• Journal of the Korean Society of Groundwater Environment
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• v.4 no.1
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• pp.14-19
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• 1997

Laboratory experiments were conducted to study the effects of pH and salt level on the soil sorption equilibrium of pentachlorophenol (PCP) which is hydrophobic and ionogenic. Experimental results indicated that the sorption equilibrium constant (Kp) of PCP increased with decreasing pH. A quantitative sorption model involving linear isotherms was estabilished to predict the pH effect on the PCP sorption equilibrium over the pH range from 3 to 8. The model prediction was in good agreement with the experimental data. Also, the Kp increased with salt concentration over the entire pH range. At added salt levels less than 0.1M, increase in Kp was larger than when the added levels were higher than 0.1M. Salt might increase the PCP sorption by inducing 'salting out-effect' or by forming deprotonated PCP-cation ion pairs such as PCP$\^$-/K$\^$＋/. Taking the pH range (5-8) and the salt content (up to 50 g/L) in the groundwater of Metropolitan landfill sites into consideration, the results indicated that the retardation factor of PCP in this area might range from 3 to 550 depending upon pH and salt content.

• Journal of Biosystems Engineering
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• v.11 no.2
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• pp.41-54
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• 1986

순환식(循環式) 벼 건조과정(乾燥科程)을 건조(乾燥)-템퍼링의 연속 과정으로 간주하여 이를 해석(解析)할 수 있는 시뮬레이션 모델을 개발하였으며, 시뮬레이션 결과치와 실험치가 잘 일치하였다. 특히 벼의 박층건조방정식(薄層乾燥方程式)으로 Page 형의 방정식(方程式)과 수분확산방정식(水分擴散方程式)을 이용한 모델을 비교하였으며, 수분확산계수는 백미부(白米部), 쌀겨부(部) 및 왕겨부(部)로 나누어 고려하였다. 시뮬레이션 모델을 이용하여 순건조(純乾燥) 및 템퍼링 시간(時間)이 건조속도(乾燥速度), 소요(所要)에너지 및 곡물품질(穀物品質)에 미치는 영향을 분석(分析)하고 적절한 순건조시간(純乾燥時間) 및 템퍼링 시간을 제시하였다.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.13 no.7
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• pp.1475-1482
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• 2009

In this paper, a computer simulation is developed for isotachophoretic protein separation in a serpentine micro channel for optimal lab on a chip design using 2D Finite Element Method. This 2D ITP model is composed of 5 components such as hydrochloric acid as Leader, caproic acid as terminator, acetic acid and benzoic acid as two proteins, and histindine as background electrolyte. The computer model is based on mass conservation equation for 5 components, charge conservation equation for electric potential, and electro neutrality condition for pH calculation. For the validation of the 2D spatial ITP model, the results are compared with the Simul5 developed by Bohuslav Gas Group. The simulation results are in a good agreement in a ID planar channel. This proves the precision of our model. The 2Dproteinseparation is conducted in a 2D curved channel for Lab on a chip design and dispersions of proteins are revealed during the electrophoretic process in a curved shape.

• Proceedings of the KOSOMBE Conference
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• v.1992 no.11
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• pp.157-160
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• 1992

표면에 여러 가지 기능성기를 가지는 microspheres는 immunoassay, drug delivery system, cell separation등 의용공학분야에 응용이 기대되고 있다. 이들 분야의 응용을 위하여 유화제를 사용하지 않으면서, 기존의 회분식, 반회분식, seed 중합법등의 문제점을 극복한 two stage shot growth technique올 개발하여 여러 가지 기능성기가 표면에 도입된 microspheres를 제조하였으며, 응용의 전단계로서 이들 microspheres에 대한 모델 단백질(BSA)의 흡착실험을 pH, 기능 성기의 종류와 양, BSA농도를 변수로 행하여 최대 흡착량을 보이는 조건을 결정하였다.

• Polymer(Korea)
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• v.30 no.1
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• pp.45-49
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• 2006

In this study, it was investigated on the boron separation ken synthetically prepared seawater. ion exchange resin used in the experiments was Amberlite IRA 743, containing glucamine functional group. The experiments were carried out as a function of the conditions of the pH, boron initial concentration and temperature of seawater in a batch reactor. As a result, optimum conditions for boron adsorption were at pH 8.5 and 313 K, respectively. The adsorption rate was increased very fast with increasing the temperature, but decreased with increasing the initial concentration of boron. Also, the kinetics for boron adsorption applied the pseudo-second order model, as follows: $$\frac{X}{1-X}=780[C_0]^{-1.65}t^{1.48}\;exp\;({-\frac{17883}{RT}}\)\;;\;pH8.5$$

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.608-609
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• 2007

본 논문에서는 765kV 선로의 편단가압 시 기존 운전중인 선로에서의 전압상승에 대하여 분석하였다. EMTP-RV를 이용하여 당진T/P$\sim$신서산S/S$\sim$신안성S/S의 실계통 모델을 구현하여, 선로길이 및 전원용량을 변경시키면서 시뮬레이션 하였으며 그 결과를 분석하였다.

• Proceedings of the KIEE Conference
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• 1999.11b
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• pp.325-327
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• 1999

In this research, selection of component load and measurement device is considered for accurate component load modeling. The procedure of component load characteristic experiments is also presented.

• Journal of the Korean Geotechnical Society
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• v.19 no.6
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• pp.127-149
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• 2003

The bridge tested was 3 spans 90m-long PSC beam concrete bridge with a stub-type abutment which had a skew of 60$^{\circ}$ about the axis of bridge. A cement concrete was placed at the superstructural slab of the bridge. Inclinometers and straingauges were installed at piles as well. During 7 days-curing of superstructural slab, the pile behavior in response to hydration heat and drying shrinkage of the slab was monitored. Then monitored values were compared with the horizontal movement obtained from the HACOM program and the calculated lateral behavior obtained from the nonlinear p-y curves of pile. As a result, lateral behavior of H-piles by the field measurement occurred due to the influence of hydration heat and drying shrinkage obtained during curing of superstructural concrete. The lateral displacements by hydration heat and drying shrinkage were 2.2mmand 1.4mm respectively. It was observed as well that the inflection point of lateral displacement of pile was shown at 1.3m down from footing base. It means that the horizontal movement of stub abutment did not behave as the fixed head condition of a pile but behave as a similar condition. The measured bending stress did not show the same behavior as the fixed head condition of pile but showed a similar condition. The increment of maximum bending stress obtained from the nonlinear p-y curves of pile was about 300(kgf/$\textrm{km}^2$) and was 2 times larger than measured values regardless of installation places of straingauges. Meanwhile, lateral load, maximum lateral displacement, maximum bending stress and maximum bending moment of pile showed a linear behavior as curing of superstructural concrete slab.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.458-465
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• 2020

Isotherms, kinetics and thermodynamic properties for adsorption of acid fuchsin (AF) dye by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration and contact time and temperature. The effect of pH on adsorption of AF showed a bathtub with high adsorption percentage in acidic (pH 8). Isothermal adsorption data were fitted to the Freundlich, Langmuir, and Dubinin-Radushkevich isotherm models. Freundlich isothem model showed the highest agreement and confirmed that the adsorption mechanism was multilayer adsorption. It was found that adsorption capacity increased with increasing temperature. Freundlich's separation factor showed that this adsorption process was an favorable treatment process. Estimated adsorption energy by Dubinin-Radushkevich isotherm model indicated that the adsorption of AF by activated carbon is a physical adsorption. Adsorption kinetics was found to follow the pseudo-second-order kinetic model. Surface diffusion at adsorption site was evaluated as a rate controlling step by the intraparticle diffusion model. Thermodynamic parameters such as activation energy, Gibbs free energy, enthalpy entropy and isosteric heat of adsorption were investigated. The activation energy and enthalpy change of the adsorption process were 21.19 kJ / mol and 23.05 kJ / mol, respectively. Gibbs free energy was found that the adsorption reaction became more spontaneously with increasing temperature. Positive entropy was indicated that this process was irreversible. The isosteric heat of adsorption was indicated physical adsorption in nature.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.11
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• pp.1238-1243
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• 2005

The batch experiments of biosorption were carried out for the removal of lead ion from metal solution using Laminaria japonica and Kjellmaniella crassifolia, two species of marine algaes as biosorbent. We have investigated biosorption kinetics and equilibrium of lead by using marine algaes. We observed that biosorption of lead occurred very rapidly by marine algaes ; the biosorption reached equilibrium less than 2 hr. These experimental data could be accurately described by a pseudo-second-order rate equation, obtaining values between $0.883{\times}10^{-3}$ and $0.628{\times}10^{-3}\;g/mg/min$ for the biosorption rate constant $k_{2,ad}$. It could be described with Langmuir, Redlich-Peterson, and Koble-Corrigan(Langmuir-Freundlich) equation. The biosorption capacity by L. japonica and K. crassifolia were in the sequence of Pb>Cd>Cr>Cu and Pb>Cu>Cd>Cr, respectively. The biosorption capacity of L. japonica were increased with pH increasing.