• Title/Summary/Keyword: particle inversion

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Retrieval of Vertical Single-scattering albedo of Asian dust using Multi-wavelength Raman Lidar System (다파장 라만 라이다 시스템을 이용한 고도별 황사의 단산란 알베도 산출)

  • Noh, Youngmin;Lee, Chulkyu;Kim, Kwanchul;Shin, Sungkyun;Shin, Dongho;Choi, Sungchul
    • Korean Journal of Remote Sensing
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    • v.29 no.4
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    • pp.415-421
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    • 2013
  • A new approach to retrieve the single-scattering albedo (SSA) of Asian dust plume, mixed with pollution particles, using multi-wavelength Raman lidar system was suggested in this study. Asian dust plume was separated as dust and non-dust particle (i.e. spherical particle) by the particle depolarization ratio at 532 nm. The vertical profiles of optical properties (the particle extinction coefficient at 355 and 532 nm and backscatter coefficient at 355, 532 and 1064 nm) for non-dust particle were used as input parameter for the inversion algorithm. The inversion algorithm provides the vertical distribution of microphysical properties of non-dust particle only so that the estimation of the SSA for the Asian dust in mixing state was suggested in this study. In order to estimate the SSA for the mixed Asian dust, we combined the SSA of non-dust particles retrieved by the inversion algorithms with assumed the SSA of 0.96 at 532 nm for dust. The retrieved SSA of Asian dust plume by lidar data was compared with the Aerosol Robotics Network (AERONET) retrieved values and showed good agreement.

Plane-wave Full Waveform Inversion Using Distributed Acoustic Sensing Data in an Elastic Medium (탄성매질에서의 분포형 음향 센싱 자료를 활용한 평면파 전파형역산)

  • Seoje, Jeong;Wookeen, Chung;Sungryul, Shin;Sumin, Kim
    • Geophysics and Geophysical Exploration
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    • v.25 no.4
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    • pp.214-216
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    • 2022
  • Distributed acoustic sensing (DAS), an increasingly growing acquisition technique in the oil and gas exploration and seismology fields, has been used to record seismic signals using optical cables as receivers. With the development of imaging methods for DAS data, full waveform inversion (FWI) is been applied to DAS data to obtain high-resolution property models such as P- and S-velocity. However, because the DAS systems measure strain from the phase distortion between two points along optical cables, DAS data must be transformed from strain to particle velocity for FWI algorithms. In this study, a plane-wave FWI algorithm based on the relationship between strain and horizontal particle velocity in the plane-wave assumption is proposed to apply FWI to DAS data. Under the plane-wave assumption, strain equals the horizontal particle velocity, which is scaled by the velocity at the receiver position. This relationship was confirmed using a numerical experiment. Furthermore, 4-layer and modified Marmousi-2 velocity models were used to verify the applicability of the proposed FWI algorithm in various survey environments. The proposed FWI was implemented in land and marine survey environments and provided high-resolution P- and S-velocity models.

Average Particle Size Prediction of Rubber Dispersed Phase in High Impact Polystyrene (내충격성 폴리스티렌의 고무상 입자경 예측)

  • Lee, Seong-Jae;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.31 no.5
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    • pp.327-334
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    • 1996
  • A correlative analysis has been carried out to predict the average particle size of rubber dispersed phase In high impact polystyrene manufactured by bulk polymerization. To do the correlation, a mechanistic model suggested previously by the author was used for describing the size of stabilizing particles agitated under the turbulent viscous shear subranges in a prepolymerization reactor, where the rubber particles were assumed to be formed at the time of phase inversion in the reactor. Viscosities required for the model were postulated to describe the overall behavior of butadiene rubber and polystyrene mixture along the wide range of conversion. The good agreement between the model and the experimental data from a plant was quite satisfactory for the prediction of the average rubber particle size of high impact polystyrene.

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Meteorological Characteristics of the Wintertime High PM10 Concentration Episodes in Busan (부산지역 겨울철 고농도 미세먼지 발생일의 기상학적 특성)

  • Jeon, Byung-Il
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.815-824
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    • 2012
  • The purpose of this study was to analyze the meteorological characteristics of wintertime high PM10 concentration episodes in Busan. $PM_{10}$ concentration has been reduced for the past four years and recorded near or exceeded 100 ${\mu}g/m^3$ (national standard of $PM_{10}$). High concentration episodes in Busan were 6 case, $PM_{2.5}/PM_{10}$ ratio was 0.36~0.39(mean 0.55). High $PM_{10}$ concentration occurred during higher air temperature, more solar radiation and sunshine, lower relative humidity, and smaller cloud amount. Synoptically, it also occurred when Busan was in the center or the edge of anticyclone and when sea breeze intruded. An analysis of upper air sounding showed that high $PM_{10}$ concentration occurred when surface inversion layer and upper subsidence inversion layer existed, and when boundary layer depth and vertical mixing coefficient were low. An analysis of backward trajectory of air mass showed that high $PM_{10}$ concentration was largely affected by long range transport considering that it occurs when air mass is intruded from China.

Development and Performance Evaluation of Radial Exhaust Multi-port System for Real-time Particle Size Distribution Measurement (실시간 입자분포 측정을 위한 Radial Exhaust Multi-port System의 개발 및 성능평가)

  • Lee, Hong Ku;Lee, Yang-Woo;Jeon, Ki Soo;Ahn, Kang-Ho
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.133-137
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    • 2013
  • Measuring particle size distribution is one of the primary concerns in aerosol studies. For a nano-particle size distribution measurement, many scientists use a combination of a differential mobility analyzer (DMA) and a condensation particle counter (CPC) system, which is a called scanning mobility particle sizer (SMPS). Although it has a very high particle size resolution, some issues still remain. These problems include residence time between a DMA and a CPC, discontinuity of a CPC, and disturbance due to long scanning time during the precise measurement of particles. In particular, long scanning time is not adequate for measuring particle size distribution since the particle concentration is changing during the measurement. In this study, we developed radial exhaust multi-port system (REM-system) with no scanning time and high resolution to measure real-time particle size distribution. As a result of the REM-system performed using mono-disperse particle, it is expected that this system will be suitable for measuring continuously changing aerosol. If the counting efficiency of multi-condensation particle counter (M-CPC) and data inversion matrix are completed, REM-system will be a very adequate system for unsteady aerosol, which changes for SMPS scanning time.

Nanoemulsions containing Vitamin E acetate prepared by PIC(phase inversion composition) methods: Factors affecting droplet sizes

  • Kim, Eun-Hee;Cho, Wan-Goo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.602-611
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    • 2013
  • We have investigated the influence of system composition and preparation conditions on the particle size of vitamin E acetate (VE)-loaded nanoemulsions prepared by PIC(phase inversion composition) emulsification. This method relies on the formation of very fine oil droplets when water is added to oil/surfactant mixture. The oil-to-emulsion ratio content was kept constant (5 wt.%) while the surfactant-to-oil ratio (%SOR) was varied from 50 to 200 %. Oil phase composition (vitamin E to medium chain ester ratio, %VOR) had an effect on particle size, with the smallest droplets being formed below 60 % of VOR. Food-grade non-ionic surfactants (Tween 80 and Span 80) were used as an emulsifier. The effect of f on the droplet size distribution has been studied. In our system, the droplet volume fraction, given by the oil volume fraction plus the surfactant volume fraction, was varied from 0.1 to 0.3. The droplet diameter remains less than 350 nm when O/S is fixed at 1:1. The droplet size increases gradually as the increasing the volume fraction. Particle size could also be reduced by increasing the temperature when water was added to oil/surfactant mixture. By optimizing system composition and homogenization conditions we were able to form VE-loaded nanoemulsions with small mean droplet diameters (d < 50 nm). The PIC emulsification method therefore has great potential for forming nanoemulsion-based delivery systems for food, personal care, and pharmaceutical applications.

Design and Applications of Molecularly Imprinted Polymers for Selective Separations (선택적 분리를 위한 분자 각인 고분자의 설계 및 응용)

  • 정수환;오창엽;서정일;박중곤
    • KSBB Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2001
  • Molecular imprinting has now been established as a technique which allows the creation of tailor-made binding sites for many classes of compounds. MIPs were prepared by covalent and non-covalent chemical bonding systems, by interactions between functional monomer and template. The shape of MIP is divided to particle and membrane. MIP membranes can be prepared by surface imprinting, in-situ polymerization, wet phase inversion and the dry phase inversion method. MIPs have been mainly used for analytical separation and biosensor systems to separate and detect chiral compounds and materials with similar structures. However the application of MIP by the chemical industries is still in its infancy stages. This review summarizes the preparative characteristics and applications of MIP with respect to chiral separations and biosensors.

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Effect of Storage Temperature on the Dispersion Stability of O/W Nano-emulsions (O/W 나노에멀젼 분산안정성에 미치는 보관온도의 영향)

  • Lee, Ye-Eun;Yoo, In-Sang
    • KSBB Journal
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    • v.29 no.5
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    • pp.385-391
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    • 2014
  • In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

Effect of Solvent Content on Morphology and Rubber Particle Size Distribution of High Impact Polystyrene (용매 함량이 내충격성 폴리스티렌의 형태구조 및 고무 입도분포에 미치는 영향)

  • 정한균;박정신;장대석;이성재
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.307-315
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    • 2002
  • Major factors affecting the impact resistance of high impact polystyrene (HIPS), the rubber-toughened grade of polystyrene, are rubber-phase particle size and size distribution, molecular weight, morphology, and degree of grafting. Accordingly, it is important to control or investigate these factors. In this study, the effect of solvent content was analyzed by the morphology and particle size distribution of rubber phase, and final properties in bulk-solution polymerization of HIPS. The prepolymerization time was, first, determined by measuring the evolution of particle size distribution of dispersed phase to explain the phase inversion with time. As the solvent content increased, the size of rubber particle increased and then gradually decreased. Rubber-phase morphology was likely to have higher degree of grafting as the solvent content increased. Rheological and mechanical properties decreased as the solvent content increased because of the decrease of matrix molecular weight due to the chain transfer reaction to solvent and the existence of residual solvent. Nevertheless, the impact resistance seemed to increase when the rubber particle size increased.

Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.