• 제목/요약/키워드: particulate metal

검색결과 206건 처리시간 0.027초

산업폐기물 소각시설에서 폐기물 유형에 따른 입자상물질의 배출특성 (Emission Characterization of Particulate Matters According to the Types of Wastes from Industrial Waste Incinerator)

  • 박정호;서정민;조정구;류재용;한성종
    • 한국환경과학회지
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    • 제16권11호
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    • pp.1225-1230
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    • 2007
  • The emissions characteristics of particulate matters(PM) according to the types of wastes from industrial waste incinerator of 800 kg/hr treatment capacity were investigated. For this study, the incinerate waste are as follows; waste resin, waste wood, waste urethane, waste gunny, and waste paper. The particulate samples were collected to be emitted in stack and air pollution control(both cyclone and bag filter). In stack, the concentrations of PM were in the range of 2.61 to $26.51 mg/Sm^3$ and the major chemical species were C, Si, Cl, K, Na, Ca in all the wastes. In cyclone fly ash, the mean content of heavy metal were in the order of Fe > Zn > Pb > Cu > Mn > Cr > Ni > Cd > As > Hg and the heavy metal content of waste resin were Zn 34,197.5 mg/kg, Fe 27,587.6 mg/kg, Pb 6,055.8 mg/kg, respectively. In bag filter fly ash, the mean content of heavy metal were in the order of Zn > Pb > Fe > Cu > Mn > Cd > Cr > Ni > As > Hg and the heavy metal content of waste wood were Pb 36,405.2 mg/kg, Fe 15,762.9 mg/kg, Cu 9,989.5 mg/kg, Cd 2,230.1 mg/kg, respectively. Comparing the heavy metal content of both cyclone and bag filter, in cyclone, the Cr, Fe, Ni content were higher than in bag filter and the Cd, Cu, Hg content were lower than in bag filter.

A Study on Characteristics of Atmospheric Heavy Metals in Subway Station

  • Kim, Chun-Huem;Yoo, Dong-Chul;Kwon, Young-Min;Han, Woong-Soo;Kim, Gi-Sun;Park, Mi-Jung;Kim, Young-Soon;Choi, Dal-Woong
    • Toxicological Research
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    • 제26권2호
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    • pp.157-162
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    • 2010
  • In this study, we investigated the atmospheric heavy metal concentrations in the particulate matter inside the subway stations of Seoul. In particular, we examined the correlation between the heavy metals and studied the effect of the heavy metals on cell proliferation. In six selected subway stations in Seoul, particulate matter was captured at the platforms and 11 types of heavy metals were analyzed. The results showed that the mean concentration of iron was the highest out of the heavy metals in particulate matter, followed by copper, potassium, calcium, zinc, nickel, sodium, manganese, magnesium, chromium and cadmium in that order. The correlation analysis showed that the correlations between the heavy metals was highest in the following order: (Cu vs Zn), (Ca vs Na), (Ca vs Mn), (Ni vs Cr), (Na vs Mn), (Cr vs Cd), (Zn vs Cd), (Cu vs Cd), (Ni vs Cd), (Cu vs Ni), (K vs Zn), (Cu vs K), (Cu vs Cr), (K vs Cd), (Zn vs Cr), (K vs Ni), (Zn vs Ni), (K vs Cr), and (Fe vs Cu). The correlation coefficient between zinc and copper was 0.937, indicating the highest correlation. Copper, zinc, nickel, chromium and cadmium, which are generated from artificial sources in general, showed correlations with many of the other metals and the correlation coefficients were also relatively high. The effect of the heavy metals on cell proliferation was also investigated in this study. Cultured cell was exposed to 10 mg/l or 100 mg/l of iron, copper, calcium, zinc, nickel, manganese, magnesium, chromium and cadmium for 24 hours. The cell proliferation in all the heavy metal-treated groups was not inhibited at 10 mg/l of the heavy metal concentration. The only exception to this was with the cadmium-treated group which showed a strong cell proliferation inhibition. This study provides the fundamental data for the understanding of simultaneous heavy metal exposure tendency at the time of particulate matter exposure in subway stations and the identification of heavy metal sources. Moreover, this study can be used as the fundamental data for the cell toxicity study of the subway-oriented heavy metal-containing particulate matter.

Release of Heavy metals by resuspension of coastal sediment

  • Song, Young-chae;Subha, Bakthacachallam;Woo, Jung Hui
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2014년도 춘계학술대회
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    • pp.260-261
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    • 2014
  • In the present study analysed the physico chemical properties and distribution of heavy metal and also analysed the changes of heavy metal distribution by resuspension and properties of heavy metal release into sea water. From the experimental result showed sediment resuspension plays an important role in the release of heavy metals in coastal environment. Heavy metal release percentage was high in different mixing time of resuspension and different amounts of sediment due to resuspension of particulate matter.

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무가압함침법으로 제조된 입자강화 금속복합재료의 마모특성 (Wear Characteristics of Particulate Reinforced Metal Matrix Composites Fabricated by Pressureless Metal Infiltration Process)

  • 김재동;정순억;김형진
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2002년도 추계학술대회 논문집
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    • pp.379-384
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    • 2002
  • The effect of size and volume fraction of ceramic particles with sliding velocity on the wear properties were investigated for the metal matrix composites fabricated by pressureless infiltration process. The particulate metal matrix composites exhibited about 5.5 - 6 times of excellent wear resistance compared with AC8A alloy at high sliding velocity, and as increasing the particle size and decreasing the volume fraction the wear resistance was improved. The wear resistance of metal matrix composites and AC8A alloy exhibited different aspects. Wear loss of AC8A alloy increased with sliding velocity linearly. whereas metal matrix composites indicated more wear loss than AC8A alloy at slow velocity region, however a transition point of wear loss was found at middle velocity region which show the minimum wear loss, and wear loss at high velocity region exhibited nearly same value with slow velocity region. In terms of wear mechanism, the metal matrix composites exhibited the abrasive wear at slow to high sliding velocity generally, however AC8A alloy showed abrasive wear at low sliding velocity and adhesive and melt wear at high sliding velocity.

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GPF 종류에 따른 직접분사식 가솔린 엔진의 입자상 물질 저감특성 (PM Reduction Characteristics of Gasoline Direct Injection Engines with Different Types of GPFs)

  • 이의형;박철웅;이선엽;임종한
    • 대한기계학회논문집B
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    • 제39권4호
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    • pp.351-358
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    • 2015
  • 세계적인 배출가스 규제의 강화와 함께 화석 연료의 매장량 감소와 유가 상승은 새로운 엔진 기술 개발을 촉진시켰다. 가솔린 직접 분사(GDI; Gasoline Direct Injection) 엔진은 연료를 직접 연소실에 공급하고 정밀한 연소제어를 통해 공연비가 희박한 혼합 상태에서도 연소가 가능하게 하였는데, 이러한 방식은 기존 포트 분사 엔진보다 연비와 출력을 모두 향상시킬 수 있다. 하지만 GDI엔진은 디젤 엔진의 경우와 마찬가지로 soot 발생률이 높아짐에 따라 입자상 물질의 배출이 증대되는 문제를 안고 있다. 이러한 문제를 해소하고자 본 연구에서는 가솔린 입자상 물질 필터(GPF; Gasoline Particulate Filter)를 개발하여 입자상 물질의 배출정도를 저감시키고자 하였다. 필터의 설계 효율에 따라 3가지의 Metal foam 필터와 단일 Metal fiber 필터를 실험에 적용하여 PM과 PN의 저감률을 비교하였다.

黃砂現象時 粉塵의 粒度分布와 化學組成에 關한 硏究 (A Study on the Size Distribution and Chemical Component of Suspended Particulate during the Period of Sandy Dust Phenomena)

  • 이민희;한의정;신찬기;한진석
    • 한국대기환경학회지
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    • 제4권2호
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    • pp.57-66
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    • 1988
  • Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul and suspended particulate was collected by Andersen air sampler during this period. The samples were analyzed for 16 components $(SO_n^{2-}, NO_3^-, Cl^-, PO_4^{3-}, NH_4^+, F^-, Al, Fe, K, Cu, Mn, Na, Pb, Mg, Ca, Cd)$. The conclusions are as follwes: 1. Total suspended particulate concentation during the period of sandy dust phenomena was 489 $\mug/m^3$ (ordinary times: 140-125 $mug/m^3$) 2. The water - soluble ion component concentration of suspended particulate during the period of sandy dust phenomena was few and the metal concentration of that was more than that of ordinary times. 3. The cumulative frequency distribution of suspended particulates in logarithmic diagram did not show similar to normal log distribution during the period of sandy dust phenomena. 4. $SO_4^{2-}, NO_3^-, Cl^-, and PO_4^{3-}$ was onsided to coarse particle, and $NH_4^+$ and F to fine particle in the size distribution of water - soluble ion components during the period of sandy dust phenomena. 5. Metal concentration was high and Al, Fe, Cu, Mn, Na, Mg, and Ca was onsided to coarse particle, and K, Pb, and Cd to fine particle in the size distribution of metal components. 6. During the period of sandy dust phenomena the quantity of respirable particle (< 1 $\mum$) was about 3 times and that of metal components were about 2 - 11 times than that of ordinary times. 7. The concentrations of $NO_3^-, Cl^-, NH_4^+$ at ordinary times were 1.1 - 4 time than that of the period of sandy dust phenomena.

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선박 디젤엔진 배출 미세먼지 저감을 위한 정전 여과 매연 집진기 개발에 관한 연구 (An Electrostatic Diesel Particulate Filtration System for Removal of Fine Particulate Matters from Marine Diesel Engines)

  • 김영훈;이건희;홍기정;김용진;김학준;박인용;한방우
    • 한국입자에어로졸학회지
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    • 제19권4호
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    • pp.101-110
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    • 2023
  • In order to reduce particulate matters (PM) from marine diesel engines, we developed novel electrostatic diesel particulate matter filtration system. Electrostatic diesel particulate filtration (DPF) system consists of electrostatic charger and filtration part. The electrostatic charger and filtration part are composed of a metal discharge electrode and a metal fiber filter (porosity: 68.1-86.1%), respectively. In the electrostatic charger part, diesel soot particles are reduced by electrostatic force. The filtration part after electrostatic charger part reduces diesel soot particles through inertial and diffusion forces. The filtration efficiency of electrostatic DPF system was examined through the experiments using engine dynamometer system (300 kW) and ship (200 kW). The PM reduction efficiencies due to inertial and electrostatic forces showed about 70-75% and 80-90%, respectively, according to the RPM of the engine. The differential pressure of the electrostatic DPF system applied to the ship was about 1-9 mbar, which was less than the allowable differential pressure for ship engines in South Korea (100 mbar). The results show that the electrostatic DPF system is suitable for application to the PM reduction emitted from ships.

Metal Concentrations in atmospheric particulate from seoul and asan, in Korea

  • Son, Bu-Soon;Yang, Won-Ho;Park, Jong-An;Jang, Bong-Ki;Kim, Jong-Oh;Joon Choc
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2003년도 Challenges and Achievements in Environmental Health
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    • pp.89-93
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    • 2003
  • Daily average concentrations of fine particulates have been measured simultaneously in Seoul and Asan area by using PM minivolTM portable air sampler(Air Metrics, U.S.A) from September 2001 to August 2002. The sampler were analyzed by ICP-OES(inductively coupled plasma optical emission spectrometry, optima 3000DV, Perkin Elmor) to determine the fine particulate concentrations of metallic elements(As, Mn. Ni, Fe, Cr, Cu, Cd, Pb, Zn, Si). The concentration of PM$\sub$2.5/ showed a high trend in the Seoul area. Zn showed a similar distribution ratio for the fine particle in both Seoul and Asan. Mn and Fe, Cr, Cd are highly correlated in the Seoul and Asan area(P<0.05).

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Chromatic Parameters in the Condition Monitoring of Synthetic Hydraulic Oils

  • Ossia, C.V.;Kong, H.;Han, H.G.;Markova, L.;Makarenko, V.
    • KSTLE International Journal
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    • 제8권1호
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    • pp.1-6
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    • 2007
  • Chromatic device was developed using light emitting diodes, optic fibers and photodiodes. Chromatic ratio and total contamination parameters based on transmitted light intensity in Red, Green, and Blue wavelengths were used for oil chemical and particulate contamination assessment. Chromatic ratio criterion was found independent of the particulate contamination of oil; but depended on chemical degradation, being more sensitive for synthetic than mineral hydraulic oil. Total contamination index of the sensor depended on both the chemical degradation and particulate contamination of the oil; being most sensitive in blue wavelength, and least in the red. Test results for synthetic hydraulic oils monitored corroborated with results of other tests such as viscosity, total acid number, elemental optical emission spectroscopy, particulate counts and UV-VIS photospectrometry. Chromatic ratio showed a clearer indication of oil degradation, compared to key monitoring parameters such as total acid number, viscosity and particle counts. The results showed that these parameters are effective criteria for the condition monitoring of synthetic hydraulic oils.

산업 도시의 산업단지 부지와 주거 지역의 대기 중 호흡성 분진과 구성 미량 원소의 특성 (Characteristics of Atmospheric Respirable Particulate Matters and Trace Elements within Industrial Complex and Residential Sites in an Industrial City)

  • 김모근;신승호;조완근
    • Environmental Analysis Health and Toxicology
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    • 제25권1호
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    • pp.27-40
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    • 2010
  • The current study was designed to scientifically evaluate the atmospheric particulate pollution in residences relative to their proximity to a Korean major iron/metal industrial complex (IMIC). This objective was achieved by measuring the concentrations and elemental composition of particulate matter with aerodynamic diameters equal to or less than 10 ${\mu}m$(PM10) in industrial ambient air from IMIC and residential ambient air with relative proximities to IMIC. The trace metals were analyzed using an inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The industrial mean values exceeded the Korean year/70-${\mu}g/m^3$ standard for PM10, whereas the residential mean values did not. However, the maximum residential values did exceed or were close to the Korean PM10 year standard. For individual elements, the ambient concentrations ranged widely from values in the order of a few $ng/m^3$ to thousands of $ng/m^3$. The residential mean mass concentrations in the PM10 measured in the present study were higher than or similar to those reported in earlier studies. This study suggests that residents in neighborhoods near the IMIC are exposedto elevated particulate levels compared to residents living further away from such a source.