• Title/Summary/Keyword: parameter characterization

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Preparation and Characterization of Visible Light-Sensitive N-doped TiO2 Using a Sol-gel Method (Sol-gel법을 이용한 백색도가 높은 가시광 응답형 N-doped TiO2 제조 및 특성 평가 연구)

  • Lee, NaRi;Yu, Ri;Kim, Tae Kwan;Pee, Jae-Hwan;Kim, YooJin
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.477-482
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    • 2017
  • Nitrogen-doped titanium dioxide (N-doped $TiO_2$) is attracting continuously increasing attention as a material for environmental photocatalysis. The N-atoms can occupy both interstitial and substitutional positions in the solid, with some evidence of a preference for interstitial sites. In this study, N-doped $TiO_2$ is prepared by the sol-gel method using $NH_4OH$ and $NH_4Cl$ as N ion doping agents, and the physical and photocatalytic properties with changes in the synthesis temperature and amount of agent are analyzed. The photocatalytic activities of the N-doped $TiO_2$ samples are evaluated based on the decomposition of methylene blue (MB) under visible-light irradiation. The addition of 5 wt% $NH_4Cl$ produces the best physical properties. As per the UV-vis analysis results, the N-doped $TiO_2$ exhibits a higher visible-light activity than the undoped $TiO_2$. The wavelength of the N-doped $TiO_2$ shifts to the visible-light region up to 412 nm. In addition, this sample shows MB removal of approximately 81%, with the whiteness increasing to +97 when the synthesis temperature is $600^{\circ}C$. The coloration and phase structure of the N-doped $TiO_2$ are characterized in detail using UV-vis, CIE Lab color parameter measurements, and powder X-ray diffraction (XRD).

Availability Assessment of Meteorological Drought Index for Agricultural Drought Estimation in Ungauged Area of Agricultural Drought Parameter (농업가뭄인자 미계측 지역의 농업가뭄 추정을 위한 기상학적 가뭄지수의 활용성 평가)

  • Park, Min Woo;Kim, Sun Joo;Kwon, Hyung Joong;Kim, Phil Shik;Kang, Seung Mook;Lee, Jae Hyuk
    • Journal of The Korean Society of Agricultural Engineers
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    • v.59 no.5
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    • pp.127-136
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    • 2017
  • The object of this study was to assess availability of meteorological drought index for agricultural dorught estimation in ungauged area of agricultural drought parameters which are reservoir water level and soil moisture. The IADI (Integrated Agricultural Drought Index) and the SPI (Standard Precipitation Index), which are the criteria for determining agricultural drought and meteorological drought, were calculated and compared. For this purpose, the droughts that occurred in the Baeksan reservoir in Gimje and the Edong reservoir in Suwon were evaluated by using the IADI and SPI drought indecies. In addition, we compared and analyzed the depth of drought based on the two drought indices. Evaluations derived form the IADI and SPI showed that the standard precipitation index tended to indicate the occurrence of drought earlier than the integrated agricultural drought index. However, the integrated agricultural drought index was better than the standard precipitation index at evaluating the severity of drought during the period of irrigation. The relationship between these two drought indices seems to be useful for decision making in the case of drought, and it is considered that more studies are needed to examine the applicability of these drought indexes.

Characterization and Fatigue Life Evaluation of Rubber/Clay Nanocomposites (고무-점토 나노복합체 물성 및 피로내구성 평가)

  • Woo, Chang-Su;Park, Hyun-Sung;Joe, Deug-Hwan;Jun, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1199-1203
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    • 2011
  • Nanocomposites were prepared through the compounding of rubber and clay. Measurements of the static and dynamic mechanical properties of different compositions over a temperature range $70-100^{\circ}C$ showed that the mechanical properties of these rubber/clay nanocomposites are superior to those of existing rubber materials. In this study, by using the parameter of the maximum Green.Lagrange strain appearing at certain locations, the relationship between fatigue life and maximum Green.Lagrange strain, and the correlations between test-piece tests and bench tests of actual rubber components are proved. In order to predict the fatigue life of rubber components at the design stage, a simple procedure of life prediction is suggested. The predicted fatigue lives of the rubber engine mounts agree fairly well with the fatigue lives determined experimentally.

Contaminant Fate and Transport Modeling for Risk Assessment (위해성평가를 위한 지중 오염물질 거동 모델 이용)

  • Kim, Mee-Jeong;Park, Jae-Woo
    • Journal of Soil and Groundwater Environment
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    • v.12 no.1
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    • pp.44-52
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    • 2007
  • This study reviewed the overall process of application of contaminant fate and transport model as part of risk assessment. Site characterization and establishment of a conceptual model prior to establishing or selecting a appropriate model were described. Types of models, model selection guidance, and generic site conditions for model application were presented, the process of model calibration, validation, and sensitivity analysis were reviewed. Objectives of modeling should be defined before model selection, and the complexity of selected models should balance the quantity and quality of available input data with the desired model output. If model output is highly sensitive to an assumed or default value of input parameter, or fate and transport models cannot be adequately calibrated or validated, consideration should be given to other options such as using measured data or using another model.

Analysis of Mechanical and Ultrasonic Properties for the Evaluation of Material Degradation in Modified 9Cr-1Mo Steel (개량형 9Cr-1Mo 강의 열화도 평가를 위한 기계적 성질 및 초음파 특성 분석)

  • Hyun, Y.K.;Won, S.H.;Lee, S.H.;Son, Y.H.;Lee, J.H.;Kim, I.B.
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.4
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    • pp.198-204
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    • 2010
  • Modified 9Cr-1Mo steels possess excellent high-temperature mechanical properties and are widely used in energy conversion industries. However, in-service materials degradation, such as softening, carbide-induced embrittlement, temper embrittlement, etc., can take place during long-term operation. Evolution of microstructure due to service exposure to high temperature has a strong effect on the performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarsening of $M_{23}C_6$-type carbides are the primary cause of degradation of mechanical properties such as toughness, hardness, tensile strength and creep resistance. This study was aimed at finding reliable parameter for assessing the integrity of modified 9Cr-1Mo steels. Characteristic parameters were attained between mechanical and ultrasonic properties.

Effect of M2O3 on the Sinterbility and Electrical Conductivity of ZrO2(Y2O3) System(III) : Ceramics of the ZrO2-Y2O3-Ln2O3 System (ZrO2(Y2O3)계 세라믹스의 소결성과 전기전도도에 대한 M2O3의 영향(III) : ZrO2-Y2O3-Ln2O3계 세라믹스)

  • 오영제;정형진;이희수
    • Journal of the Korean Ceramic Society
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    • v.24 no.2
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    • pp.123-132
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    • 1987
  • Yttria-stabilized zirconia with erbia-lanthana were investigated with respect to the amount of Ln2O3 (Ln; Er, La) addition in the range of 0.5∼5 mol% to the base composition of 8 mol% yttriazirconia. Following analysis and measurement were adopted for the characterization of synthesizes of solid electrolyte; phase transformation, lattice parameter, crystallite size, relative density, chemical composition and SEM/EDS. Electrical conductivity by two-probe method versus temperature from 350$^{\circ}C$ to 800$^{\circ}C$ and frequency in the range of 5Hz∼13MHz by complex impedance method was also conducted together with the determination of oxygen ion transference number by EMF method for the evaluation of their electrical properties. The results were as followsing; Electrical conductivity were decreased with increase in Ln2O3 content, but their activation energies increased. In the case of La2O3 addition, espicially, its electrical conductivity was decreased owing to the segregation of second phases at the grain-boundary. Grain-boundary conductivity of the specimen contained 0.5 mol% Er2O3 exhibited a maximum conductivity among thecompositions experimented. However, their bulk conductivities decreased in both case. Oxygen ion transference number was also reduced with decrease in oxygen partial pressure. For example, in the case of Er2O3 addition it retained value in the range of 0.97∼0.94 abvove 4.74${\times}$10-2in oxygen partial pressure. With the increase in the quantities of the evaporation of additive components, the crystallite size of stabilized zirconia decreased, and their relative density also reduced owing to the formation of porosity in their matrices. In the case of La2O3 the sinterbility was improved in the limited amount of addition up to 0.5 mol%, in the same range of addition the strength of sintered bodies were improved perhaps owing to the precipitation of metastable tetragonal phase in the fully stabilized zirconia.

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Silicon Substrate Coupling Modeling and Analysis including RF Package Inductance (RF 패키지 인덕턴스가 실리콘 기판 커플링에 미치는 영향 모델링 및 해석)

  • Jin, U-Jin;Eo, Yeong-Seon;Sim, Jong-Jin
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.39 no.1
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    • pp.49-57
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    • 2002
  • Including RF Package inductance, substrate coupling through conductive silicon(Si)-substrate is modeled and quantitatively characterized. 2-port substrate coupling model is extended for the characterization of multi-port substrate coupling between digital circuit block and analog/RF circuit block. Furthermore, scalable parameter extraction model is developed. Multi-port substrate coupling can be investigated by linearly superposing a frequency-dependent 2-port substrate coupling model using scalable parameters. In addition, Substrate coupling including RF package inductance effect is quantitatively investigated. It is shown that package effect increases substrate coupling and shifts a characteristic frequencies(i.e., poles) to the higher frequency range. The proposed methodology can be efficiently used to the mixed-signal circuit performance verification.

Fabrication and Characteristic of C-doped Base AlGaAs/GaAs HBT using Carbontetrachloride $CCI_4$ ($CCI_4$ 를 사용하여 베이스를 탄소도핑한 AlGaAs/GaAs HBT의 제작 및 특성)

  • 손정환;김동욱;홍성철;권영세
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.12
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    • pp.51-59
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    • 1993
  • A 4${\times}10^{19}cm^{3}$ carbon-doped base AlGaAs/GaAs HBY was grown using carbontetracholoride(CCl$_4$) by atmospheric pressure MOCVD. Abruptness of emitter-base junction was characterized by SIMS(secondary ion mass spectorscopy) and the doping concentration of base layer was confirmed by DXRD(double crystal X-ray diffractometry). Mesa-type HBTs were fabricated using wet etching and lift-off technique. The base sheet resistance of R$_{sheet}$=550${\Omega}$/square was measured using TLM(transmission line model) method. The fabricated transistor achieved a collector-base junction breakdown voltage of BV$_{CBO}$=25V and a critical collector current density of J$_{O}$=40kA/cm$^2$ at V$_{CE}$=2V. The 50$\times$100$\mu$$^2$ emitter transistor showed a common emitter DC current gain of h$_{FE}$=30 at a collector current density of JS1CT=5kA/cm$^2$ and a base current ideality factor of ηS1EBT=1.4. The high frequency characterization of 5$\times$50$\mu$m$^2$ emitter transistor was carried out by on-wafer S-parameter measurement at 0.1~18.1GHz. Current gain cutoff frequency of f$_{T}$=27GHz and maximum oscillation frequency of f$_{max}$=16GHz were obtained from the measured Sparameter and device parameters of small-signal lumped-element equivalent network were extracted using Libra software. The fabricated HBT was proved to be useful to high speed and power spplications.

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Foundation Design the 151 story Incheon Tower in Reclamation Area

  • Abdelrazaq, Ahmad;Badelow, Frances;Kim, Sung-Ho;Park, Yung-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.157-171
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    • 2009
  • A 151 storey super high-rise building located in an area of reclaimed land constructed over soft marine clay in Songdo, Korea is currently under design. This paper describes the design process of the foundation system of the supertall tower, which is required to support the large building vertical and lateral loads and to restrain the horizontal displacement due to wind and seismic forces. The behaviour of the foundation system due to these loads and foundation stiffness influence the design of the building super structure, displacement of the tower, as well as the raft foundation design. Therefore, the design takes in account the interactions between soil, foundation and super structure, so as to achieve a safe and efficient building performance. The site lies entirely within an area of reclamation underlain by up to 20m of soft to firm marine silty clay, which overlies residual soil and a profile of weathered rock. The nature of the foundation rock materials are highly complex and are interpreted as possible roof pendant metamorphic rocks, which within about 50m from the surface have been affected by weathering which has reduced their strength. The presence of closely spaced joints, sheared and crushed zones within the rock has resulted in deeper areas of weathering of over 80m present within the building footprint. The foundation design process described includes the initial stages of geotechnical site characterization using the results of investigation boreholes and geotechnical parameter selection, and a series of detailed two- and three-dimensional numerical analysis for the Tower foundation comprising over 172 bored piles of varying length. The effect of the overall foundation stiffness and rotation under wind and seismic load is also discussed since the foundation rotation has a direct impact on the overall displacement of the tower.

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The appropriate shape of the boundary transition section for a mountain-gorge terrain model in a wind tunnel test

  • Hu, Peng;Li, Yongle;Huang, Guoqing;Kang, Rui;Liao, Haili
    • Wind and Structures
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    • v.20 no.1
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    • pp.15-36
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    • 2015
  • Characterization of wind flows over a complex terrain, especially mountain-gorge terrain (referred to as the very complex terrain with rolling mountains and deep narrow gorges), is an important issue for design and operation of long-span bridges constructed in this area. In both wind tunnel testing and numerical simulation, a transition section is often used to connect the wind tunnel floor or computational domain bottom and the boundary top of the terrain model in order to generate a smooth flow transition over the edge of the terrain model. Although the transition section plays an important role in simulation of wind field over complex terrain, an appropriate shape needs investigation. In this study, two principles for selecting an appropriate shape of boundary transition section were proposed, and a theoretical curve serving for the mountain-gorge terrain model was derived based on potential flow theory around a circular cylinder. Then a two-dimensional (2-D) simulation was used to compare the flow transition performance between the proposed curved transition section and the traditional ramp transition section in a wind tunnel. Furthermore, the wind velocity field induced by the curved transition section with an equivalent slope of $30^{\circ}$ was investigated in detail, and a parameter called the 'velocity stability factor' was defined; an analytical model for predicting the velocity stability factor was also proposed. The results show that the proposed curved transition section has a better flow transition performance compared with the traditional ramp transition section. The proposed analytical model can also adequately predict the velocity stability factor of the wind field.