• Title/Summary/Keyword: pO157

Search Result 258, Processing Time 0.037 seconds

Challenges in Carbon/Carbon Composites Technologies

  • Dhami, T.L.;Bahl, O.P.
    • Carbon letters
    • /
    • v.6 no.3
    • /
    • pp.148-157
    • /
    • 2005
  • Carbon/Carbon Composites due to their far superior thermo-mechanical properties are used in a number of demanding applications. However, the material still is used only in specific high tech applications with few exceptions in general industrial applications. The material is extremely expensive and the major challenge is to reduce its cost. Various innovative processing routes are outlined to reduce the cost of processing.

  • PDF

Optical property of spin Diode

  • Lee, J. H.;Jun, K-I;Shin, Kyung-Ho;Park, S. Y.;K. Rhie;Lee, B. C.
    • Proceedings of the Korean Magnestics Society Conference
    • /
    • 2002.12a
    • /
    • pp.156-157
    • /
    • 2002
  • 자성체, 반도체의 계면을 조절하여 스핀 산란을 없애는 방법으로 A12O3를 이용하여, 스핀의 정보를 잃지 않고 반도체에 주입할 수 있는 방법을 연구하였다. 반도체에 월형 편광된 laser를 조사하여 내부에서 여기한 전자 spin이 자성체 내부로 흘러가면서 일어나는 현상을 관측한 것이다[1], [2]. 일반적인 반도체와 금속간의 접합을 구성한 schottky-barrier 특성이 아닌 접합 사이에 인위적으로 barrier를 형성하여 그 특성을 관측하였다. n-type 과 p-type의 시료를 제작하여 I-V 특성을 온도에 따라 I-V 특성 측정하였다. (중략)

  • PDF

Selective Functionalization of Calix[6]arene

  • 남계천;박기숙
    • Bulletin of the Korean Chemical Society
    • /
    • v.16 no.2
    • /
    • pp.153-157
    • /
    • 1995
  • Calix[6]arenes are selectively dialkylated at the lower rim and further functionalized by the aminomethylation and Claisen Rearrangement reactions. Dialkylation was conducted by the reaction of calix[6]arene and alkyl halides such as benzyl bromide, allyl bromide, ethyl bromoacetate, propyl bromide, and methyl iodide under the carefully controlled reaction conditions. Aminomethylation was carried out with the treatment of disubstituted calix[6]arene and secondary amine in the presence of formaldehyde. Claisen rearrangement reaction of the O-diallylcalix[6]arene produced the p-diallylcalix[6]arene.

Mechanism and Adsorption Capacity of Arsenic in Water by Zero-Valent Iron (수용액 중 영가 철의 비소흡착 및 반응기작 구명)

  • Yoo, Kyung-Yoal;Ok, Yong-Sik;Yang, Jae E.
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.39 no.3
    • /
    • pp.157-162
    • /
    • 2006
  • Objective of this research was to evaluate optimal conditions of arsenic adsorption in water by zero-valent iron (ZVI). Batch experiment showed that adsorption of arsenic by ZVI followed a Langmuir isotherm model. The masses of As(V) adsorbed onto ZVI were increased as decreasing pH of the reacting solution (pH 3: 2.05, pH 5: 1.82, pH 7: 1.24, pH 9: 1.03 mg As/g $Fe^0$) and as increasing the temperature ($15^{\circ}C$ : 1.59, $25^{\circ}C$ : 1.81, 35 : $1.93^{\circ}C$ mg As/g $Fe^0$). The SEM and EDS (energy dispersive X-ray spectrometer) analysis of morphology and structure of ZVI before and after reacting with arsenic in water revealed that a relatively smooth and large surface of ZVI was transformed into a coarse and small surface particle after the reaction. The EDS spectra on the chemical composition of ZVI demonstrated that arsenic was incorporated into ZVI by adsorption mechanism. The XRD analysis also identified that the only peak for $Fe^0$ in the ZVI before the reaction and confirmed that $Fe^0$ was transformed into $Fe_2O_3$ and FeOOH, and As into $FeAsO_4{\cdot}2H_2O$.

Piezoelectric and Dielectric Characteristics of $NaKNbO_3$ ceramics according to the poling condition (분극조건에 따른 무연 $NaKNbO_3$ 세라믹스의 압전 및 유전 특성)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Lee, Kab-Soo
    • Proceedings of the KIEE Conference
    • /
    • 2005.11a
    • /
    • pp.157-159
    • /
    • 2005
  • In this study, in order to develop Pb-free piezoelectric ceramics, $[Li_{0.04}(Na_{0.44}K_{0.52)-(Nb_{0.86}Ta_{0.10}Sb_{0.04})]O_3$ ceramics were fabricated by conventional mixed oxide method and their piezoelectric characteristics were investigated according to the poling condition. The transition temperature from orthorhombic phase to tetragonal phase observed at $93[^{\circ}C]$ and Curie temperature was $346[^{\circ}C]$. At $50[^{\circ}C]$ poling temperature, dielectric constant, electromecha nical coupling factor kp, piezoelectric $d_{33}$ const ant, coercive field Ec, remanant polarization Pr and mechanical quality factor Qm showed the optimum value of 737, 0.45, 209[pC/N], 1l.34[kV/cm], $7.14[{\mu}C/cm^2]$ and 205, respectively.

  • PDF

Kinetics and Mechanism of the Hydrolysis of N-(p-Nitrophenyl)-benzohydrazonyl Azide Derivatives (N-(p-니트로페닐)-벤조히드라조닐아지드 유도체의 가수분해 반응메카니즘과 그의 반응속도론적 연구)

  • Nack-Do Sung;Ki-Sung Kwon;Tae-Rin Kim
    • Journal of the Korean Chemical Society
    • /
    • v.22 no.3
    • /
    • pp.150-157
    • /
    • 1978
  • The rate constants for the hydrolysis of the derivatives of N-(p-nitrophenyl)-benzohydrazonyl azide (p-$CH_3,\;p-CH_3O,\;p-NO_2$, p-Cl, p-Br) have been determined by UV spectrophotometry in 50% dioxane-water at $25^{\cicr}C$ and a rate equation which can be applied over wide pH range was obtained. Below pH 5, the rate of hydrolysis of hydrazonyl azides is accelerated by electron-donating group ($\rho$ = -0.47), whereas at the pH values greater than 7, the $\rho$-value is 0.68. The effect of salt, solvent, substituent and azide ion on the rate of hydrolysis are rationalized in terms of $S_N1$ and $S_N2$ mechanism; below pH 5, the hydrolysis proceed through $S_N1$, however, above pH 7, the hydrolysis is started by the attack of hydroxide ion and in the range of pH 5∼7, these two reactions occur competitively.

  • PDF

Performance Analysis of Double-Glazed Flat Plate Solar Collector with Cu-based Solar Thermal Absorber Surfaces

  • Lee, Jeong-Heon;Jeong, Da-Sol;Nam, Yeong-Seok
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.157.1-157.1
    • /
    • 2016
  • In this work, we experimentally investigated the solar absorption performance of Cu-based scalable nanostructured surfaces and compared their performance with the conventional TiNOX. We fabricated Cu-based nanostructured surfaces with a controlled chemical oxidation process applicable to a large area or complex geometry. We optimized the process parameters including the chemical compounds, dipping time and process temperature. We conducted both lab-scale and outdoor experiments to characterize the conversion efficiency of each absorber surfaces with single and double glazing setup. Lab-scale experiment was conducted with $50mm{\times}50mm$ absorber sample with 1-sun condition (1kW/m2) using a solar simulator (PEC-L01) with measuring the temperature at the absorber plate, cover glass, air gap and ambient. From the lab-scale experiment, we obtained ${\sim}91^{\circ}C$ and $94^{\circ}C$ for CuO and TiNOX surfaces after 1 hr of solar illumination at single glazing, respectively. To measure the absorber performance at actual operating condition, outdoor experiment was also conducted using $110mm{\times}110mm$ absorber sample. We measured the solar flux with thermopile detector (919P-040-50). From outdoor experiment, we observed ${\sim}123^{\circ}C$ and $131^{\circ}C$ for CuO and TiNOX with 0.6 kW/m2 insolation at double glazing, respectively. We showed that the suggested nanostructured CuO solar absorber has near-equivalent collection efficiency compared with the state-of-the-art TiNOX surfaces even with much simpler manufacturing process that does not require an expensive equipment.

  • PDF

Antimicrobial Activity of GC-l00X against Major Food-Borne Pathogens and Detaching Effects of It against Escherichia coli O157:H7 on the surface of Tomatoes (GC-100X의 주요 식품위해 미생물에 대한 항균효과와 토마토 표면에 부착된 Escherichia coli O157:H7에 대한 세척 효과)

  • 박용호;권남훈;김소현;김지연;임지연;김준만;정우경;박건택;배원기
    • Journal of Food Hygiene and Safety
    • /
    • v.17 no.1
    • /
    • pp.36-44
    • /
    • 2002
  • GC-l00X is non-corrosive alkaline ionic water (pH 12). It is composed of hydroxyl radicals and supplemented with xylitol. Its antimicrobial activity was examined against 6 major food-borne pathogens; Staphylococcus aureus FRI 913, Salmonella enterica serova Enteritidis ATCC 13076, S. enterica serova Typhimurium Korean isolate, Vibrio parahaemolyticus ATCC 17803, Escherichia coli O157:H7 ATCC 43894 and Pseudomonas aeruginosa KCTC 1637 at three different temperatures (4$^{\circ}C$, $25^{\circ}C$ and 36$^{\circ}C$) with or without an organic material (2% yeast extract), respectively. The antimicrobial activities showed over 4 log-reductions (1.0$\times$10$^4$CFU/ml reduction) against all pathogens reacted at 37$^{\circ}C$ for 3 hours in the absence of the organic material. The activities showed same results when GC-l00X was diluted with same volume of distilled water or standard hard water (CaCO$_3$300 ppm). Its antimicrobial activity was more effective and quicker in Gram-negative bacteria than Gram-positive bacteria. Its washing efficacy against E. coli O157:H7 exposed to the surfaces of tomatoes (grapes) was compared with that of the other sanitizers such as other kitchen synthetic detergent and 100-ppm chlorine water. For the toxicological evaluation of the sanitizers, viable counts of E. coli O157:H7 penetrated into the core of tomatoes after washing products were also compared. The result revealed that GC-100X stock solution and its 5% diluted solution had similar washing effects to 100-ppm chlorine water and more effective than the other kitchen synthetic detergent. This result indicated that GC- l00X had antimicrobial activity and no toxicological side effects, therefore, could be useful for a new sanitizer to use in flood safety and kitchen hygiene.

Investigation of Hazardous Microorganisms in Baby Leafy Vegetables Collected from a Korean Market and Distribution Company (유통 중인 어린잎채소의 미생물 오염도 조사)

  • Kim, Se-Ri;Chu, Hyeonjin;Yi, Seung-Won;Jang, Youn-Jung;Shim, Won-Bo;Nguyen, Bao Hung;Kim, Won-Il;Kim, Hyun Ju;Ryu, Kyeongyul
    • Journal of Food Hygiene and Safety
    • /
    • v.34 no.6
    • /
    • pp.526-533
    • /
    • 2019
  • The purpose of this study was to investigate hazardous microorganisms in mixed baby leafy vegetables and various baby leafy vegetables used as raw materials for fresh-cut produce in spring and summer. To estimate microbial loads, a total of 298 samples including 181 samples of mixed baby leafy vegetables purchased in a Korean market and 117 samples of various baby leafy vegetables from distribution companies were collected. Fecal indicators (coliform and Escherichia coli) as well as food-borne pathogens (E. coli O157:H7, Salmonella spp., Staphylococcus aureus) were enumerated. As a result, the mixed baby leafy vegetable samples showed significantly higher (P<0.05) coliform bacteria numbers in summer (5.59±1.18 log CFU/g) compared to spring (3.60±2.53 log CFU/g). E. coli was detected in 1.3% (1/79) and 42.2% (43/102) of samples collected in spring and summer, respectively. Only one sample collected from a market in spring was contaminated with S. aureus. In the experiment with baby leafy vegetables, the number of coliforms detected in baby leafy vegetables cultivated in soil in spring was 1.15±1.95 log CFU/g, and that in summer was 4.09±2.52 log CFU/g. However, the number of coliforms recovered from baby leafy vegetables cultivated in media was above 5.0 log CFU/g regardless of season. Occurrences of E. coli were 44.4% (12/27) and 19.0% (4/21) for baby leafy vegetables cultivated in soil and media, respectively. However, E. coli O157:H7 and Salmonella spp. were not detected. These results are in relation to microbial loads on mixed baby leafy vegetables associated with raw materials. Therefore, it is necessary to develop and implement hygienic practices at baby leafy vegetable farms to enhance the safety of fresh produce.