples from a city and an industrial region by HRGC/HRMS. The average concentrations of PCDD/Fs and PCBs in human milk were 15.13 TEQ pg/g fat and 5.64 TEQ pg/g fat respectively. We discovered two kinds of homologue distributions. We compared congeners of each distributions with those of the commercial PCBs products. The daily intake of infant was predicted to be 60 TEQpg/kg/day according to the mean concentration of PCDD/Fs based on primipara. This value is much higher than the estimated range for background exposure to adult in the USA (1-3 TEQ pg/g fat).

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Rapid analytical method of the polychlorinated biphenyls in PCBs containing liquid wastes (PCBs 함유 액상폐기물의 신속분석방법 고찰)

  • Shin, Sun-Kyoung;Jeon, Tae Wan;Yoon, Jeong-Ki;Kim, Tae-Seung;Oh, Gi Jong;Kim, Young Shik;Kim, Kyoung Soo
    • Analytical Science and Technology
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    • v.21 no.3
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    • pp.174-182
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    • 2008
  • The study on the development of rapid analytical method of PCBs containing waste was performed by considering the extraction, column cleanup process, analytical condition and so on. In the established method, new sample clean-up procedure, new quantification peaks and temperature program were introduced. Method detection limit of the method was 0.5 mg/L, and the method could save the total run time to 2/3, therefore save the analysis cost, The new rapid analytical method of transformer oil was suggested to the waste official test method.

PCBs 오염토양의 생물학적 처리

  • Na In-Uk;Hwang Gyeong-Yeop;Choi Ji-Won;Kim Seon-Mi;Choi Su-Jin
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.49-53
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    • 2006
  • The possibility of removal of PCBs (Polychlorinated Biphenyls) in soil was studied using biological method. The effects of soil and co-substrate on both PCBs reduction rate and chloride ion concentration in soil were investigated. It was shown that PCBs concentration of all the soils used in this study were reduced from 5ppm to below 1ppm after 60days, also chloride ion concentration in slurry increased, Results showed that leaf mold and humic acid as co-substrate do not seem to be effective for biological treatment of PCBs in soil,

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Pool Combustion of Iso-Propanol Fuel including IPA and PCBs in different Type Vessels

  • An Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.102-108
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    • 2006
  • On the refutation demanded for a control of various toxic substances. PCBs(poly chlorinated biphenyl) has a fatal poisonous matter in the ecosystem and the environmental pollution as it Is a kind of stable chemical substance. Especially, the gross Product of PCBs is estimated at about one million tonnage all over the world. However it is kept on storing in untreated state, then has a deterioration by the Prolonged storage and a risk of overflowing. Therefore, this research examined the fundamental characteristics of combustion and emission for the target of using the IPA (iso-propyl alcohol) solution as a part of PCBs control. IPA was filled to three kinds of Vessel, i.e. Vessel I, II, and III, and then was investigated as follows combustion shape, flame temperature. mass burning velocity, and PM(Particulate matter). A radial thermometer and a C-A thermocouple measured the flame temperature, and the optical extinction method by using He-Ne laser and the filter weight method used in the PM measurement. As a result, with an increasing of L/S ratio, the flame length become shorter and the burning velocity is more rapid, but the particulate matters is higher. It is supposed that the air flow rate is high on Vessel. and then the combustion is Promoted in the surface area of the upstream zone. The future works plan to investigate the characteristics with an using of the mixing of IPA and PCBs

Residues of Co-planar PCBs in Ginseng at Environment of North Gyeongbuk (경북 북부 인삼 재배환경 중 Co-planar PCBs의 잔류)

  • Kim, Jung-Ho
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.987-995
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    • 2011
  • Co-planar PCBs(polychlorinated biphenyls) of non-ortho are investigated in soil and ginseng on the North Gyeongbuk with HRGC/HRMS. PCB77 in soil on Yeongju and Sangju are detected 0.0007 pgTEQ/g and 0.0009 pgTEQ/g, respectively. PCB81 in soil on Yeongju and Sangju are detected 0.0113 pgTEQ/g and 0.0108 pgTEQ/g, respectively. Also PCB126 in soil on Yeongju and Sangju are detected 0.0907 pgTEQ/g and 0.0944 pgTEQ/g, respectively. But PCB169 in soil on Yeongju and Sangju is not detected. Total Co-planar PCBs of non-ortho in soil on Yeongju and Sangju are 0.1027 pgTEQ/g and 0.1061 pgTEQ/g, respectively. PCB77 in ginseng on Yeongju and Sangju are detected 0.0008 pgTEQ/g. Then PCB81 in ginseng on Yeongju and Sangju are detected 0.0104 pgTEQ/g and 0.0112 pgTEQ/g, respectively. But PCB126 in ginseng on Yeongju and Sangju are detected 0.0585 pgTEQ/g and 0.0579 pgTEQ/g, respectively. PCB169 in ginseng on Yeongju and Sangju is not detected. Total Co-planar PCBs of non-ortho in ginseng on Yeongju and Sangju are 0.0697 pgTEQ/g and 0.0700 pgTEQ/g, respectively. Relationship of PCBs in between soil and ginseng shown significance($R^2$ : 0.99).

Depositional Characteristics of Atmospheric PCBs in Several Media Used Passive Air Samplers (대기 중 PCBs의 PAS에 이용되는 여러 매체의 PCBs 침착 특성)

  • Chun, Man-Young
    • Journal of Environmental Health Sciences
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    • v.39 no.2
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    • pp.151-158
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    • 2013
  • Objective: This study was carried out to determine the depositional characteristics of pine needles, pine tree bark, moss, and soil, which are used as a passive air sampler (PAS) of atmospheric polychlorinated biphenyls (PCBs). Methods: All four media were sampled from the same site. PCB concentrations were analyzed by GC/MSD, and the lipid contents were measured using the gravimetric method. Results: The total PCB concentration (IUPAC No. 28, 52, 101, 138, 153, 180) was the highest in soil (227.97 pg/g dry), followed by pine needles (71.36 pg/g dry), pine tree bark (44.58 pg/g dry), then moss (21.91 pg/g dry). Pine needles contained the highest lipid contents (21.31 mg/g dry), whereas soil (10.01 mg/g dry), pine tree bark (4.85 mg/g dry), and moss (1.92 mg/g dry) contained less. The concentration of lower-chlorinated PCBs was relatively high in pine needles, pine tree bark and moss, but not in soil. The PCB concentrations were proportional to their lipid contents in pine needles, pine tree bark and moss, but a different trend was revealed in soil. Conclusions: The PCBs concentrations in the media were affected by various factors including atmospheric PCB concentrations, lipid contents, and depositional pathways. However, each of these factors had a varying influence depending on the type of medium.

Bioaccumulation of Polychlorinated Biphenyls (PCBs) and Organochlorine Pesticides in Manila Clams (Ruditapes philippinarum) Collected from the Mid-western Coast of Korea

  • Choi, Jin-Young;Yang, Dong-Beom;Hong, Gi-Hoon
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.237-245
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    • 2010
  • Bioaccumulation of polychlorinated biphenyls (PCBs) and organochlorine pesticides was studied in sediment dwelling bivalves, Manila clams (Ruditapes philippinarum), collected from the midwestern coast of Korea. As witnessed by the dominance of tetra- to penta-chlorinated congeners in sediments and the penta- to hexa-chlorinated congener dominance in clams, the profile of PCBs in the sediments and Manila clams differed. Lipid and organic carbon-normalized biota-sediment accumulation factors (BSAFs) were determined for organochlorine pesticides. BSAFs of $\beta$-hexachlorocyclohexane ($\beta$-HCH) and $\Sigma$DDTs were in the range of 0.06~1.36 and 0.31~1.06. No clear relationships were found between BSAFs of $\Sigma$DDTs in Manila clams and the concentrations of DDTs in the associated sediment. The accumulated PCBs and organochlorine pesticides were compared in Manila clams and oysters (Crassostrea gigas) collected from 3 sites. Highly chlorinated PCBs were more commonly found in oyster tissues than in clam tissues. The reasons for the different accumulation pattern of organic pollutants in the two organisms are discussed.

Voluntary Insurance for Ensuring Risk-Free On-the-Go Banking Services in Market Competition: A Proposal for Bangladesh

  • Rahman, Akim M.
    • The Journal of Asian Finance, Economics and Business
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    • v.5 no.1
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    • pp.17-27
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    • 2018
  • In 21st Century business world, services are carried out in multifaceted, competitive and rationality manner that are characterized by evolving many factors, which are often unpredictable. On-the-go banking is a product in financial sector. However, it faces serious pitfalls being it riskiness. Bank customers compete for time-saving options. On contrary, PCBs compete for marginalizing its operating costs for enhancing its revenues. On strategic tactics, PCBs targets city customers in multi-facets including offering incentives for enhanced usages of on-the-go banking. Influencing customer's intention, attitude and behavior in banking, PCBs also offers incentive under market system along with often informational asymmetry. However, it causes exploitation. In most cases customers don't read terms & conditions of services. They don't save contract-copy. These weaknesses cause abuses. Customer faces hidden charges, extra fees, account hacked. Addressing the issue, Voluntary Insurance Option is proposed where PCBs will introduce it as a product of bank-services. Transferring risk away from customer will benefit both PCBs and bank-customers. This product can attract new customers who were on the brink using digital banking but just felt it was too risky. This model can facilitate the parties involved for increasing usage of on-the-go banking-services while customers can maintain optimal utility of usages.

PCBs concentration and congener distribution in transformer insulation oil samples using GC/ECD and HRGC/HRMS analysis (GC/ECD와 HRGC/HRMS 분석을 이용한 변압기 절연유 중 PCBs 농도 및 이성체 분포)

  • Kim, Kyoung-Soo;Kim, Hyoung-Seop;Song, Byung-Joo;Jeong, Mi-Jeong;Kim, Jong-Guk;Park, Seok-Un;Shin, Sun-Kyoung
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.232-240
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    • 2005
  • The total PCBs level in the transformer insulation oil samples using GC/ECD and HRGC/HRMS were ranged from 0.087 to $223.6{\mu}g/g$ and ranged from N.D. to $154.04{\mu}g/g$, respectively. The calculated TEQ values were ranged from 0.00067 to 6.8 ng WHO-TEQ/g. Among the samples, 6 samples showed higher than 2 ppm concentration (specific waste criterion of Korea). A variety in the concentration of total PCBs were observed between ECD and HRMS analysis. This is maybe due to quantification mehtod. The Aroclor 1248 wasn't present in the samples. The distribution pattern of Co-PCB congeners showed that the ratio of monoortho substituted congeners were higher than non-ortho substituted congeners. Among that, PCB-167 congener was predominant. In addition, the distribution of Co-PCBs congeners was different with that of flue gas and ambient air samples as well as commercial PCB formulations (Aroclor, Kanechlor).