• Title/Summary/Keyword: particle-in-binder

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The Relationship between Rheology Properties and Particle size distribution in Cement paste (시멘트 페이스트에서 유동성과 입도분포와의 관계)

  • Hwang, Hae-Jeong;Lee, Seung-Heun;Lee, Won-Jun;Kim, Won-Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.721-724
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    • 2006
  • In this study, particle size distribution of cement powder system were adjusted using the blast furnace slag powder, Blaine $2250cm^2/g\;and\;8300cm^2/g$, which easy to adjust particle size distribution to examine how particle size distribution of the binder has an effect on rheological properties of the cement paste. In addition, the relationship between n-value of Rosin-Rammler function and plastic viscosity were discussed. All measured flow curves represented thixotropy behavior and the hysteresis area was smaller for the more added coarse particle. When the combination was based on a ratio of $20{\sim}25vol%$ fine particles, $30{\sim}40vol%$ OPC and $40{\sim}45vol%$ coarse particles of the total volume, a high fluidity and low yield strength was achieved.

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Compaction of Hydrogen Storage Alloy Powders Using Polymer Binders (고분자 결합제를 이용한 수소저장합금 분말의 성형)

  • Song, Kyu-Tae;Kim, Chan-Jung;Choi, Byung-Jin;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.51-57
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    • 1994
  • Compaction techniques of hydrogen storage alloy 'powders, to solve the problems due to disintegration during the cyclic hydriding and dehydriding, by using polytetrafluoroethylene (PTFE) and silicon sealant as a polymer binder were studied. Optimum conditions of compaction were as follows. Binder content, 10 % for PTFE and 5 % for silicon sealant ; particle size of alloy powders, $-25{\mu}m$ ; compacting pressure, $4ton/cm^2$. Compacts obtained were easily activated and had a good strength even after 30 cycles of hydriding and dehydriding. PTFE added compacts showed very good rate capability, however, in the silicon added compacts hydrogen absorption rate was somewhat slow because of higher elasticity and adhesiveness of the binder.

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Thermal Stability of Lithiated Silicon Anodes with Electrolyte

  • Park, Yoon-Soo;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.145-148
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    • 2011
  • The thermal behavior of lithiated Si anodes has been investigated using differential scanning calorimetry (DSC). In particular, the effect of Si particle size on the thermal stability of a fully lithiated Si electrode was investigated. For DSC measurements, a lithiated Si anode was heated in a hermetically sealed high-pressure pan with a polyvinylidene fluoride (PVDF) binder and a 1 M $LiPF_6$ solution in an ethylene carbonate (EC)-diethyl carbonate (DEC) mixture. The thermal evolution around $140^{\circ}C$ increases with lithiation and with decreasing particle size; this phenomenon is attributed to the thermal decomposition of the solid electrolyte interface (SEI) film. Exothermic peaks, following a broad peak at around $140^{\circ}C$, shift to a lower temperature with a decrease in particle size, indicating that the thermal stability of the lithiated Si electrode strongly depends on the Si particle size.

Micro Metal Injection Molding Using Hybrid Micro/Nano Powders

  • Nishiyabu, Kazuaki;Kakishita, Kenichi;Osada, Toshiko;Tanaka, Shigeo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.36-37
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    • 2006
  • This study aims to investigate the usage of nano-scale particles in a micro metal injection molding ($\mu$-MIM) process. Nanoscale particle is effective to improve transcription and surface roughness in small structure. Moreover, the effects of hybrid micro/nano particles, Cu/Cu and SUS/Cu were investigated. Small dumbbell specimens were produced using various feedstocks prepared by changing binder content and fraction of nano-scale Cu particle (0.3 and $0.13{\mu}m$ in particle size). The effects of adding the fraction of nano-scale Cu powder on the melt viscosity of the feedstock, microstructure, density and tensile strength of sintered parts were discussed.

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Study on Phosphate Investment for High Temperature Precision Castings(I);The Effect of Particle size and Distribution of Silica Sand on the characteristics of the Investment (고온정밀주조용 인산염계 매몰재에 관한 연구(I);매몰재의 특성에 미치는 규사의 입도와 입도분포의 영향)

  • Ahn, Ji-Hong;Lee, Jong-Nam
    • Journal of Korea Foundry Society
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    • v.5 no.2
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    • pp.85-96
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    • 1985
  • In order to investigate the effect of particle size and distribution of silica sand on the characteristics of investment, W/P ratio, setting time, temperature change during setting, setting expansion, thermal expansion and compressive strength of the investments were measured. In this experiment, magnesia clinker and mono ammonium phosphate were used as binder, and particle size and distribution of silica sand were classified for convinence into 10 categories. The main results obtained from this investigation were summerized as follows. 1. W/P ratio decreased with increase of particle size and evenness in distribution of sand grain. 2. Setting time decreased with increase of evenness in distribution of sand grain, and temperature during setting increased with evenness in distribution of sand grain. 3. Setting expansion decreased with increase of particle size, while it increased with evenness in distribution of sand grain. 4. Thermal expansion decreased with increase of particle size. 5. Compressive strength increased with increase of particle size and evenness in distribution of sand grain. From above results, G.F.N. 250 sand which contains 30% of 50-100 mesh could be recommended for investment casting.

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I-V Measurements of large area $HgI_2$ X-ray detector produced by PIB method (PIB법을 이용한 대면적 $HgI_2$ 검출기의 I-V 특성평가)

  • Kim, Kyung-Jin;Park, Ji-Koon;Kang, Sang-Sik;Cha, Byung-Youl;Cho, Sung-Ho;Sin, Jeong-Uk;Mun, Chi-Ung;Nam, Sang-Hee;Kim, Jin-Yung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.254-255
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    • 2005
  • In this paper, we investigated electrical characteristics of the X-ray detector of mercuric iodide (HgI2) film fabricated by PIB(Particle-in-Binder) Method on ITO substrates 17cm$\times$20cm in size with thicknesses ranging from approximately 200${\mu}m$ to 240${\mu}m$. In the present study, using I-V measurements, their electrical properties such as leakage current, X-ray sensitivity, and signal-to-noise ratio (SNR),were investigated. The results of our study can be useful in the future design and optimization of direct active-matrix flat-panel detectors (AMFPD) for various digital X-ray imaging modalities.

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Effect of Particle Size Distribution of Binder on the Rheological Properties of Slag Cement Pastes (결합재의 입도분포가 슬래그 시멘트 페이스트의 유동 특성에 미치는 영향)

  • Hwang, Hae-Jeong;Lee, Seung-Heun;Lee, Won-Jun
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.6-11
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    • 2007
  • The rheological properties of slag cement pastes by effect of particle size distribution of binder were investigated using a Rheostress 1 rheometer (Haake) with a cylindrical spindle and the relationship between fluidity particle size distribution using the Rosin-Rammler equation. Samples are combined the two types of slag powder and OPC, fine slag particles sized Elaine specific surface area $8,000cm^2/g$, coarse slag particles sized Elaine specific surface area $2,000cm^2/g$, intermediate OPC particles $3,450cm^2/g$, used to search for the combination that would yield the best quality product. The all flow curves which were measured by rheometer showed hysterisis and could be classified into 4 types. When the combination was based on a ratio of 15-20 vol% fine particles, 40-50 vol% intermediate particles, 30-40 vol% coarse particles of the total volume, a high fluidity and low yield-strength was achieved. The Rosin-Rammler function can explain aboved correlation flow curve types. On type 1, the n-value had a correlation with plastic viscosity however the blend of type 2 and 3 showed consistent n-value regardless of plastic viscosity. In addition, the blend in type 4 tended to a rise in fluidity according to the increase of the n-value.

Optimum Binder Ratio of Mass Concrete for LNG Tank (LNG저장시설 적용을 위한 매스콘크리트 최적 결합재 혼입율 검토)

  • Kim, Young-Jin;Park, Sang-Jun;Kim, Kyoung-Min;Lee, Eui-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.240-245
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    • 2013
  • The optimum binder ratio of the low heat mass concrete for LNG tank was evaluated in the present study. Three types of binder such as OPC I, ground granulated blast-furnace slag powder were mixed and were used. Also fine particle cement and activator were used to raise an early age strength development and ground limestone was used to reduce the cost. As a result of the study, mix ratio II (30:30:40) was suitable for Bottom Center and mix ratio III(40:30:30) was suitable for Roof based on compressive strength and semi-adiabatic temperature.

Studies on the Multi-layered Coated Paper(II) -Effects of Binder in Pre-coated Layer on Properties of Top-coated Layer- (다층 도공지에 관한 연구(II) - 프리코팅층의 바인더가 탑층에 미치는 영향 -)

  • Choi, Ki-Soon;Shin, Woo-Seul;Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.443-453
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    • 2011
  • This study was carried out in order to elucidate effects of types of binder used in pre-coated layer on optical properties and printability of top-coated layer. Coated papers with four different types of SB latex were prepared. Tg, particle size and gel contents of latices were of different. Optical properties and printability of coated paper including print mottle were evaluated. It was confirmed that properties of pre-coated layer distinctively affected final properties of top-coated layer. Tg was found to be the most influencing factor on the print mottle of coated paper: the SB latex with lower Tg and higher particle size resulted in a superior print mottle. These results indicate that final printability and properties of top-coated layer can be controlled by adjusting pre-coated layer.

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DR (Digital Radiography) 적용을 위한 Biology 초음파 특수용매를 이용한 $PbI_2$ 합성법

  • Kim, Seong-Heon;Yun, Min-Seok;O, Gyeong-Min;Kim, Yeong-Bin;Lee, Sang-Hun;Jo, Gyu-Seok;Park, Hye-Jin;Nam, Sang-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.146-146
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    • 2009
  • 최근에 광도전체와 형광체를 기반으로 평판형 디지털 방사선 검출기의 상업적 발전가능성에 많은 관심을 가지고 있다. 본 연구는 기존의 직접변환방식에 널리 사용되었던 비정질 셀레늄 (amorphous selenium) 기반의 디지털 방사선 검출기보다 높은 전기적신호 및 동작특성을 가지는 물질층을 제작하기 위해 High Purity (99.99%)의 상용화된 $PbI_2$를 특수용매에 담가두었다가 약 1시간동안 Biology 초음파 처리한 후 농축기를 사용하여 건조된 $PbI_2$를 3Roll-milling을 사용하여 미세크기의 Powder를 얻어내었다. 합성된 $PbI_2$ Powder를 PIB(Particle-in-Binder)법을 이용하여 전도성을 가진 ITO(Indium-tin-oxide)코팅된 유리판에 제작된 필름의 상부에 Magnetron sputtering system 을 사용하여 전극을 $1cm{\times}1cm$의 크기로 증착하였다. I-V 테스트를 통하여 X선 조사시 $PbI_2$필름의 Sensitivity, Dark current, SNR(signal-to-noise ratio)을 측정하여 필름의 전기적 검출 특성을 정량적으로 평가하였고 SEM(scanning electron microscope)을 통하여 입자의 크기를 관찰하였다.

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