• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.808-809
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• 2006

The decrease of the distance between particle centers due to the growth of the sinter necks can be explained by the well known two-particle model. Unfortunately this model fails to provide a comprehensive description of the processes for 3D specimens. Furthermore, there is a significant discrepancy between the calculated and the measured shrinkage because particle rearrangements are not considered. Only the recently developed analysis of the particle movements inside of 3D specimens using micro focus computed tomography $({\mu}CT)$, combined with photogrammetric image analysis, can deliver the necessary experimental data to improve existing sintering theories. In this work, ${\mu}CT$ analysis was applied to spherical copper powders. Based on photogrammetric image analysis, it is possible to determine the positions of all particle centers for tracking the particles over the entire sintering process and to follow the formation and breaking of the particle bonds. In this paper, we present an in-depth analysis of the obtained data. In the future, high resolution synchrotron radiation tomography will be utilized to obtain in-situ data and images of higher resolution.

• 한국분말재료학회지
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• 제27권3호
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• pp.193-197
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• 2020

Porous Cu-14 wt% Co with aligned pores is produced by a freeze drying and sintering process. Unidirectional freezing of camphene slurry with CuO-Co₃O₄ powders is conducted, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The dried bodies are hydrogen-reduced at 500℃ and sintered at 800℃ for 1 h. The reduction behavior of the CuO-Co₃O₄ powder mixture is analyzed using a temperature-programmed reduction method in an Ar-10% H₂ atmosphere. The sintered bodies show large and aligned parallel pores in the camphene growth direction. In addition, small pores are distributed around the internal walls of the large pores. The size and fraction of the pores decrease as the amount of solid powder added to the slurry increases. The change in pore characteristics according to the amount of the mixed powder is interpreted to be due to the rearrangement and accumulation behavior of the solid particles in the freezing process of the slurry.

• 한국분말재료학회지
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• 제23권1호
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• pp.49-53
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• 2016

The present study demonstrates the effect of freezing conditions on the pore structure of porous Cu-10 wt.% Sn prepared by freeze drying of $CuO-SnO_2$/camphene slurry. Mixtures of CuO and $SnO_2$ powders are prepared by ball milling for 10 h. Camphene slurries with 10 vol.% of $CuO-SnO_2$ are unidirectionally frozen in a mold maintained at a temperature of $-30^{\circ}C$ for 1 and 24 h, respectively. Pores are generated by the sublimation of camphene at room temperature. After hydrogen reduction and sintering at $650^{\circ}C$ for 2 h, the green body of the $CuO-SnO_2$ is completely converted into porous Cu-Sn alloy. Microstructural observation reveals that the sintered samples have large pores which are aligned parallel to the camphene growth direction. The size of the large pores increases from 150 to $300{\mu}m$ with an increase in the holding time. Also, the internal walls of the large pores contain relatively small pores whose size increases with the holding time. The change in pore structure is explained by the growth behavior of the camphene crystals and rearrangement of the solid particles during the freezing process.

• 한국지반공학회논문집
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• 제32권2호
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• pp.31-41
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• 2016

강우유출수 비점오염 침투처리시설에 사용되는 모래와 제올라이트 필터에서 여재 파쇄가 침투에 미치는 영향을 분석하였다. 여재 파쇄의 원인으로 다짐에너지와 침투력의 영향을 검토하였다. 여재 파쇄가 침투에 미치는 영향을 조사하기 위해 비다짐 및 다짐 침투층에 대한 일차원 컬럼 침투시험을 수행하였다. 시험결과로부터 다음 결론을 얻었다. 1) 침투력에 의한 여재 파쇄량은 상대적으로 적은 것으로 분석되었다. 2) 다짐여재와 비교하여 비다짐여재는 파쇄량이 적고 침투에 따른 투수성 변화도 작다. 3) 부유오염물을 함유하지 않는 침투수가 침투하는 경우에도 파쇄된 여재의 재배열, 재이동이 원인으로 추정되는 투수성 감소가 발생하였다. 4) 여재 파쇄의 영향만을 고려한다면 필터 재료로서 모래의 적용성이 제올라이트 보다 양호함을 확인했다.

• 대한기계학회논문집A
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• 제20권11호
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• pp.3474-3490
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• 1996

A metal matrix composites(MMCs) for A16061 reinforced with silicon carbide particles is fabricated by melt-stirring method. The primary products of MMCs billets are prepared by volume fractions 5 vol% to 20 vol% and particle size $13\mu m$ to $22\mu m$.This paper will be made to examine the microstructure and mechanical properties of fabricated $SiC_p$/Al 6061 composite by melt-stirring and squeeze casting method. The MMC billets is extruded at $500^{\circ}C$ under the constant extrusion velocity $V_e$=2mm/min using curved shape die. Extrusion force, particle rearrangement, micro structure and mechanical properties of extruded composites will be investigated. The mechanical properties of primary billets manufactured by melt-stirring and squeeze casting method will be compared with extrusion specimen. The effect of volume fraction and size of the reinforcements will be studied. The increase in uniformity of particle dispersion is the major reason for an improvement in reliability due to hot extrusion with optimal shape die. Experimental Young's modulus and 0.2% offset yield strength for the extruded MMCs will be compared with theretical values calculated by the Eshelby method. A method will be proposed for the prediction of Young's modulus and yield strength in $SiC_p$ reinforced MMCs.

• Journal of Pharmaceutical Investigation
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• 제40권4호
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• pp.237-244
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• 2010

This study investigated basic material properties and compressibility of commonly used pharmaceutical excipients. Five classes of excipients are selected including starch, lactose, calcium phosphate, microcrystalline cellulose (MCC), and povidone. The compressibility was evaluated using compression parameters derived from Heckel and Kawakita equation. The Heckel plot for lactose and dicalcium phosphate showed almost linear relationship. However, for MCC and povidone, curves in the initial phase of compression were observed followed by linear regions. The initial curve was considered as particle rearrangement and fragmentation and then plastic deformation at the later stages of the compression cycle. The Kawakita equation showed MCC exhibited higher compressibility, followed by povidone, lactose, and calcium phosphate. MCC undergoes significant plastic deformation during compression bringing an extremely large surface area into close contact and facilitating hydrogen bond formation between the plastically deformed, adjacent cellulose particles. Lactose compacts are consolidated by both plastic deformation and fragmentation, but to a larger extent by fragmentation. Calcium phosphate has poor binding properties because of its brittle nature. When formulating tablets, selection of suitable pharmaceutical excipients is very important and they need to have good compression properties with decent powder flowability. Material properties tested in this study might give a good guide how to select excipients for tablet formulations and help the formulation scientists design the optimum ones.

• 한국지반신소재학회논문집
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• 제10권1호
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• pp.19-28
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• 2011

본 논문에서는 동결-융해 반복작용이 화강풍화토의 압축강도 특성에 미치는 영향에 관한 내용을 다루었다. 이를 위해 세립분 함유량을 변화시켜 다양한 시료조건을 조성한 후 동결-융해 시험 환경을 조성한 후 동결-융해 반복작용 사이클을 강제 부가하였다. 시료에 대한 평면변형률압축시험 및 미세입자구조의 변화를 가시적으로 확인할 수 있는 전자주사현미경(SEM) 촬영 및 분석을 수행하였다. 먼저, SEM 분석 결과 화강풍화토는 동결-융해 반복작용에 노출될 경우 입자들이 뭉쳐 간극이 증가하는 추세를 보였다. 한편, 압축강도 특성의 경우 세립분 함유량에 따라 다소 차이를 보이는 것으로 나타났는데 세립분 함유량이 적은 경우에는 강도저하 현상을, 세립분 함유량이 많은 경우에는 강도 증가 현상을 보임을 확인할 수 있었다.

• 한국결정성장학회지
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• 제30권4호
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• pp.150-155
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• 2020

구조용 세라믹재료로 주로 사용되는 알루미나(Al₂O₃)는 우수한 기계적 특성을 위해 치밀한 미세구조를 요구하며, 소결온도를 낮추기 위해 상업적으로 액상소결(liquid phase sintering)이 적용된다. 본 연구에서는 SiO₂, MgO, CaO를 액상소결 조제로 사용하는 92 % 상업용 알루미나의 액상소결 시, 착색제(coloring agent)로 주로 사용되는 산화코발트(Co₂O₃)의 첨가량과 다양한 소결온도가 알루미나의 미세구조 및 기계적 특성에 미치는 영향을 고찰하였다. 약 11 w t% 산화코발트 첨가에 따라 1200℃부터 고상입자 재배열에 의한 수축이 시작되었고 1300℃ 이상의 온도에서 용해 재석출 및 합체(coalescence)에 의한 알루미나의 결정립 성장이 관찰되었다. 1400℃ 이상의 열처리 온도 혹은 과량의 Co₂O₃ 첨가는 액상의 점도를 낮추어 소결밀도를 감소시켰고, 이와 함께 경도값도 감소하였다. 산화코발트를 11 w t% 첨가하여 1350℃에서 소결할 경우, 3.86 g/㎤의 밀도와 12.32 GPa의 경도를 갖는 치밀한 소결체 제조가 가능하였다.

• 한국재료학회지
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• 제34권4호
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• pp.208-214
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• 2024

To fabricate intermetallic nanoparticles with high oxygen reduction reaction activity, a high-temperature heat treatment of 700 to 1,000 ℃ is required. This heat treatment provides energy sufficient to induce an atomic rearrangement inside the alloy nanoparticles, increasing the mobility of particles, making them structurally unstable and causing a sintering phenomenon where they agglomerate together naturally. These problems cannot be avoided using a typical heat treatment process that only controls the gas atmosphere and temperature. In this study, as a strategy to overcome the limitations of the existing heat treatment process for the fabrication of intermetallic nanoparticles, we propose an interesting approach, to design a catalyst material structure for heat treatment rather than the process itself. In particular, we introduce a technology that first creates an intermetallic compound structure through a primary high-temperature heat treatment using random alloy particles coated with a carbon shell, and then establishes catalytic active sites by etching the carbon shell using a secondary heat treatment process. By using a carbon shell as a template, nanoparticles with an intermetallic structure can be kept very small while effectively controlling the catalytically active area, thereby creating an optimal alloy catalyst structure for fuel cells.

• 한국지반공학회논문집
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• 제30권2호
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• pp.19-32
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• 2014

중동지역 Sabkha층 탄산질 모래는 패각류가 퇴적되어 생성되었으며, 내부간극을 포함한 다공질의 입자로 구성되어 있다. 일반적으로 흙은 항복하중에서 구조가 파괴되어 간극수압 및 침하량이 급격히 증가하게 된다. 그러나 석영질 모래와는 달리 탄산질 모래의 경우 항복하중에 따른 입자파쇄시 내부간극이 외부로 노출되어 간극수압이 감소 될 수 있다. 탄산질 모래에서 발생된 과잉간극 수압은 하중 재하시 상대밀도 증가로 인한 과잉간극수압과 입자파쇄에 따른 내부간극 노출로 인한 과잉간극수압, 파쇄입자의 재배열로 인한 과잉간극 수압의 합에 의해 결정되며, 내부간극의 노출량에 따라 음(-)의 값이 나타날 수 있다. 입자파쇄량이 크면 간극수압이 작게, 입자파쇄량이 작으면 간극수압이 크게 나타난다. 삼축압축시험 결과 음(-)의 간극수압이 나타난 구간은 외부간극 감소에 비해 입자파쇄가 우세한 영역이며, 현장 Sabkha층에서 확인된 입자파쇄 우세 영역의 크기는 1.50~3.46%의 값을 나타내었다.