• Composites Research
• /
• v.31 no.3
• /
• pp.88-93
• /
• 2018

In this study, damaged composite laminates were repaired by a stepped patch repair method using halloysite nanotube(HNT) and milled carbon(MC) reinforced composite materials with different amount of the particles. And the mechanical and structural effects of the particles on the interface between the damaged and repair surfaces were analyzed. At this time, after exposing them to a harsh environment of high temperature and humidity for a long time, the recovery rate of the material properties relative to the material forming the damaged plate was compared. As a result, at $70^{\circ}C$ high temperature distilled water, the hygroscopicity of the HNT/GFRP composites was significantly different from that of the MC/GFRP composites. Especially, 0.5, 1 wt. % HNT was added, the moisture absorption rate was the lowest and this was the factor that contributed to the mechanical strength increase. On the other hand, MC showed a high hygroscopic resistance only with a small amount, and the strength was different according to the action direction of the load, and the addition amount was also different.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.18 no.2_spc
• /
• pp.227-235
• /
• 2020

In this study, we discussed the limitations of gross alpha measurements for the characterization of radioactive wastes produced in nuclear facilities through experimental tests and Monte Carlo N-particle transport simulations. The determination of gross alpha is essential for the disposal of radioactive waste produced in nuclear facilities in Korea. The measurements of gross alpha are easy to perform and yield rapid analytical results, but it cannot be used for quantitative analysis. The error of counting efficiency for gross alpha with various masses of the deposit on planchets using KCl and ²⁴¹Am was determined. The relative deviation of the counting efficiency in samples having the same mass was 20%. Uranium was extracted from the soil through acid leaching and extraction chromatography, and the concentration of U determined by inductively coupled plasma-mass spectrometry (ICP-MS) was compared with the results for gross alpha. The gross alpha was underestimated by 50% compared to the U concentration by ICP-MS. The counting efficiency depended on the energy from the alpha emitters, which differed by up to three times in determination of the counting efficiency depending on the kinds of alpha radionuclides of interest. Therefore, the gross alpha is not compatible with the sum of radioactivity for each alpha emitter and is suitable as a screening method.

• Applied Chemistry for Engineering
• /
• v.9 no.6
• /
• pp.852-856
• /
• 1998

Effects of packing materials on the pressure fluctuations in a fluidized bed have been analysed using statistical method to interpret fluidized bed behavior. The experiments were carried out in a fluidized bed of 6.7cm - ID, and the experimental variables were particle size and its distributions, fluidizing velocity, aspect ratio, and packing materials, etc. Screen packings are used as packing material, the properties of the pressure fluctuations in the fluidized bed were measured by a differential pressure transducer. The measured properties for the pressure fluctuations were the mean, the standard deviation, and the major frequency of the power spectral density functions, etc. The standard deviations of the pressure fluctuations have been slightly affected in the radial directions of fluidized bed, and almost constant in axial directions the height above 4.5cm of the distributor of fuidized bed without packing materials. The major frequency decreased with increaing packing size, whereas it showed maximum at 10% of packing materials. It has been found that the standard deviation of the pressure fluctuations can effectively explain the fluidized phenomena, and the packing materials severely affected the properties of the pressure fluctuations.

• Applied Chemistry for Engineering
• /
• v.10 no.5
• /
• pp.644-651
• /
• 1999

In this experiment the Iron phthalocyanine (FePc) films on Si-wafer and alumina pallet were prepared using vacuum sublimation with conditions of changing reaction time, temperature, and deposition rate. Then, some samples were annealed following annealing. Techniques such as XRD, SEM, and resistance measurement method, were dedicated to characterize the changes of surface structure, phase transformation and electric resistance sensitivity in accordance with change of film thickness. In proportion to the decrease of deposition temperature from $370^{\circ}C$ to $350^{\circ}C$, intensities of (200), (011), (211) and (114) planes of $\alpha$-phase were decreased and (100) plane of $\beta$-phase were appeared. The film thickness were controlled by regulating the volume of precursor material during rapid deposition. As a result, it was observed that crystalline particle size had been increased according to the increase of film thickness and $\alpha$-phase transformed to $\beta$-phase. In consequence of measuring the crystallinity of films annealed between $150^{\circ}C$ and $350^{\circ}C$, $\alpha$- to $\beta$-phase transformation was appeared to begin at $150^{\circ}C$ and completely transformed to $\beta$-phase at $350^{\circ}C$. Electric resistance sensitivity of FePc film to $NO_x$ gas along temperature change of FePc films was observed to be more stable with the decrease of the film thickness.

• Journal of the Korean Chemical Society
• /
• v.50 no.6
• /
• pp.464-470
• /
• 2006

the coricosteroid drug dexamethasone is an efficacious antiinflammatory drug, it is difficult to formulate in an injectable formulation due to its poor aqueous solubility. A lipid-based nanosphere formulation containing dexamethasone was designed for solubilization of the drug in aqueous solution and sustained release of the drug from the nanosphere. The lipid nanospheres, composed of phospholipid, cholesterol and cationic lipid, were prepared by self emulsification-solvent diffusion method followed by diafiltration. Physicochemical characteristics such as mean particle diameter, zeta potential and drug loading efficiency of the lipid nanospheres were investigated according to the variation of either the kind of lipid or the lipid composition. The lipid nanospheres had a mean diameter 80-120 nm and dexamethasone loading efficiency of greater than 80%. The drug loading efficiency increased with the increase of the length of aliphatic chain attached to the phospholipid. However, the drug loading efficiency was inversely proportional to the increase of cholesterol content in the lipid composition. The lipid nanosphere could not be prepared without the use of cationic lipid and the drug loading efficiency was proportional to the increase of cationic lipid content. The lipid nanospheres containing dexamethasone are a promising novel drug carrier for an injectable formulation of the poorly water-soluble drugs.

• Journal of the Korean Electrochemical Society
• /
• v.6 no.2
• /
• pp.145-152
• /
• 2003

Capacitance of a hybrid capacitor that has characteristics of both electrolyte capacitor and supercapacitor is determined by anode surface covered with oxide layer. In this study, optimal condition processes for anode to fabricate a high voltage hybrid capacitor was investigated. We mixed aluminum powder having mean particle size of $40{\mu}m$ with NaCl powders at weight ratio of 4 : 1 and prepared a disk type electrode after annealing at various temperature. After dissolving NaCl in $50^{\circ}C$ distilled water, heat treatment, eletropolishing, chemical treatment, and the first and the second etching of Al disk were conducted. In each process, capacitances and resistances of the disk measured by ac-impedance analyzer were compared to find its optimum treatment condition. Also, the surface morphology of treated disks were observed and compared by SEM. After the second etching, the Al disk was anodized at 365V to make an anode of hybrid supercapacitor that can be operated at 300V, Capacitance and resistance of the anodized Al disk electrode was compared with those of commercialized conventional aluminum electrolytic capacitor at different frequencies.

• Journal of Dairy Science and Biotechnology
• /
• v.35 no.3
• /
• pp.208-214
• /
• 2017

The aims of this study were to manufacture a hydrolyzed goat milk protein (HGMP)/chitosan ologisaccharide (CSO) nano-delivery system (NDS) and to investigate the effects of production variables, such as sodium tripolyphosphate (TPP), HGMP, and CSO concentration levels, on the formation and physicochemical properties of the NDS. An HGMP/CSO NDS was produced using the ionic gelation method at pH 5.5. Transmission electron microscopy and a particle size analyzer were used to determine the morphological and physicochemical properties of NDSs, respectively. The size of the HGMP/CSO NDS decreased from 225 to 138 nm as HGMP and CSO concentration levels decreased. The NDS had a positive surface charge, with a zeta-potential value of +23 mV. The encapsulation efficiency (EE) of docosahexaenoic acid was enhanced as the HGMP concentration level increased. Additionally, increasing the concentration level of CSO resulted in an increase in the EE of resveratrol. The HGMP/CSO NDS exhibited good physical stability during freeze-drying. Thus, our findings showed that the HGMP/CSO NDS was successfully manufactured and that HGMP and CSO concentration levels were key factors affecting the physicochemical properties of the NDS.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.24 no.2
• /
• pp.242-254
• /
• 2016

This paper is the forth investigation on the evaluation methods of flow characteristics in a steady flow bench. In the previous works, it was concluded that the assumption of the solid rotation might cause serious problems and both of the eccentricity and the velocity profile distort the flow characteristics when using the ISM at 1.75B plane. Also particle image velocimetry (PIV) measurement at this position showed that the real velocity profile was far from the assumption of ISM evaluation. In this paper, the planar velocity profiles were measure from 1.75B to 6.00B position by PIV and the characteristics were examined according to the valve angles and lifts for further investigations about the effect of the position on the velocity profile. The results show that $26^{\circ}$ valve angle is always an unique exceptional case in all aspects. If the valve angle is $21^{\circ}$ and below, the planar velocity profiles according to the lift and the position are similar to each other, however, the tangential velocity curves along with the radial direction have common tendencies up to $16^{\circ}$ angle. Also the well arranged swirl behaviors are generally observed at the position above 3.00B and the velocity contour lines come closer to the concentric circle as the valve lift increases. In addition, the gradient of tangential velocity along with the radial direction from the swirl center becomes stable and constant as the position goes downstream. Concurrently the velocity gradient is larger to the eccentric direction of the center. In the meantime the tangential velocity curves along with the radial direction are irregular and various at 1.75B, however, they become regular and reach higher level as the evaluation position goes downstream. At this time the curves of 4.50B are the best fitted to the ideal one. On the other hand in an exceptional case, $26^{\circ}$, the velocity contours are very complicated over 6mm valve lift regardless the position and the gradient increases to the opposite direction of the eccentric center. Also, 6.00B is a best fitting position in the geometrical cylinder center base. With respect to the swirl center, the distribution range of centers for 1.75B is different to that for the other positions and the eccentricities of this plane are larger regardless the valve angle. After 1.75B, there is no certain tendency in the center position change according to the valve angle and lift. Additionally, the eccentricities are not sufficiently small to neglecting the effect on ISM measurement.

• Korean Journal of Remote Sensing
• /
• v.30 no.6
• /
• pp.743-754
• /
• 2014

In this present paper, we, for the first time, calculated $SO_2$ inflow from China to Korea peninsula based on OMI $SO_2$ products and HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) backward trajectory calculations. The major factors used to estimate $SO_2$ flux are long range transported $SO_2$ concentration, transport speed of air mass, and thickness of transported air mass layer. The mean and maximum $SO_2$ fluxes are estimated to be 0.81 and $2.11g{\cdot}m^{-2}{\cdot}h^{-1}$, respectively based on OMI products while, those of $SO_2$ fluxes are 0.50 and $1.18g{\cdot}m^{-2}{\cdot}h^{-1}$ respectively using insitu data obtained at the surface. For most cases, larger $SO_2$ inflow values were found at the surface than those estimated for the air mass layer which extends from surface up to 1.5 km. However, increased transport speed of air mass leads to the enhanced $SO_2$ flux at the altitude up to 1.5 km at the receptor sites. Additionally, we calculate uncertainties of $SO_2$ flux using error propagation method.

• Korean Journal of Materials Research
• /
• v.2 no.1
• /
• pp.3-11
• /
• 1992

Aluminum sulfate hydrate was prepared using sulfuric acid from Ha-dong kaolin. The effects of calcination-temperature and calcination-time of kaolin, reaction-temperature and reaction-time, and sulfuric acid concentration on the formation of aluminum sulfate hydrate were investigated. The precipitation condition of aluminum sulfate hydrate from sulfuric acid solution was determined. Also, the products heat-treated at different temperatures have been investigated by X-ray diffraction, thermogravimetry, differential thermal analysis, Fourier transform infrared spectrophotometer, scanning electron microscopy, particle size distribution analysis and chemical analysis. In the optimum condition, the conversion of aluminum oxide in kaolin to aluminum sulfate hydrate was 60%. From the results of XRD, TG-DTA, and FT-IR, it is suggested that the aluminum sulfate hydrate is thermally decomposed as follows ; $Al_2(SO_4)_3{\cdot}18H_2O{\rightarrow}Al_2(SO_4)_3{\cdot}6H_2O{\rightarrow}Al_2(SO_4){\rightarrow}\;amorphous\;alumina{\rightarrow}{\gamma}-alumina{\rightarrow}{\delta}-alumina{\rightarrow}{\theta}-alumina{\rightarrow}{\alpha}-alumina$. The purity of alumina powder prepared by calcining aluminum sulfate hydrate at $1200^{\circ}C$ was 99.99 percent.