• 제목/요약/키워드: pH variation

검색결과 1,310건 처리시간 0.024초

$ZrSiO_4$가 첨가된 마찰재의 마찰 안정성 (Friction Stability of Materials with $ZrSiO_4$ Addition)

  • 이동규;박상찬
    • 한국안전학회지
    • /
    • 제14권3호
    • /
    • pp.110-119
    • /
    • 1999
  • This study was conducted to invent brake of non-steel material without using asbestos and disc pad added $ZrSiO_4$ was made. The physical properties and friction characteristics were investigated by varying methods. The physical properties were inspected of shear strength, hardness, heat expansion, specific gravity, % of gashole, thickness variation, weight variation and pH variation. The friction stability was measured by friction coefficient on variations of speed, temperature and deceleration condition. It was found that the physical properties were in general excellent. According to the friction characteristics tests, $ZrSiO_4$ had an abrasive property. As a results, the friction materials containing $ZrSiO_4$ 3~5vol% showed better resistance to fading and improved friction stability than the materials without ZrSiO$_4$.

  • PDF

$C_{22}$ Quinolium-(TCNQ) LB막 누적을 위한 $\prod$-A 특성 ($\prod$-A Characteritics of $C_{22}$ Quinolium-(TCNQ) for LB FILM Deposition)

  • 박승규;김태완;홍언식;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1991년도 추계학술대회 논문집
    • /
    • pp.7-9
    • /
    • 1991
  • $\prod$-A characteristics of N-docosylquinolium-TCNQ complex were investigated with the following variations. I> $\prod$-A characteristics with a variation of spreading amount. ii> $\prod$-A characteristics with a variation of barrier speed. iii> $\prod$-A characteristics with a variation of subphase temperature. An optimum surface pressure for a deposition of Langmuir-Blodgett(LB) layer was found to be a 40∼50 mN/m in pure water subphase (pH 5.4, $25^{\circ}C$).

에탄올-물 혼합용매내에서의 p-니트로벤질클로라이드의 가용매 분해반응에 대한 압력의 영향 (The Effect of Pressure on the Solvolysis Reaction of p-Nitrobenzyl Chloride in Binary Mixture of Ethanol-Water)

  • 권오천;김정림;유지철
    • 대한화학회지
    • /
    • 제25권3호
    • /
    • pp.152-159
    • /
    • 1981
  • p-니트로벤질클로라이드의 가용매분해 반응속도를 50 와 $60{\circ}C$에서 압력을 1∼1200bar로 변화시키고 에탄올-물 혼합용매의 조성이 0.0∼0.5인 에탄올 몰분율의 범위내에서 전기전도도법으로 측정하였다. 반응의 속도상수로부터 활성화 파라미터, ${\Delta}V_\0^{\neq},\ {\Delta}H^{\neq}$${\Delta}S^{\neq}$를 구한결과 ${\Delta}V_\0^{\neq}$는 혼합용매의 몰분율이 0.3부근에서 extremum을 나타내었고 ${\Delta}H^{\neq}$${\Delta}S^{\neq}$는 0.1 부근에서 extremum을 나타내었다. 이러한 현상은 용매구조의 변화에 의하여 검토되었고 ${\Delta}V^{\neq}$의 압력의존성도 고찰하였다. ${\Delta}H^{\neq}$${\Delta}S^{\neq}$이 압력의존성은 그 부호에 있어서 고전열역학계에 대한 Maxwell관계의 식과 일치함을 보여주었다.

  • PDF

Diurnal Variation in Hydration of the Cervical Intervertebral Disc Assessed Using T2 Mapping of Magnetic Resonance Imaging

  • Chanyuan Liu;Jingyi Wang;Bowen Hou;Yitong Li;John N. Morelli;Peisen Zhang;Jun Ran;Xiaoming Li
    • Korean Journal of Radiology
    • /
    • 제23권6호
    • /
    • pp.638-648
    • /
    • 2022
  • Objective: The study aimed to investigate the diurnal variation in cervical disc hydration and its relationship with cervical degeneration. Materials and Methods: C3-C7 discs of 86 prospectively enrolled participants (37 males, 49 females; mean age ± standard deviation, 23.5 ± 2.5 years) were assessed using T2 mapping in the morning and evening. All discs were stratified by Miyazaki grade or C2-C7 Cobb angle and T2 values (T2). The degree of diurnal T2 variation (T2-DDV), defined as (morning T2 - evening T2)/morning T2 x 100%, was measured for the entire disc, annulus fibrosus (AF), nucleus pulposus (NP), and endplate zones. Results: T2 of the entire disc decreased significantly after the daytime load (p < 0.001), with a T2-DDV of 13.3% for all discs and 16.0%, 12.2%, and 13.0% for healthy (grade I), mild degenerative (grade II), and advanced degenerative (grade III/IV) discs, respectively. T2 of regional NPs and AFs decreased significantly from morning to evening (p ≤ 0.049) except in the healthy anterior inner AF (p = 0.092). Compared with healthy discs, mild degenerative discs displayed lower T2 and T2-DDV in regional NPs (p < 0.001). Advanced degenerative discs showed higher T2-DDV in the anterior inner AF compared with healthy discs (p = 0.050). Significant diurnal T2 changes in the endplate zones were observed only in healthy discs (p = 0.013). Cervical discs in the low Cobb angle group showed higher T2-DDV in the anterior AFs and anterior NP and lower T2-DDV in the posterior AF than those in the high Cobb angle group (p ≤ 0.041). Conclusion: This study characterized the diurnal variation in hydration of the cervical discs as assessed using T2 mapping and revealed early chemo-mechanical coupling dysfunction in degenerating discs. Cervical sagittal alignment on MRI can affect the diurnal stress patterns of the cervical discs. T2 mapping is sensitive to disc biomechanical dysfunction and offers translational potential from biomechanical research to clinical application.

Biotic ligand model과 종 민감도 분포를 이용한 토양 공극수 내 Cu의 생태독성학적 허용농도 결정에 미치는 환경인자의 영향 (Effect of Environmental Factors on the Determination of the Ecotoxicological Threshold Concentration of Cu in Soil Pore Water through Biotic Ligand Model and Species Sensitivity Distribution)

  • 유기현;안진성;정부윤;남경필
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제22권1호
    • /
    • pp.49-58
    • /
    • 2017
  • Biotic ligand model (BLM) and species sensitivity distribution (SSD) were used to determine the site-specific Cu threshold concentration (5% hazardous concentration; HC5) in soil pore water. Model parameters for Cu-BLM were collected for six plants, one collembola, and two earthworms from published literatures. Half maximal effective concentration ($EC_{50}\{Cu^{2+}\}$), expressed as $Cu^{2+}$ activity, was calculated based on activities of major cations and the collected Cu-BLM parameters. The $EC_{50}\{Cu^{2+}\}$ varied from 2 nM to $251{\mu}M$ according to the variation in environmental factors of soil pore water (pH, major cation/anion concentrations) and the type of species. Hazardous activity for 5% (HA5) and HC5 calculated from SSD varied from 0.076 to $0.4{\mu}g/L$ and 0.4 to $83.4{\mu}g/L$, respectively. HA5 and HC5 significantly decreased with the increase in pH in the region with pH less than 7 due to the decrease in competition with $H^+$ and $Cu^{2+}$. In the region with pH more than 7, HC5 increased with the increase in pH due to the formation of complexes of Cu with inorganic ligands. In the presence of dissolved organic carbon (DOC), Cu and DOC form a complex, which decreases $Cu^{2+}$ activity in soil pore water, resulting in up to 292-fold increase in HC5 from 0.48 to $140{\mu}g/L$.

Studies on Ionic Conduction in Ce0.95Eu0.05P2O7 at Intermediate Temperatures

  • Wang, Hongtao;Sun, Lin;Luo, Chunhua;Fan, Suhua
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권5호
    • /
    • pp.1465-1468
    • /
    • 2014
  • In this study, an intermediate temperature ionic conductor, $Ce_{0.95}Eu_{0.05}P_2O_7$, was prepared by solid state reaction. The variation of conductivities with the pressure $pH_2O$ or time were studied. The highest conductivity of $Ce_{0.95}Eu_{0.05}P_2O_7$ sample was observed in dry air atmosphere at $300^{\circ}C$ to be $1.1{\times}10^{-4}S{\cdot}cm^{-1}$ and in wet air atmosphere ($pH_2O=7.4{\times}10^3Pa$) at $100^{\circ}C$ to be $1.4{\times}10^{-3}S{\cdot}cm^{-1}$, respectively. The log ${\sigma}$ ~ log ($pO_2$) plot result indicated that $Ce_{0.95}Eu_{0.05}P_2O_7$ was almost a pure ionic conductor under high oxygen partial pressure and a mixed conductor of ion and electron under low oxygen partial pressure.

일부 한국인 하악 제2소구치 교두 변이 양상에 대한 3차원적 분석 (Three-dimensional analysis of the cusp variation patterns of mandibular second premolar in Koreans)

  • 남신은
    • 대한치과기공학회지
    • /
    • 제42권3호
    • /
    • pp.220-227
    • /
    • 2020
  • Purpose: This study aims to investigate the cusp variation pattern of the Korean mandibular second premolar and to determine the difference in tooth diameter and surface area using a virtual three-dimensional model. Methods: Dental casts from 69 students were scanned as a virtual dental models with a three-dimensional dental model scanner. Tooth diameter, absolute and relative individual areas, total crown area, the number of lingual cusps and central groove pattern were analyzed using RapidForm 2004. The Mann-Whitney U-test and the Kruskal-Wallis test were performed to verify sexual dimorphism, the difference in tooth diameter and surface according to the cusp variation pattern (α=0.05). Results: There was no significant difference except in buccolingual diameter (p<0.05) and buccolingual diameter at the cervix (p<0.05). The relative surface area of the total clinical crown was 65.76% for the buccal half and 34.24% for the lingual half, with a ratio of 2:1. In the case of the presence of two lingual cusps, the ratio was 21.47% for the mesiolingual half and 14.12% for the distaolingual half, with a ratio of 3:2. The dominant central groove patterns of the second premolar were the H-pattern (42.0%), followed by the Y-pattern (37.7%), then the U-pattern (20.3%). The relative buccal half was largest in the U-pattern central groove and the relative lingual half was largest in the Y-pattern central groove (p<0.05). Conclusion: This study is significant in that it measured quantitative surface areas and the findings could be a meaningful reference to comprehend dental anatomy in Koreans.

Genetic Variation in the Selected Populations of Hovenia dulcis var. koreana Nakai. Based on RAPD Analysis

  • Kim Sea-Hyun;Han Jin-Gyu;Chung Hun-Gwan;Cho Yoon-Jin;Park Hyung-Soon
    • Plant Resources
    • /
    • 제8권3호
    • /
    • pp.293-299
    • /
    • 2005
  • This study used RAPD markers to assume genetic diversity and variation in selected populations of Hovenia dulcis var. koreana. Ratio of polymorphic RAPD markers were 93.4% in selected populations of Hovenia dulcis Thunb., difference of genetic structure among populations and within populations showed 16.45%, 83.55%, respectively in amount of total genetic variation of 4 populations. Total gene diversity($H_T$) that show genetic diversity appeared 0.313 and coefficient of gene differentiation($G_{ST}$) that compare genetic differentiation of populations appeared 0.1645, analysis of AMOVA for variation among populations and within populations was significantly different (P<0.001). Genetic diversity of whole populations showed that 12.44% difference among population and 87.56% difference within populations. As a result, difference within populations was larger than difference among populations in genetic diversity. Nei's genetic distance and cluster analysis appeared that mean genetic distance among populations was 0.076, thus dividing two main groups and geographic relationship did not show in populations.

  • PDF

여고생 착의습관이 기후적응에 미치는 영향 (Effect of Clothing Habit on Climatic Adaptation by Female High School Students)

  • 안필자
    • 한국의류학회지
    • /
    • 제18권5호
    • /
    • pp.615-621
    • /
    • 1994
  • This study was carried out to investigate the effect of clothing habit on physiological adaptation to the change of season. The survey of clothing weight in fall '||'&'||' winter for 2 years, the frequency of cold infection in winter and degree of fatigue was performed with 110 female high school students. The actual condition of clothing and the correlations between clothing weight and cold infection, and between the clothing weight and degree of fatigue were suveyed. The results are followed as; 1. The clothing insulation was nearly same to indoor standard clothing insulation in H hun wearing normal clothing, but was higher 2 clo in S hun clothed uniform. Especially in spite of similar enviromental condition the clothing weight, minimum '||'&'||' maximum and variation of clothing weight for 2 years were showed to be heavier in S hun than H hun. Also indoor thermal sensation felt by the subjects indicated "cold", and the difference between clothing insulation and standard clothing insulation showed increase gradually. 2. L group was indicated to be lower in cold infaction ratio than M '||'&'||' H group, and the correlation between clothing group and cold infection ratio was recognized to be significant (p<0.05). And H hun and L-H group showed to be lower in cold infection ratio than S hun, H-L group. 3. The coefficience between clothing weight and degree of fatigue was recognized to be significant (p<0.05).

  • PDF

Pullout capacity of shallow inclined anchor in anisotropic and nonhomogeneous undrained clay

  • Bhattacharya, Paramita
    • Geomechanics and Engineering
    • /
    • 제13권5호
    • /
    • pp.825-844
    • /
    • 2017
  • This study aimed to find out the pullout capacity of inclined strip anchor plate embedded in anisotropic and nonhomogeneous fully saturated cohesive soil in undrained condition. The ultimate pullout load has been found out by using numerical lower bound finite element analysis with linear programming. The undrained pullout capacity of anchor plate of width B is determined for different embedment ratios (H/B) varying from 3 to 7 and various inclination of anchor plates ranging from $0^{\circ}$ to $90^{\circ}$ with an interval of $15^{\circ}$. In case of anisotropic fully saturated clay the variation of cohesion with direction has been considered by varying the ratio of the cohesion along vertical direction ($c_v$) to the cohesion along horizontal direction ($c_h$). In case of nonhomogeneous clay the cohesion of the undrained clay has been considered to be increased with depth below ground surface keeping $c_v/c_h=1$. The results are presented in terms of pullout capacity factor ($F_{c0}=p_u/c_H$) where $p_u$ is the ultimate pullout stress along the anchor plate at failure and $c_H$ is the cohesion in horizontal direction at the level of the middle point of the anchor plate. It is observed that the pullout capacity factor increases with an increase in anisotropic cohesion ratio ($c_v/c_h$) whereas the pullout capacity factor decreases with an increase in undrained cohesion of the soil with depth.