• Title/Summary/Keyword: paste-fill

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Screen printed c - Si solar cell의 전면 전극 Finger width 및 spacing 최적화에 대한 연구

  • Kim, Sang-Seop;Choe, Jae-U;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.391-391
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    • 2011
  • Crystalline silicon solar cell을 양산에 적용하기 위해 전면 전극의 패턴을 형성하는 방법으로 Ag paste를 이용한 screen printing이 가장 일반적으로 사용된다. 전면 전극의 패턴 형성 시, Finger의 width와 spacing은 Fill factor, JSC, VOC 등 태양전지의 중요 parameter들과 관련되어, 효율에 영향을 미치기 때문에, printing 시 Finger width와 spacing을 최적화하여 최대한의 효율을 내는 조건을 찾는 것이 바람직하다. 본 연구에서는 Finger width를 $30{\mu}m{\sim}100{\mu}m$, spacing을 $1.8{\mu}m{\sim}2.8{\mu}m$ 까지 가변하여 c-Si solar cell을 제작하였으며, 제작된 cell의 LIV를 측정을 통하여, 최적의 효율을 내는 조건을 찾고자 하였다. 그 결과 Finger width $30{\mu}m$, Finger spacing $1.8{\mu}m$의 조건에서 17.12%로 최고의 효율을 나타내었다.

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Fabrication of Transparent Electrode Film for Organic Photovoltaic using Ag grid and Conductive Polymer (Ag grid와 전도성 고분자를 이용한 인쇄기반 OPV용 투명전극 형성)

  • Yu, Jongsu;Kim, Jungsu;Yoon, Sungman;Kim, Dongsoo;Kim, Dojin;Jo, Jeongdai
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.116.1-116.1
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    • 2011
  • Materials with a combination of high electrical conductivity and optical transparency are important components of many electronic and optoelectronic devices such as liquid crystal displays, solar cells, and light emitting diodes. In this study, to fabricate a low-resistance and high optical transparent electrode film for organic photovoltaic, the following steps were performed: the design and manufacture of an electroforming stamp mold, the fabrication of thermal roll imprinted (TRI) poly-carbonate (PC) patterned films, the manufacture of high-conductivity and low-resistance Ag paste which was filled into patterned PC film using a doctor blade process and then coated with a thin film layer of conductive polymer by a spin coating process. As a result of these imprinting processes the PC films obtained a line width of $10{\pm}0.5{\mu}m$, a channel length of $500{\pm}2{\mu}m$, and a pattern depth of $7.34{\pm}0.5{\mu}m$. After the Ag paste was used to fill part of the patterned film with conductive polymer coating, the following parameters were obtained: a sheet resistance of $9.65{\Omega}$/sq, optical transparency values were 83.69 % at a wavelength of 550 nm.

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Pore Characteristics of Stainless Steel Slag AOD Blended Cement Pastes by Carbonation Curing (스테인리스 스틸 슬래그 AOD 혼입 시멘트 페이스트의 탄산화 양생에 의한 공극특성)

  • Hwang, Chul-Sung;Park, Kyoung Tae;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.3
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    • pp.90-96
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    • 2018
  • In this study, the mechanical and micro-structural change of cement pastes incorporating Stainless-Steel Slag Argon Oxygen Decarburization Slag (STS-A) containing ${\gamma}-C_2S$ as a carbon capture materials were investigated with carbonation curing condition. ${\gamma}-C_2S$ is non-hydraulic, therefore does not react with water. But ${\gamma}-C_2S$ has a reactivity under carbonation curing condition with water. The reaction products fill up the pore in pastes. The microstructure of STS-A blended cement pastes could be densified by this reaction. The pore structure of cement pastes incorporating STS-A was measured using mercury intrusion porosimetry (MIP) after carbonation curing ($CO_2$ concentration is about 5%). Also the fractal characteristics were investigated for the effect of carbonation curing on the micro-structural change of paste specimens. From the results, the compressive strength of carbonated specimens incorporating STS-A increased and pore-structure of carbonated paste is more complicated.

Changes of Qualities in Vacuum Packed Fermented Pork Using a Korean Traditional Sensoning During Storage (전통양념으로 발효숙성하여 진공포장한 돼지고기의 저장 중 품질 변화)

  • Jin, S.K.;Kim, I.S.;Hah, K.H.;Hur, S.J.;Park, K.H.;Lyou, H.J.;Bae, D.S.
    • Journal of Animal Science and Technology
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    • v.47 no.1
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    • pp.39-48
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    • 2005
  • Outside muscle of pork ham were cut to cube(7 $\times$ 10 $\times$2 ern) and three Korea traditional seasonings such as soybean paste(Tl), garlic paste(T2), red pepper paste(T3) were seasoned by the proportions of meat to seasonings(1 : 1), respectively. The seasoned samples were fermented by fill into plastic box at 0 $\pm$ 1 $^{\circ}C$ for 10 days. And then, the fermented meat from each pack was vacuum-packaged and stored at 0 $\pm$ 1 $^{\circ}C$ for up to 9 weeks. pH and shear force were decreased during storage periods in all treatment groups and WHC was decreased with storage in T2. The saccarinity of T1 was increased and salinity increased during storage in all treatment groups. pH of T2 was increased than that of other treatments, while decreased saccarinity and shear force of in T2. The salinity were higher in the order of T1 > T2 > T3. Volatile basic nitrogen (VBN) value were increased with storage in all treatment groups. Thiobarbituric acid reactive substances (TSARS) value of Tl was increased with storage while it was decreased T2. Thiobarbituric acid reactive substances(TSARS) value was higher in the order of T1 > T3 > T2 at 9weeks of storage. Surface meat L' values of T1 was increased with storage and T3 decreased with storage whereas, surface meat a' values of T1 was decreased with storage, and T2 was increased with storage. Surface meat b' values of T3 was decreased with storage. Escherichia coli were decreased during storage periods in all treatment groups.

Low-cost Contact formation of High-Efficiency Crystalline Silicon Solar Cells by Plating

  • Kim D. S.;Lee E. J.;Kim J.;Lee S. H.
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.37-43
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    • 2005
  • High-efficiency silicon solar cells have potential applications on mobile electronics and electrical vehicles. The fabrication processes of the high efficiency cells necessitate com placated fabrication precesses and expensive materials. Ti/Pd/Ag metal contact has been used only for limited area In spite of good stability and low contact resistance because of Its expensive material cost and precesses. Screen printed contact formed by Ag paste causes a low fill factor and a high shading loss of commercial solar cells because of high contact resistance and a low aspect ratio. Low cost Ni/Cu metal contact has been formed by using a low cost electroless and electroplating. Nickel silicide formation at the interface enhances stability and reduces the contact resistance resulting In an energy conversion efficiency of $20.2\%\;on\;0.50{\Omega}cm$ FZ wafer. Tapered contact structure has been applied to large area solar cells with $6.7\times6.7cm^2$ in order to reduce power losses by the front contact The tapered front metal contact Is easily formed by the electroplating technique producing $45cm^2$ solar cells with an efficiency of $21.4\%$ on $21.4\%\;on\;2{\Omega}cm$ FZ wafer.

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Modeling of Mechanical Properties of Concrete Mixed with Expansive Additive

  • Choi, Hyeonggil;Noguchi, Takafumi
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.391-399
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    • 2015
  • This study modeled the compressive strength and elastic modulus of hardened cement that had been treated with an expansive additive to reduce shrinkage, in order to determine the mechanical properties of the material. In hardened cement paste with an expansive additive, hydrates are generated as a result of the hydration between the cement and expansive additive. These hydrates then fill up the pores in the hardened cement. Consequently, a dense, compact structure is formed through the contact between the particles of the expansive additive and the cement, which leads to the manifestation of the strength and elastic modulus. Hence, in this study, the compressive strength and elastic modulus were modeled based on the concept of the mutual contact area of the particles, taking into consideration the extent of the cohesion between particles and the structure formation by the particles. The compressive strength of the material was modeled by considering the relationship between the porosity and the distributional probability of the weakest points, i.e., points that could lead to fracture, in the continuum. The approach used for modeling the elastic modulus considered the pore structure between the particles, which are responsible for transmitting the tensile force, along with the state of compaction of the hydration products, as described by the coefficient of the effective radius. The results of an experimental verification of the model showed that the values predicted by the model correlated closely with the experimental values.

저온에서 Hydropolymer를 이용한 ZnO 나노입자 염료감응형 태양전지

  • Gwon, Byeong-Uk;Son, Dong-Ik;Park, Dong-Hui;Hong, Tae-U;Choe, Heon-Jin;Choe, Won-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.439-439
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    • 2011
  • 기존의 고온에서 제작되는 TiO2 나노 입자를 이용한 염료감응형 태양전지를 저온에서 제작하기 위해 전자 이동층으로 ZnO 나노 입자를 사용하여, 저온($200^{\circ}C$)에서 염료감응태양전지(DSSC)를 제작하였다[1,2]. 상대전극(counter electrode)으로는 RF magnetron sputtering을 사용하여 ITO/glass위에 Pt를 증착하여 태양전지의 특성을 측정하였다. $180^{\circ}C$ 이상에서 hydropolymer가 증발되는 것을 이용하여, ZnO 나노입자와 hydropolymer 혼합한 paste 제작하여 소결 후 ZnO 나노입자 사이에 다공성을 생성시켜 Dye가 잘 침투하여 ZnO 나노입자 표면에 잘 흡착 되도록 하였다[3]. 20 nm 및 60 nm 크기의 ZnO 나노 입자를 사용하여 실험 해본 결과, 20 nm에 비하여 60 nm ZnO 나노입자의 경우 IPCE 값이 약 7% 정도로 높은 전환효율 값을 보였다. 60 nm ZnO 나노입자를 전자 수송층으로 사용한 DSSC 소자에서 단위면적당 흐르는 전류(Jsc), 전압 (Voc), fill factor (ff), 그리고 효율(${\eta}$)의 최대값은 4.93 mA/$cm^2$, 0.56V, 0.40, and 1.12%, 로 보였다.

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Effect of Performance in Dye-sensitized Solar Cells by PEG Contents (PEG 함량변화가 염료감응형 태양전지의 효율에 미치는 영향)

  • Baek, Hyoung-Youl;Han, Zhen-Ji;Li, Hu;Gu, Hal-Bon;Park, Kyung-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.178-181
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    • 2008
  • A solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of polyethylene glycol(PEG), added to the $TiO_2$ paste, on surface morphology of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increase with PEG addition up to 20 % by weight of $TiO_2$ and then decrease with further addition due to the aggregation of $TiO_2$ nano particles in the $TiO_2$ film. In this study, the best result of dye-sensitized solar cell was the short circuit current(Isc) of $22.6mAcm^{-2}$, the open circuit voltage (Voc) of 0.73 V, the fill factor (ff) of 0.55 and the overall energy conversion efficiency (${\eta}$) of 9.1 % under illumination with AM 1.5 simulated sunlight.

The Research of Ni/Cu Contact Using Light-induced Plating for Cryatalline Silicom Solar Cells (결정질 실리콘 태양전지에 적용될 Light-induced plating을 이용한 Ni/Cu 전극에 관한 연구)

  • Kim, Min-Jeong;Lee, Soo-Hong
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.350-355
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    • 2009
  • The crysralline silicon solar cell where the solar cell market grows rapidly is occupying of about 85% or more high efficiency and low cost endeavors many crystalline solar cells. The fabricaion process of high efficiency crystalline silicon solar cells necessitate complicated fabrication processes and Ti/Pd/AG contact, This metal contacts have only been used in limited areas in spite of their good srability and low contact resistance because of expensive materials and process. Commercial solar cells with screen-printed solar cells formed by using Ag paste suffer from loe fill factor and high contact resistance and low aspect ratio. Ni and Cu metal contacts have been formed by using electroless plating and light-induced electro plating techniques to replace the Ti/Pd/Ag and screen-printed Ag contacts. Copper and Silver can be plated by electro & light-induced plating method. Light-induced plating makes use the photovoltaic effect of solar cell to deposit the metal on the front contact. The cell is immersed into the electrolytic plating bath and irradiated at the front side by light source, which leads to a current density in the front side grid. Electroless plated Ni/ Electro&light-induced plated Cu/ Light-induced plated Ag contact solar cells result in an energy conversion efficiency of 16.446 % on 0.2~0.6${\Omega}$ cm, $20{\times}20mm^2$, CZ(Czochralski) wafer.

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A Study on Pullout-Resistance Increase in Soil Nailing due to Pressurized Grouting (가압 그라우팅 쏘일네일링의 인발저항력 증가 원인에 관한 연구)

  • Jeong, Kyeong-Han;Park, Sung-Won;Choi, Hang-Seok;Lee, Chung-Won;Lee, In-Mo
    • Journal of the Korean Geotechnical Society
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    • v.24 no.4
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    • pp.101-114
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    • 2008
  • Pressurized grouting is a common technique in geotechnical engineering applications to increase the stiffness and strength of the ground mass and to fill boreholes or void space in a tunnel lining and so on. Recently, the pressurized grouting has been applied to a soil-nailing system which is widely used to improve slope stability. Because interaction between pressurized grouting paste and adjacent ground mass is complicated and difficult to analyze, the soil-nailing design has been empirically performed in most geotechnical applications. The purpose of this study is to analyze the ground behavior induced by pressurized grouting paste with the aid of laboratory model tests. The laboratory tests are carried out for four kinds of granitic residual soils. When injecting pressure is applied to grout, the pressure measured in the adjacent ground initially increases for a while, which behaves in the way of the membrane model. With the lapse of time, the pressure in the adjacent ground decreases down to a value of residual stress because a portion of water in the grouting paste seeps into the adjacent ground. The seepage can be indicated by the fact that the ratio of water/cement in the grouting paste has decreased from a initial value of 50% to around 30% during the test. The reduction of the W/C ratio should cause to harden the grouting paste and increase the stiffness of it, which restricts the rebound of out-moved ground into the original position, and thus increase the in-situ stress by approximately 20% of the injecting pressures. The measured radial deformation of the ground under pressure is in good agreement with the expansion of a cylindrical cavity estimated by the cavity expansion theory. In-situ test revealed that the pullout resistance of a soil nailing with pressurized grouting is about 36% larger than that with regular grouting, caused by grout radius increase, residual stress effect, and/or roughness increase.