• Title/Summary/Keyword: pH variation

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Statistical Evaluation Method of Irradiated Materials Properties by Nano-Indentation Method

  • V.P. Alekin;I.S. Cho;Y.S. Pyun;C.H. Hahn;Park, Y.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.05a
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    • pp.62-62
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    • 2003
  • A statistical evaluation method was proposed to evaluate mechanical properties by using small specimens and nano-indentation for irradiation study. The method is empirically based on nano-indentation which values are statistically treated. The nano-indentation in function of indentation depth (h) is expressed using the variation factor V(h). Statistical parameters of the indentation are given by histograms. Analytical and experimental relation between histograms of phase dimension distribution and parameters V(h) and G(h) is considered using the condition of additivity of phases' microhardness. The method is applied to estimate mechanical properties of irradiated materials.

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Changes in Chemical and Sensory Properties of Dongchimi during Fermentation (동치미의 발효 중 화학적 및 관능적 성질의 변화)

  • Kang, Kun-Og;Sohn, Hyun-Joo;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.267-271
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    • 1991
  • The chemical and organoleptic properties of dongchimi studied for their changes during fermentation at $4{\sim}35^{\circ}C$ in 7% NaCl solution with seasonings. It was found that pH decrease showed three variation points in its slope at about pH 5.2, 4.7 and 4.1 during fermentation. A negative linear relationship between total acidity and logarithmic value of pH was obtained. The slope of the relationship curve was increased as the fermentation temperature increased. The reducing sugar was increased until pH reached$4.0{\sim}4.2$ followed by a small decrease and its amount was lowered as the temperature increased from $4\;to\;25^{\circ}C$ The major nonvolatile organic acids were lactic and citric acids. The increase in lactic acid were more marked at $25^{\circ}C$ than at $4^{\circ}C$. As fermentation proceeded the fresh radish odor significantly decreased while sourness and yeast-moldy odor increased. The crispness of the radish decreased slightly during fermentation.

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Application of Enhanced Coagulation for Nakdong River Water Using Aluminium and Ferric Salt Coagulants (낙동강 원수를 대상으로 Al염계 및 Fe염계 응집제를 이용한 고도응집의 적용)

  • Moon, Sin-Deok;Son, Hee-Jong;Yeom, Hoon-Sik;Choi, Jin-Taek;Jung, Chul-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.9
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    • pp.590-596
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    • 2012
  • Enhanced coagulation is best available technologies to treat NOM in water to produce clean drinking water. In this research, the comparison experiments between conventional coagulation (CC) and enhanced coagulation (EC) using 4 type coagulants i.e., ferric chloride, aluminium sulphate (alum), poly aluminium sulphate organic magnesium (PSOM) and poly aluminium chloride (PACl) were performed in terms of surrogate parameters such as dissolved organic carbon (DOC), trihalomethane formation potential (THMFP), haloacetic acid formation potential (HAAFP) and zeta potential variation in order to find out the most effective coagulant and conditions to fit Nakdong River water. When applied to EC process, the turbidity removal efficiency did not increased gradually compared to the CC process when adding coagulants. Furthermore, the removal efficiency of turbidity became decreased much more as coagulants were added increasingly whereas the removal efficiency of DOC, THMFP and HAAFP became increased by 13~18%, 9~18% and 9~18% respectively compared to the CC process. The characteristics of turbidity removal showed relatively high removal efficiency considering the pH variation in entire pH range when using $FeCl_3$ and PACl. Additionally, in case of alum and PSOM steady removal efficiency was shown between pH 5 and pH 8. In terms of DOC surrogate the coagulants including 4 type coagulants indicated high removal efficiency between pH 5 and pH 7. The removal efficiency of dissolved organic matter (DOM) in EC between less than 1 kDa and more than 10 kDa augmented by 11~21% and 16% respectively compared to the CC process. The removal efficiency of hydrophobic and hydrophilic organic matter proved to be increased by 27~38% and 11~15% respectively. In conclusion, the most effective coagulant relating to EC for Nakdong River water was proved to be $FeCl_3$ followed by PSOM, PAC and alum in order.

Adsorption of chlorhexidine digluconate on acid modified fly ash: Kinetics, isotherms and influencing factors

  • Singh, Astha;Sonal, Sonalika;Kumar, Rohit;Mishra, Brijesh Kumar
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.205-211
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    • 2020
  • Chlorhexidine digluconate (CHD) in the aquatic environment causes irreversible change to microbes, making them resistant to biodegradation, which needs remediation other than biological process. Adsorption study was performed for the removal of CHD on fly ash (FA) as a function of pH and ionic strength. Experimental result has been validated by characterization using Scanning electron microscopy, Fourier Transform-Infrared Spectroscopy and Brunauer-Emmett-Teller. CHD adsorption with FA showed an increasing trend with an increase in pH. Variation in pH proved to be an influential parameter for the surface charge of adsorbent and the degree of ionization of the CHD molecules. The adsorption capacity of CHD decreased from 23.60 mg g-1 to 1.13 mg g-1, when ionic strength increased from to M. The adsorption isotherms were simulated well by the Freundlich isotherm model having R2 = 0.98. The Lagergren's model was incorporated to predict the system kinetics, while the mechanistic study was better explained by pseudo-second order for FA. On the basis of operational conditions and cost-effectiveness FA was found to be more economical as an adsorbent for the adsorption of CHD.

Performance variation of catalyst for hydrogen peroxide thruster with drying condition (과산화수소 추력기용 촉매의 건조 조건 변화에 따른 성능 변화)

  • Lee, Jeong-Sub;An, Sung-Yong;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.53-56
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    • 2009
  • In this paper, performance evaluation of catalyst for hydrogen peroxide thruster with drying condition is described. Platinum was selected as a catalyst, and alumina of pellet type was chosen as a catalyst support. Evaporation method known as general method for catalyst production was used to make the catalyst. From previous experiments, it is favorable during catalyst making process that solution of active material has low pH level. Therefore, some kinds of low pH level solution had been tested. The drying temperatures are 25, 50, 70, and $90^{\circ}C$. From experimental results, it shows better performance that drying temperature was $90^{\circ}C$ since the catalyst particle could not be crystallized but be evenly spreaded out due to the rapid evaporation of solvent.

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Influence of Corrosion Potential and Current Density on Polarization Curve Variations using Polycarbonate[III]

  • Park, Chil-Nam;Yang, Hyo-Kyung;Kim, Sun-Kyu;Kim, Myung-Sun;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.43-50
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    • 2000
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves using polycarbonate. The results were particularly examined to identify the influences affecting the corrosion potential including various conditions such as temperature, pH, catalytic enzyme, and salt. The lines representing the active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme, and salt. The tafel slope for the anodic dissolution was determined based on the polarization effect with various conditions. The slope of the polarization curves describing the active-to-passive transition region were noticeably shifted in direction. Also, from the variation in the conditions, the optimum conditions were established for the most rapid transformation, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(Ir/If). The value of Ir/If was then used in measuring the extent of the critical corrosion sensitivity of the polycarbonate. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

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A Study on Rheological and Texture of Saccharification Process Cooked Rice, Glutinous Rice, potato and Sweet Potato (서류의 당화과정중 물성 및 Texture에 관한 연구)

  • 강선희;김경자;곽연주
    • Korean journal of food and cookery science
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    • v.7 no.2
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    • pp.7-18
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    • 1991
  • This study was experimented saccharification process added malt extract solution into cooked sweet potato and potato with time, temperature and was tested reducing sugar changes, structural changes, pH and sensory evaluation about cooked shik-hae of rice, glutinous rice, potato, sweet potato. The results are summarized as follows: 1. Enzyme activity was highest in malt after four days of barley germination at a room temperature. 2. Electronmicroscopic observation indicated that raw starch granule of potato and that of sweet potato was 25-60$\mu\textrm{m}$ and 8~18$\mu\textrm{m}$ in size, respectively and its shape is oval and globular for potato and sweet potato respectively. 3. Reducing sugars were 1,682.6mg and 1,695.6mg in rice and glutinous rice, respectively, for 6-hour-saccharification at $50^{\circ}C$. Reducing sugars were 1,689.1mg and 1,497.8mg in sweet potato, potato, respectively, for 6.hour-saccharification at $60^{\circ}C$. 4. pH variation during saccharification for sweet potato and potato was pH 5.8~5.4. 5. Sensory evalution showed that there were more significant differences in sweety odor, roasted nutty taste and sweety taste of sweet potato among four samples than the other's color shininess.

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The Polymer Membrane Electrode by Surfactants for Measuring Continuously Thiocyanate Ion in Wastewater (폐수중 티오시안산이온을 측정하기 위한 계면활성제를 이용한 고분자 막전극)

  • 최종석;안형환;강안수;우인성;황명환
    • Journal of the Korean Society of Safety
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    • v.6 no.4
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    • pp.13-20
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    • 1991
  • Ion-selective electrode responsive to the thiocynate ion prepared by using the quaternary ammonium salts as a active material and PVC as a membrane matrix. The effect of chemical structure and composition of active material, and the membrane thickness on the linear response. the detection limit, and Nernstian slope of the electrode studied. Under the above optimum conditions of membrane, the effect of pH and the selectivity coefficients to various interfering anions were compared and investigated. It was concluded that the functions of thiocynate ion-selective electrode(ISE) were closely related to the chemical structure of the quaternary ammonium salts. The linear response, and the detection limit of the electrode potential increased with the increase of the carbon chain length of the alkyl group in the quaternary ammonium salts in the ascending order of Aliquat 336T, TOAT, TDAT, and TDDAT. The optimum membrane thickness was 0.3mm. The electrode characteristics was better with the decrease of the concentration of active material, and the best concentration was 3 weight percent. The membrane potential was independent of the pH variation in the region from pH 2 to 12. The order of the selectivity coefficients is as follows:Cl $O_4$$^{[-10]}$$I^{[-10]}$ >N $O_3$$^{[-10]}$ >B $r^{[-10]}$$F^{[-10]}$ >C $l^{[-10]}$ >O $A_{c}$ $^{[-10]}$ 〓S $O_4$$^{2-}$.

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Kinetics and Mechanism of Reaction of Hydrogen Peroxide with Copper(Ⅱ)-Schiff Base Complexes (구리(Ⅱ)-시프염기 착물과 과산화수소의 반응속도 및 메카니즘)

  • Kim, Sun-Deuk;Joung, Mu-Su;Jin, Gyoung-Rok;Kim, Chang-Su
    • Journal of the Korean Chemical Society
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    • v.39 no.12
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    • pp.932-939
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    • 1995
  • Rates of the decomposition of hydrogen peroxide by copper(Ⅱ)-Schiff base complexes were measured at various concentrations of hydrogen peroxide. Decomposition rates of hydrogen peroxide increased with increasing pH for CuⅡBSDT and CuⅡBSTP but then decreased with the same variation of the pH for CuⅡBSTT. A possible mechanism in accord with experimental results was proposed. The mechanism involves the deprotonation of copper(Ⅱ)-Schiff base complexes of hydrogen peroxide, followed by the formation of peroxo complexes at the rate-determining step.

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Field-Scale Treatment of Acid Mine Drainage by Hybrid Electrolysis Process (전기분해 복합공정을 이용한 산성광산배수 실증처리 연구)

  • Sung, Il-Jong;Pak, Seung-Il;Yang, Jae-Kyu;Bae, Se-Dal;Jin, Hai-Jin;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.19 no.3
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    • pp.142-152
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    • 2014
  • In this study, generic characteristics of the acid mine drainage (AMD), removal efficiency of iron, aluminium and manganese by chemical treatment, electrolysis and hybrid process using electrolysis after neutralization were evaluated. The pH of AMD was inversely proportional to the rainfall. In dry-season, the average pH of AMD was ranged from 4.5 to 5.5, showing slight variation. However, the pH of AMD was gradually decreased along with rainfall and dropped to 3.02 in September showing the greatest rainfall. Removal efficiency of heavy metals by chemical treatments using three different neutralizing agents or by electrolysis was low. However, a hybrid process performed with electrolysis after addition of neutralization shows higher removal capacity for heavy metal ions than neutralization-alone and electrolysisalone process.