• Title/Summary/Keyword: particulates

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Comparison of Commuters' PM10 Exposure Using Different Transportation Modes of Bus and Bicycle (버스와 자전거를 이용한 통근 수단에 따른 PM10 노출량의 비교)

  • Kim, Won;Kim, Sung-Yeon;Lee, Ji-Yeon;Kim, Seong-Keun;Lee, Ki-Young
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.447-453
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    • 2009
  • Cycling has been lately recommended as an alternative commuting mode because it is believed to be good for health and the environment. However, the exposure to environmental pollutants, such as fine particulates, could be a potential problem for cycling in urban environments. In this study, we compared commuters' $PM_{10}$ exposure using the different transportation modes of bicycle and bus. When a bicycle was used as a commuting mode, the additional $PM_{10}$ exposure due to transportation was about 3.5 times higher than that when using a bus. The difference of additional $PM_{10}$ exposures by cycling and bus was statistically significant (p<0.01). The $PM_{10}$ exposure during cycling was significantly correlated with atmospheric $PM_{10}$ concentration (r=0.98, p<0.01) and its correlation coefficient was higher than that of bus (r=0.55, p<0.05). The results of this study demonstrated that the main reasons of higher $PM_{10}$ exposure when using the bicycle as the mode of transport were its vicinity to road traffic and routes that were unavoidably close to road traffic. Bicycle commuting along the road side may not be good for health. Exclusive bicycle lanes away from road traffic are recommended.

Depositional Characteristics of Atmospheric PBDEs on Pine Needles, Bark and Soil (대기 중 폴리브롬화디페닐에테르의 소나무 잎, 소나무 껍질 및 토양으로의 침착 특성)

  • Chun, Man Young
    • Journal of Environmental Health Sciences
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    • v.40 no.3
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    • pp.215-224
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    • 2014
  • Objective: This study was carried out in order to determine the depositional characteristics of pine needles, pine bark, and soil used as a passive air sampler (PAS) for atmospheric polybrominated diphenyl ethers (PBDEs). Methods: All three media were sampled from the same site. The PBDE concentrations were analyzed by HRGC/HRMS, and the lipid contents were measured using the gravimetric method by n-hexane extraction. Results: The total PBDE concentration was the highest in soil (22,274.57 pg/g dry), followed by pine bark (20,266.39 pg/g dry), and then pine needles (7,380.22 pg/g dry). Pine needles contained the highest lipid contents (21.31 mg/g dry), whereas soil (10.01 mg/g dry), and pine bark (4.85 mg/g dry) contained less. There were poor correlations between lipid content and total PBDE concentrations in the media ($R^2$=0.8216, p=0.2814). Congeners BDE 47, 99, 183, 196, 197, 206, 207 and 209 showed peak concentrations. Among these, BDE 206, 207, and 209 are highly brominated PBDEs that exist as particulates in ambient air. They accounted for 81.2% [69.2 (pine needles) - 89.0% (tree bark)] of the concentration and therefore are noted as the main congener of the total PBDEs. Conclusions: It can therefore be concluded that for reducing error by improper sampling, the same species of media should be recommended for use as a PAS for atmospheric PBDEs due to the differences in depositional characteristics.

Effects of Interface Boundary Strength on Wear and Wear Transition during Sliding in Silicon Carbide Ceramics (탄화규소계 세라믹스에서 미끄럼시의 마모 및 마모천이에 미치는 계면강도의 영향)

  • Kim, Dong-Jin;Park, Seong-Khil;Ryu, Hyun;Um, Chang-Do;Cho, Seong-Jai;Kim, Seock-Sam
    • Tribology and Lubricants
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    • v.11 no.4
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    • pp.21-27
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    • 1995
  • The effects of interface boundary strength on wear and wear transition during sliding have been investigated in silicon carbide ceramics. Three different microstructures, i.e., solid state sintered silicon carbide, liquid phase sintered silicon carbide and liquid phase sintered silicon carbide composite reinforced with TiB$_{2}$ particulates, were designed by hot pressing. Examinations of crack patterns and fracture modes indicated that interface boundaries were relatively strong between silicon carbide grains in the solid state sintered silicon carbide, intermediate in the liquid phase sintered silicon carbide and weak between silicon carbide grains and TiB$_{2}$ particles in the composite. Wear data and examinations of worn surfaces revealed that the wear behavior of these silicon carbide ceramics could be significantly affected by the interface strength. In the solid state sintered silicon carbide, the wear occurred by a grooving process. In the liquid phase sintered silicon carbide and composite, on the other hand, an abrupt transition in wear mechanism from initial grooving to grain pull-out process occurred during the test. The transition occurred significantly earlier in the composite than in the carbide.

Characteristics of Washed-off Pollutants and Dynamic EMCs in a Parking Lot and a Bridge during Storms (주차장 및 교량지역의 강우유출수내 비점오염물질의 특성 비교 및 동적 EMCs)

  • Kim, Lee-Hyung;Lee, Seonha
    • Journal of Korean Society on Water Environment
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    • v.21 no.3
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    • pp.248-255
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    • 2005
  • Since the water quality of drinking water sources has been recognized as a big issue, the ministry of Environment in Korea is designing the total maximum daily load (TMDL) program for 4 major large rivers. The TMDL program can be successfully performed as controling the nonpoint pollutants from watershed area near the river. Of the various landuses in nonpoint pollution, parking lots and bridges are stormwater intensive landuses because of high imperviousness and high pollutant mass emissions from vehicular activities. Vehicle emissions from those areas include different pollutants such as heavy metals, oil and grease and particulates from sources such as fuels, brake pad and tire wear, etc. Especially the pollutant washed-off from the landuses are directly affecting to the river water quality. Therefore this research was conducted to understand the magnitude and nature of the stormwater emissions with the goal of quantifying stormwater pollutant concentrations and mass emission rates of pollutants from parking lot and bridges in Korea. In Kongju city areas, two monitoring sites were equipped with an automatic rainfall gages and an automatic flow meter for accumulating the useful data such as rainfall, water quality and runoff flow. This manuscripts will show the concentration changes during storm duration and EMCs to characterize the concentration profiles in different land uses. Also the first flush criteria will be suggested using dynamic EMCs. The definition of dynamic EMC is a new approach explaining the relationship of EMC and first flush effect.

Quantifying the Burden of cardiovascular Disease Attributable to Total Suspended Particulate and Sulfur Dioxide Using Years Lived with Disability (장애에 따른 상실생존년수를 활용한 대기중 총먼지와 아황산가스가 심혈관계질환에 미치는 영향 측정)

  • Ha, Beom-Man;Kang, Jong-Won;Kwon, Ho-Jang;Yoon, Seok-Jun
    • Journal of Preventive Medicine and Public Health
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    • v.35 no.2
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    • pp.92-98
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    • 2002
  • Objective : To estimate the burden of cardiovascular disease attributable to the total suspended particulates (TSP) and sulfur dioxide ($SO_2$) in Korea using the YLD (years lived with disability) measurement. Methods : Congestive heart failure(CHF) and myocardial infarction (MI) were chosen as the main cardiovascular diseases whose causes are attributable to the TSP and $SO_2$ levels. In order to calculate the YLD (years lived with a disability), the following parameters in the formula were estimated. : the incidence rate, the case fatality rate, The expected duration of a disability and the average age of onset were estimated. The expected duration of a disability and the average age of onset were calculated using the DISMOD method, as developed by the GBD researchers. The burden of cardiovascular disease due to TSP and $SO_2$ was estimated using the number of years that the patient lived with a disability. Results : The VLD of the CHF due to the TSP and $SO_2$ was attributed to the TSP (94.4 person-year) and $SO_2$ levels (35.0 person-year). The YLD of the ME due to the TSP and $SO_2$ was attributed to the TSP (148.4 person-year) and $SO_2$ levels(27.6 person-year). Conclusion : The YLD method employed in this study was appropriate for quantifying the burden of cardiovascular disease. Therefore, it would provide a rational basis for planning a national health policy regarding the disease burden of the risk factors in Korea.

Development of Suspended Particulate Matter Algorithms for Ocean Color Remote Sensing

  • Ahn, Yu-Hwan;Moon, Jeong-Eun;Gallegos, Sonia
    • Korean Journal of Remote Sensing
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    • v.17 no.4
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    • pp.285-295
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    • 2001
  • We developed a CASE-II water model that will enable the simulation of remote sensing reflectance($R_{rs}$) at the coastal waters for the retrieval of suspended sediments (SS) concentrations from satellite imagery. The model has six components which are: water, chlorophyll, dissolved organic matter (DOM), non-chlorophyllous particles (NC), heterotrophic microorganisms and an unknown component, possibly represented by bubbles or other particulates unrelated to the five first components. We measured $R_{rs}$, concentration of SS and chlorophyll, and absorption of DOM during our field campaigns in Korea. In addition, we generated $R_{rs}$ from different concentrations of SS and chlorophyll, and various absorptions of DOM by random number functions to create a large database to test the model. We assimilated both the computer generated parameters as well as the in-situ measurements in order to reconstruct the reflectance spectra. We validated the model by comparing model-reconstructed spectra with observed spectra. The estimated $R_{rs}$ spectra were used to (1) evaluate the performance of four wavelengths and wavelengths ratios for accurate retrieval of SS. 2) identify the optimum band for SS retrieval, and 3) assess the influence of the SS on the chlorophyll algorithm. The results indicate that single bands at longer wavelengths in visible better results than commonly used channel ratios. The wavelength of 625nm is suggested as a new and optimal wavelength for SS retrieval. Because this wavelength is not available from SeaWiFS, 555nm is offered as an alternative. The presence of SS in coastal areas can lead to overestimation chlorophyll concentrations greater than 20-500%.

Derivation and Comparison of Narrow and Broadband Algorithms for the Retrieval of Ocean Color Information from Multi-Spectral Camera on Kompsat-2 Satellite

  • Ahn, Yu-Hwan;Shanmugam, Palanisamy;Ryu, Joo-Hyung;Moon, Jeong-Eom
    • Korean Journal of Remote Sensing
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    • v.21 no.3
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    • pp.173-188
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    • 2005
  • The present study aims to derive and compare narrow and broad bandwidths of ocean color sensor’s algorithms for the study of monitoring highly dynamic coastal oceanic environmental parameters using high-resolution imagery acquired from Multi-spectral Camera (MSC) on KOMPSAT-2. These algorithms are derived based on a large data set of remote sensing reflectances ($R_{rs}$) generated by using numerical model that relates $b_b/(a + b_b)$ to $R_{rs}$ as functions of inherent optical properties, such as absorption and backscattering coefficients of six water components including water, phytoplankton (chl), dissolved organic matter (DOM), suspended sediment (SS) concentration, heterotropic organism (he) and an unknown component, possibly represented by bubbles or other particulates unrelated to the first five components. The modeled $R_{rs}$ spectra appear to be consistent with in-situ spectra collected from Korean waters. As Kompsat-2 MSC has similar spectral characteristics with Landsat-5 Thematic Mapper (TM), the model generated $R_{rs}$ values at 2 ㎚ interval are converted to the equivalent remote sensing reflectances at MSC and TM bands. The empirical relationships between the spectral ratios of modeled $R_{rs}$ and chlorophyll concentrations are established in order to derive algorithms for both TM and MSC. Similarly, algorithms are obtained by relating a single band reflectance (band 2) to the suspended sediment concentrations. These algorithms derived by taking into account the narrow and broad spectral bandwidths are compared and assessed. Findings suggest that there was less difference between the broad and narrow band relationships, and the determination coefficient $(r^2)$ for log-transformed data [ N = 500] was interestingly found to be $(r^2)$ = 0.90 for both TM and MSC. Similarly, the determination coefficient for log-transformed data [ N = 500] was 0.93 and 0.92 for TM and MSC respectively. The algorithms presented here are expected to make significant contribution to the enhanced understanding of coastal oceanic environmental parameters using Multi-spectral Camera.

A Study on the Size Distribution and Chemical Component of Suspended Particulate during the Period of Sandy Dust Phenomena (黃砂現象時 粉塵의 粒度分布와 化學組成에 關한 硏究)

  • Lee, Min-Hee;Han, Eui-Jung;Shin, Chan-Ki;Han, Jin-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.2
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    • pp.57-66
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    • 1988
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul and suspended particulate was collected by Andersen air sampler during this period. The samples were analyzed for 16 components $(SO_n^{2-}, NO_3^-, Cl^-, PO_4^{3-}, NH_4^+, F^-, Al, Fe, K, Cu, Mn, Na, Pb, Mg, Ca, Cd)$. The conclusions are as follwes: 1. Total suspended particulate concentation during the period of sandy dust phenomena was 489 $\mug/m^3$ (ordinary times: 140-125 $mug/m^3$) 2. The water - soluble ion component concentration of suspended particulate during the period of sandy dust phenomena was few and the metal concentration of that was more than that of ordinary times. 3. The cumulative frequency distribution of suspended particulates in logarithmic diagram did not show similar to normal log distribution during the period of sandy dust phenomena. 4. $SO_4^{2-}, NO_3^-, Cl^-, and PO_4^{3-}$ was onsided to coarse particle, and $NH_4^+$ and F to fine particle in the size distribution of water - soluble ion components during the period of sandy dust phenomena. 5. Metal concentration was high and Al, Fe, Cu, Mn, Na, Mg, and Ca was onsided to coarse particle, and K, Pb, and Cd to fine particle in the size distribution of metal components. 6. During the period of sandy dust phenomena the quantity of respirable particle (< 1 $\mum$) was about 3 times and that of metal components were about 2 - 11 times than that of ordinary times. 7. The concentrations of $NO_3^-, Cl^-, NH_4^+$ at ordinary times were 1.1 - 4 time than that of the period of sandy dust phenomena.

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Studies on Particle Size Distribution of Heavy Metals in the Atmosphere (大氣中 重金屬의 粒經分布에 關한 硏究)

  • Sohn, Dong-Hun;Kang, Choon-Won
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.3
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    • pp.57-63
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    • 1986
  • Atmospheric particulate matter (A.P.M.) was collected on quartz fiber filters from March 1985 to May 1986 according to particle size using Andersen high-volume air sampler, and 6 heavy metals (Fe, Mn, Cu, Ni, Zn, Pb) in these particulates were analyzed by atomic absorption spectrophotometry. The arithmetic mean concentration of A.P.M. was 195.57$\mug/m^3$. The arithmetic mean concentrations of 6 metals (Fe, Mn, Cu, Ni, Zn and Pb) were 3385.04, 1451.67, 897.94, 159.68, 127.14 and 59.49 $ng/m^3$ respectively. The order of heavy metals contributing to A.P.M. was as follows: Fe > Zn > Pb > Cu > Mn > Ni. These heavy metals were devided into 3 groups according to their particle size distribution. The contents of heavy metals belonging to the 1st group (Fe, Mn) were increased with the particle size. On the contrary, the content of Pb belonging to the 2nd group (Pb) was increased with the decrease in the particle size. The heavy metal contents in the 3rd group (Ni, Cu, Zn) were lowest in the particle size range of 2.0-3.3 $\mum$ compared with particles larger or smaller tha this range. The seasonal variation of heavy metal concentration were as follows: Fe and Mn contents were highest in spring, but Ni and Pb contents were highest in winter. Statistical analysis showed that there was a significant correlation between A.P.M. and Fe in coarse particles, meanwhile between A.P.M. and Pb in the case of fine particles.

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Engineered nanoparticles in wastewater systems: Effect of organic size on the fate of nanoparticles

  • Choi, Soohoon;Chen, Ching-Lung;Johnston, Murray V.;Wang, Gen Suh;Huang, Chin-Pao
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.29-37
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    • 2022
  • To verify the fate and transport of engineered nanoparticles (ENP), it is essential to understand its interactions with organic matter. Previous research has shown that dissolved organic matter (DOM) can increase particle stability through steric repulsion. However, the majority of the research has been focused on model organic matter such as humic or fulvic acids, lacking the understanding of organic matter found in field conditions. In the current study, organic matter was sampled from wastewater treatment plants to verify the stability of engineered nanoparticles (ENP) under field conditions. To understand how different types of organic matter may affect the fate of ENP, wastewater was sampled and separated based on their size; as small organic particular matter (SOPM) and large organic particular matter (LOPM), and dissolved organic matter (DOM). Each size fraction of organic matter was tested to verify their effects on nano-zinc oxide (nZnO) and nano-titanium oxide (nTiO2) stability. For DOM, critical coagulation concentration (CCC) experiments were conducted, while sorption experiments were conducted for organic particulates. Results showed that under field conditions, the surface charge of the particles did not influence the stability. On the contrary, surface charge of the particles influenced the amount of sorption onto particulate forms of organic matter. Results of the current research show how the size of organic matter influences the fate and transport of different ENPs under field conditions.