• Title/Summary/Keyword: partial stability

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The Effects of Agglomeration of Catalyst on its Activity in Partial Oxidation Reforming (부분산화개질 반응에서 촉매의 응집이 촉매 활성에 미치는 영향)

  • Lee, Sang-Ho;Yoon, Sang-Ho;Jeon, Seung-Hyun;Bae, Jong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.203-206
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    • 2009
  • Agglomeration of catalysts is known as one of the major degradation mechanisms. Reforming of liquid fuel, which requires high temperature over $800^{\circ}C$, accelerates agglomeration of catalysts. In this work, The effects of agglomeration on catalysts activity in partial oxidation reforming conditions were investigated. Metal supported catalysts(Pt-CGO, Ru-CGO) were compared to perovskite-structured catalysts(NECS-P1, NECS-P2). High thermal stability of perovskite-structured catalysts was reported. Micro-reactor installed in electric furnace was used. its Temperature was raised from $800^{\circ}C$ to $1000^{\circ}C$ to accelerate agglomeration effect. To measure rate of agglomeration, BET analysis and CO pulse chemisorption were conducted on catalysts exposed to $1100^{\circ}C$. Metal supported catalysts showed degradation at $1000^{\circ}C$ and The rates were different according to metal supported. On the other hand perovskite-structured catalysts showed no degradation at $1000^{\circ}C$.

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Assessment of 23 kV Capacitive Coupler for On-line Partial Discharge Measurements

  • Jeong, J.Y.;Kang, D.S.;Sun, J.H.;Heo, J.C.;Park, C.H.
    • Journal of Electrical Engineering and Technology
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    • v.4 no.1
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    • pp.123-130
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    • 2009
  • The partial discharge (PD) measurement is a very effective method to assess the winding insulation condition of high-voltage machines, since most of the insulation failure processes are directly or indirectly caused by PD. On-line PD measurements, which can detect insulation defects of winding in the early stages on rotating machines in operation, have been accepted as the most important technique. The epoxy mica capacitive coupler is currently and extensively used for on-line detection of PD pulses of high-voltage rotating machines. To evaluate the feasibility of developing a capacitive coupler that is easier to manufacture at a lower cost compared to epoxy mica couplers, a 100pF capacitive coupler made of ceramic material is designed, fabricated and tested for on-line PD measurements of 23 kV electrical machines. A series of electrical tests and accelerated aging tests are performed on the ceramic coupler to evaluate the performance requirements, long-term reliability and thermal stability for in field application. The test results show that the newly developed ceramic coupler provides equal and improved performance at a lower cost compared to epoxy mica couplers, and estimated voltage life is anticipated to surpass 100 years.

THE PARTIAL COMBUSTION OF METHANE TO SYNGAS OVER PRECIOUS METALS AND NICKEL CATALYSTS SUPPORTED ON -γAL2O3 AND CEO2

  • Seo, Ho-Joon
    • Environmental Engineering Research
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    • v.10 no.3
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    • pp.131-137
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    • 2005
  • The catalytic activity of precious metals(Rh, Pd, Pt) and nickel catalysts supported on ${\gamma}-Al_2O_3\;and\;CeO_2$ in the partial combustion of methane(PCM) to syngas was investigated based on the product distribution in a fixed bed now reactor under atmospheric condition and also on analysis results by SEM, XPS, TPD, BET, and XRD. The activity of the catalysts based on the syngas yield increased in the sequence $Rh(5)/CeO_2{\geq}Ni(5)/CeO_2>>Rh(5)/Al_2O_3>Pd(5)/Al_2O_3>Ni(5)/Al_2O_3$. Compared to the precious catalysts, the syngas yield and stability of the $Ni(5)/CeO_2$ catalyst were almost similar to $(5)/CeO_2$ catalyst, and superior to these of any other catalysts. The syngas yield of $Ni(5)/CeO_2$ catalyst was 90.66% at 1023 K. It could be suggested to be the redox cycle of the successive reaction and formation of active site, $Ni^{2-}$ and the lattice oxygen, $O^{2-}$ produced due to reduction of $Ce^{4-}$ to $Ce^{3-}$.

A Feedback Linearization Control of Container Cranes: Varying Rope Length

  • Park, Hahn;Chwa, Dong-Kyoung;Hong, Keum-Shik
    • International Journal of Control, Automation, and Systems
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    • v.5 no.4
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    • pp.379-387
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    • 2007
  • In this paper, a nonlinear anti-sway controller for container cranes with load hoisting is investigated. The considered container crane involves a planar motion in conjunction with a hoisting motion. The control inputs are two (trolley and hoisting forces), whereas the variables to be controlled are three (trolley position, hoisting rope length, and sway angle). A novel feedback linearization control law provides a simultaneous trolley-position regulation, sway suppression, and load hoisting control. The performance of the closed loop system is shown to be satisfactory in the presence of disturbances at the payload and rope length variations. The advantage of the proposed control law lies in the full incorporation of the nonlinear dynamics by partial feedback linearization. The uniform asymptotic stability of the closed-loop system is assured irrespective of variations of the rope length. Simulation and experimental results are compared and discussed.

Partial Oxidation of Methane over Ni/SiO2

  • Roh, Hyun-Seog;Dong, Wen-Sheng;Jun, Ki-Won;Liu, Zhong-Wen;Park, Sang-Eon;Oh, Young-Sam
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.669-673
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    • 2002
  • Ni catalyst (Ni: 15 wt%) supported on precalcined SiO2 has been investigated in reforming reactions of methane to synthesis gas. The catalyst exhibited fairly good activity and stability in partial oxidation of methane (POM), whereas it deactivated in steam reforming of methane (SRM). Pulse reaction results of CH4, O2, and CH4/O2 revealed that Ni/SiO2 has high capability to dissociate methane. The results also revealed that both CH4 and O2 are activated on the surface of metallic Ni, and then surface carbon species react with adsorbed oxygen to produce CO and CO2 depending on the bond strength of the oxygen species on the catalyst surface.

Control of Electromagnetic Levitation System using ε-scaling Partial State Feedback Controller (ε조절 요소를 가진 부분 상태 궤환 제어기를 이용한 자기부상 시스템의 제어)

  • Park, Gyu-Man;Choi, Ho-Lim
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.8
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    • pp.1572-1576
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    • 2011
  • The electromagnetic levitation(EMS) system is one of the well-known nonlinear system because of its nonlinearity and several control techniques have been proposed. We propose an ${\epsilon}$-scaling partial feedback controller for the ball position control of the EMS system. The key feature of our proposed controller is the use of the scaling factor ${\epsilon}$ which provides a function of controller gain tuning along with robustness. In this paper, we show the stability analysis of our proposed controller and the convergence analysis of the state observer in terms of ${\epsilon}$-scaling factor. In addition, the experimental results show the validity of the proposed controller and improved control performance over the conventional PID controller.

Production, Partial Purification and Physico-Chemical Characteristics of Laccase from Pleurotus ostreatus (Pleurotus ostreatus가 생산하는 Laccase의 부분정제 및 효소적 특성)

  • Lee, Jae Sung;Lee, Un Jung;Suh, Dal Sun
    • Microbiology and Biotechnology Letters
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    • v.13 no.1
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    • pp.65-70
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    • 1985
  • The production media, partial purification and the enzymatic characteristics of laccase from Pleurotus ostreatus were investigated. Among various media tried the double strength onion media showed much higher production of laccase compared to glucose and/or CMC added media. The laccase from Pleurotus ostreatus has the optimum pH of 5.94 for the activity and appears to be stable at relatively broad pH spectrum (4.7-8.7). The experiments on the temperature stability shows that above 90% activity could be preserved after holding at $30^{\circ}C$ for 40 min., 60% activity was remained after 40 min. at $50^{\circ}C$. The Km value of the laccase from Pleurotus ostreatus was estimated to be 3.209mM and the molecular weight of laccase was estimated to be 55,000 by SDS-Polyacrylamide gel electrophoresis.

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Dynamic stability analysis of laminated composite plates in thermal environments

  • Chen, Chun-Sheng;Tsai, Ting-Chiang;Chen, Wei-Ren;Wei, Ching-Long
    • Steel and Composite Structures
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    • v.15 no.1
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    • pp.57-79
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    • 2013
  • This paper studies the dynamic instability of laminated composite plates under thermal and arbitrary in-plane periodic loads using first-order shear deformation plate theory. The governing partial differential equations of motion are established by a perturbation technique. Then, the Galerkin method is applied to reduce the partial differential equations to ordinary differential equations. Based on Bolotin's method, the system equations of Mathieu-type are formulated and used to determine dynamic instability regions of laminated plates in the thermal environment. The effects of temperature, layer number, modulus ratio and load parameters on the dynamic instability of laminated plates are investigated. The results reveal that static and dynamic load, layer number, modulus ratio and uniform temperature rise have a significant influence on the thermal dynamic behavior of laminated plates.

Partial Discharge Characteristics of Epoxy Composite due to Internal Void (Epoxy 복합체의 내부 보이드에 따른 부분방전특성)

  • Kim T. Y.;Shin J. Y.;Lee J. H.;Lee D. J.;Hong J. H.
    • 한국컴퓨터산업교육학회:학술대회논문집
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    • 2003.11a
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    • pp.55-58
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    • 2003
  • Stability of inside power equipments are required for electron equipment in order to operate those safely. Also, the power circuits for these have been developing, but research of dielectric strength of power supply is insufficient. In this paper, for test insulation condition variation by void it is tested insulation characteristics variation, using $\phi-q-n$ distribution variation in partial discharge test.

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A partial feedback linearization control of inverted pendulum by using nonlinear additional input (비선형 추가입력을 이용한 도립 진자의 부분 궤환 선형화 제어기 설계)

  • Kim, Yong-Jun;Yoem, Dong-Hae;Choi, Jin-Young
    • Proceedings of the KIEE Conference
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    • 2002.11c
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    • pp.58-62
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    • 2002
  • This paper proposes a new nonlinear controller to swing-up an inverted pendulum system mounted on a car. This controller considers not only the pendulum but also the displacement of the cart. A single-input multi-output system is considered to control the inverted pendulum by using partial feedback linearization and nonlinear additional input. The asymptotic stability of the system is shown by using Lyapunov function. The simulation results show effectiveness of the proposed controller.

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