• Title/Summary/Keyword: pH저감

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Analysis of Seawater Intake System using the RNG k-𝜖 Algorithm (RNG k-𝜖 알고리즘을 이용한 해수취수시스템 분석)

  • Kim, Ji-Ho;Kim, Tae-Won;Lee, Seung-Oh;Park, Young-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6447-6454
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    • 2013
  • Seawater intake systems have significant problems due to seawater pollution, suspended solids, unstable intake and maintenance etc. An underground type seawater intake system was newly developed to overcome the existing weaknesses and was facilitated in Gyukpo port. In this study, to check the performance of the new system, the samples for water quality and the 3-D numerical modeling test were conducted. The five times test included the COD, total nitrogen, total phosphorus, pH, and suspended solid for the intake system. The analyses show that the COD, total nitrogen, total phosphorus, PH showedminor changes before and after. On the other hand, the change in suspended solids was significant and water was purified below 5 mg/l, first level fisheries water, after. The numerical model adopted the RNG $k-{\epsilon}$ algorithm and the CFX model based on the finite volume method. The porosity algorithm was used to reproduce filtered-sand, outer diameter, and thickness. The numerical results showed that the double pipe is advantageous in that it provides a uniform pressure between the inner and outer pipe for the flow to be stable. In addition, the use of multiple intake pipes did not interfere with the discharge reduction of 0.98 at the both intake pipes compared with the central intake pipe.

용담댐 건설로 인한 금강 상류의 하천환경변화 분석 III - 생태변화분석 -

  • 이승현;정동양;정승권
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.977-981
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    • 2004
  • 댐 건설로 인한 인위적인 당류량 조절은 댐 하류지역에서 홍수 피해저감에 기여하고 있지만, 자연적인 유출 리듬이 파괴되며 유속, 수심, 건조지 확대와 같은 수량의 변동과 용존산소량, 영양염류, pH 같은 수질 변화, 그리고 하천 형태의 변화를 가져오게 된다. 하천에서의 생물 서식공간은 산림 등 육지 지역과는 단리 무엇보다 하천의 유체역학적인 영향을 받아 형성되고 발달한다. 인위적인 댐 방류량은 하류지역의 건조 면적을 증가시키기 때문에 하천 형태가 변화하는 결과를 가져오고, 댐 건설로 인하여 자연적인 홍수 유출이 급감하게 되면 건조면적이 확산되어 수변식물과 어류의 서식처 환경 변화를 유발하여 기존의 생태 균형이 파괴될 것으로 예상된다. 지금까지 국내에서 댐 건설로 발생되는 피해를 분석한 연구들을 분석해 보면, 수량 및 수질 변화에 대하여는 많이 제시하고 있지만 생태변화에서는 정량적인 피해를 제시한 연구가 없기 때문에 용담댐 건설로 인한 하류구간의 수변식물과 어류를 대상으로 정량적인 피해를 분석하는 것이 매우 필요하다. 따라서 본 연구에서는 용담댐 건설로 인한 인위적인 유출량 감소가 댐 하류 8km 구간에서 수변식물과 어류에 미치는 영향을 예측하고자 하였으며, 이를 위해 용담댐 기점 약 5km지점(조사지점 I)인 전북 진안군용담댐 감동리 주변지역에서 수변식물과 어류 군집에 내하여 2003년 5월부터 7월까지 3회 조사하였고, 추가로 약 1km지점(조사지점II)인 전북 진안군 용담면 월계리 주변지역에서 수변식물을 중심으로 2003년 9월에서 10월까지 2회 조사하였다. 수변식물은 조사지점(I)인 5km지점에서는 전체적으로 13과 21종으로, 벼과가 4종, 국화과가, 3종, 버드나무과, 콩과, 마디풀과가 2종씩, 바늘꽃과, 속새과, 십자화과, 장미과, 사초과, 삼과, 현삼과, 닭의장풀과가 각 1종씩 조사되었으며, 조사지점(II)인 1km지점에서는 15과 26종으로, 벼과가 4종, 마디풀과, 국화과가 3종, 버드나무과, 십자화과, 콩과가 2종씩, 바늘꽃과, 속새과, 자라풀과, 장미과, 사초과, 백합과, 현삼과, 골풀과, 닭의장풀과가 각 1종씩으로, 조사지점( I )보다 좀 더 많은 종이 분포하는 것으로 조사되었다. 또한 어류는 조사지점( I )에서 3회에 걸쳐 총 396개체가 채집되어 3목 8과 21종이었다. 이 중 한국 고유종은 11종이었고, 외래 어종은 검정우럭과 2종이 조사되었으며, Zacco platypus(피라미), Zacco temmincki(갈겨니), Acheilongnathus koreanus(칼납자루), Odontobutis platycephala(동사리), Coreoleuciscus splendidus(쉬리) 순으로 분포하고 있었고, Acheilognathus signifer(묵납자루)는 댐 건설 전에는 많이 분포하였으나 현장조사에서 서식을 확인 할 수 언어 개체수의 큰 감소내지 멸종된 것으로 추정되었다.

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Determining Kinetic Parameters and Stabilization Efficiency of Heavy Metals with Various Chemical Amendment (중금속 안정화제의 반응 매개변수 결정 및 중금속 안정화 효율성 평가)

  • Oh, Se-Jin;Kim, Sung-Chul;Kim, Tae-Hee;Yeon, Kyu-Hun;Lee, Jin-Soo;Yang, Jae-E.
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1063-1070
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    • 2011
  • In this study, total of 5 different chemical amendments were evaluated for determining kinetic parameters and stabilization efficiency of heavy metals in aqueous phase. Standard solution of Cd and Pb ($100mg\;L^{-1}$) was mixed with various ratio of amendments (1, 3, 5, 10%) and heavy metal stabilization efficiency was monitored for 24hrs. All examined amendments showed over 90% of removal efficiency for both Cd and Pb except zerovalent iron (ZVI) for Cd (43-63%). Based on result of heavy metal stabilization efficiency, it was ordered as $CaCO_3$ > Dolomite > Zeolite > Steel slag > ZVI for both Cd and Pb in aqueous phase. For kinetic study, first order kinetic model was adapted to calculate kinetic parameters. In terms of reaction rate constants (k), zeolite showed the fastest reaction rate (k value from 0.4882 for 1% to 2.0105 for 10%) for Cd and ZVI (k value from 0.2304 for 1% to 0.5575 for 10%) for Pb. Considering reaction rate constant and half life for heavy metal stabilization, it was ordered as Zeolite > $CaCO_3$ > Dolomite > Steel slag > ZVI for Cd and $CaCO_3$ > Dolomite > Steel slag > Zeolite > ZVI for Pb. Overall result in this study can be interpreted that lime containing materials are more beneficial to remove heavy metals with high efficiency and less time consuming than absorbent materials.

Combustion Characteristic Study of LNG Flame in an Oxygen Enriched Environment (산소부화 조건에 따른 LNG 연소특성 연구)

  • Kim, Hey-Suk;Shin, Mi-Soo;Jang, Dong-Soon;Lee, Dae-Geun
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.1
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    • pp.23-30
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    • 2007
  • The ultimate objective of this study is to develop oxygen-enriched combustion techniques applicable to the system of practical industrial boiler. To this end the combustion characteristics of lab-scale LNG combustor were investigated as a first step using the method of numerical simulation by analyzing the flame characteristics and pollutant emission behaviour as a function of oxygen enrichment level. Several useful conclusions could be drawn based on this study. First of all, the increase of oxygen enrichment level instead of air caused long and thin flame called laminar flame feature. This was in good agreement with experimental results appeared in open literature and explained by the effect of the decrease of turbulent mixing due to the decrease of absolute amount of oxidizer flow rate by the absence of the nitrogen species. Further, as expected, oxygen enrichment increased the flame temperatures to a significant level together with concentrations of $CO_2$ and $H_2O$ species because of the elimination of the heat sink and dilution effects by the presence of $N_2$ inert gas. However, the increased flame temperature with $O_2$ enriched air showed the high possibility of the generation of thermal $NO_x$ if nitrogen species were present. In order to remedy the problem caused by the oxygen-enriched combustion, the appropriate amount of recirculation $CO_2$ gas was desirable to enhance the turbulent mixing and thereby flame stability and further optimum determination of operational conditions were necessary. For example, the adjustment of burner with swirl angle of $30\sim45^{\circ}$ increased the combustion efficiency of LNG fuel and simultaneously dropped the $NO_x$ formation.

Ecological Characteristics and Management Plan of Geumdangsil Pine Forest of Yecheon (예천 금당실 송림의 생태적 특성 및 관리방안)

  • Lee, Soo-Dong;Lee, Chan;Kim, Donwook;Kim, Jisuk
    • Korean Journal of Environment and Ecology
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    • v.27 no.6
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    • pp.718-732
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    • 2013
  • The purpose of this study was to provide data for the basic research to found the effective conservation and management plan for the Geumdangsil Pine Forest of Yecheon designated as Natural Monument No. 469. Furthermore, this paper suggest efficient sustainable forest preservation and using. In order to achieve the sustainable forest preservation, this study was to analyse topography, land use, tree growth, soil environment, forest usage and forest management, etc. According to analysis the results, the site area is located in the flatlands where is from 130 to 140 m above sea level. The around forest was transformed into agricultural land. The 565 individuals of Pinus densiflora grows in the forest, whereas, 25 trees was cut down or died. There are signs of 25 stumps. The most of 565 trees' diameter at breast height(DBH) was centerized between 30 cm and 50 cm, moreover, the average life expectancy of trees were 85.4 years. The oldest age of tree was estimated to be 200 years. The Sample trees of rate of branch growth is from 4.3 cm to 5.1 cm per year. The middle branch which is more vigorous growth grow 24.2 cm for 3 years. Moreover, the result of soil physico-chemical properties analysis of 7 plots, 4 categories which is soil organic matter, total nitrogen, available phosphoric acid, specific electrical conductance was generally good, however, the 2 categories which is soil pH, exchangeable cation needed improvement. Currently, the site was not pressured by facilities and usage, however, there might be threaten by agriculture such as encroaching on forest. Therefore, there should establish comprehensive ecosystem management such as facility management, visitors management and operation management In this paper considered 4 fields that is ecosystem management, facility management, visitors management and operation management for sustainable management.

Effects of Autoclave and Microwave Treatments for Quality of Wet Noodles (가압가열 및 Microwave 처리가 생면의 품질에 미치는 영향)

  • Bark, Si-Woo;Kim, Koth-Bong-Woo-Ri;Kim, Min-Ji;Kang, Bo-Kyeong;Pak, Won-Min;Kim, Bo-Ram;Park, Hong-Min;Choi, Jung-Su;Choi, Ho-Duk;Ahn, Dong-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.26 no.4
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    • pp.850-856
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    • 2013
  • This study was conducted to determine the effects of physical treatments for quality of wet noodles. Noodles were being tried with a microwave (for 1 min), an autoclave (for 30 or 50 min), and both autoclave and microwave (for 30/1 min or 50/1 min). The results showed that the pH levels were slightly decreased after treatments of autoclave and autoclave/microwave. The moisture contents were considerably decreased as compared to the control except autoclave (50 min). After all treatments, the lightness was decreased in all samples, but, redness was increased (except microwave) and the yellowness was increased after autoclave (50 min) and autoclave/microwave (50/1 min). Texture was increased as compared to the control except microwave. In the sensory evaluation, the noodles treated with microwave, autoclave (50 min), and autoclave/ microwave (50/1 min) showed a high score in overall preference. From these results, both the autoclave and microwave methods can be applied to the wet noodles without diminishing its quality to a great extent.

Recovery of Copper, Reuse of $TiO_2$, and Assessment of Acute Toxicity in the Photocatalytic Oxidation of Cu(II)-EDTA (Cu(II)-EDTA 광촉매 산화반응에서의 구리회수, $TiO_2$ 재사용 및 처리수 독성평가)

  • Yang, Jae-Kyu;Choi, Bong-Jong;Lee, Seung-Mok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.8
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    • pp.844-851
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    • 2005
  • The purpose of this study was to determine feasibility of application of regenerated or recycled $TiO_2$ on the successive treatment of Cu(II)-EDTA. The recovery of copper, the reuse of $TiO_2$ and the assessment of acute toxicity was studied in the total eight successive photocatalytic reactions. Aqueous solution of $10^{-4}\;M$ Cu(II)-EDTA was treated using an illuminated $TiO_2$ at pH 6 in a circulating reactor. Two different procedures were applied in the reuse of $TiO_2$: i) recycle of $TiO_2$ without acid wash ii) regeneration of $TiO_2$ with acid wash to remove adsorbed copper in a previous experiment. The averaged decomplexation rate constant($k'_{obs}$) of Cu(II)-EDTA in recycle of $TiO_2$ without acid wash was approximately 45% less than that in regeneration of $TiO_2$ with acid wash. Removal of Cu(II) was near complete after 180 minutes in the total eight successive photocatalytic reactions using the regenerated $TiO_2$ after acid wash. In contrast, removal of Cu(II) was minimum at total fifth successive photocatalytic oxidation using the recycled $TiO_2$ without arid wash. The recovered $TiO_2$ was approximately 86% in average in each procedure. The recovered Cu(II) was 67.9% in average. The acute relative toxicity of the treated water rapidly declined at an initial reaction time up to 60 minutes but little declination was observed after 60 minutes due to little degradation of DOC. Relative toxicity of treated water using the recycled $TiO_2$ without acid wash we some what well correlated with the concentration of dissolved Cu(II). From this work, it is suggested that Cu(II)-EDTA can be effectively treated using an integrated cyclic photocatalytic oxidation with recovery of $TiO_2$ and Cu(II).

Development and Application of Okara-based Adhesives for Plywood Panels (두부비지를 이용한 합판용 접착제의 개발 및 적용)

  • Oh, Sei-Chang;Ahn, Sye-Hee;Choi, In-Gyu;Jeong, Han-Seob;Yoon, Young-Ho;Yang, In
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.3
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    • pp.30-38
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    • 2008
  • Petroleum-based resin adhesives have extensively been used for the production of wood panels. However, with the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the adhesive resins, it is necessary to be developed new adhesive systems. In this study, the potential of okara, which is a residue wasted from the production of tofu, for the development of bio-based adhesives was investigated. At first, the physical and chemical properties of okara were examined. After okara was hydrolyzed in acidic and/or alkaline solutions, okara-based adhesive resins were formulated with the mixtures of the okara hydrolyzates and phenol formaldehyde (PF) prepolymer. The adhesive resins were used for the fabrication of plywood panels, and then the adhesive strength and formaldehyde emission of the plywood panels were measured to examine the applicability of the resin adhesives for the production of plywood panels. The solids content and pH of the okara used in this study were around 20% and weak acidic state, respectively. In the analysis of its chemical composition, the content of carbohydrate was the highest, and followed by protein. The shear strengths of plywood fabricated with okara-based resin adhesives exceeded a minimum requirement of KS standard for ordinary plywood, but its wood failure did not reach the minimum requirement. In addition, the formaldehyde emissions of all plywood panels were higher than that of E1 specified in the KS standard. Based on these results, okara has the potential to be used as a raw material of environmentally friendly adhesive resin systems for the production of wood panels, but further researches - biological hydrolysis of okara and various formulations of PF prepolymer - are required to improve the adhesive strength and formaldehyde emission of okara-based resin adhesives.

Macrozoobenthic Community Structures in the Shallow Subtidal Soft-bottoms around Wando-Doam Bay during Summer Season (남해 완도-도암만 연성기질의 여름철 대형저서동물의 군집구조)

  • LIM, HYUN-SIG;CHOI, JIN-WOO;SON, MIN-HO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.23 no.2
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    • pp.91-108
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    • 2018
  • An ecological study on subtidal macrobenthic fauna was conducted from 25 stations in the estuarine area of Wando-Doam Bay, southern coast of Korea during August 2013. A total of 186 species was collected with a mean density of $1,229ind./m^2$ and a mean biomass of $265.7g/m^2$. Polychaetes showed the richest benthic fauna comprising 43% of total fauna, whereas mollusks appeared as density- and biomass-dominant fauna accounted for 45% and 48% of the mean density and biomass, respectively. The number of species and mean faunal density were relatively higher at the stations surrounded by Sinjido, Joyakdo and Gogeumdo showing a gradual decrease toward inner bay stations. Species number and density were negatively correlated with bottom water temperature, but they were positively correlated with both the bottom salinity and DO. The most dominant species in terms of density was a semelid bivalve, Theora fragilis which showed a positive correlation with TOC content of surface sediment and its high density occurred around Gogeum-Sinji-Joyakdo area where dense aquaculture facilities exist. In the bay mouth area, an amphipod species, Eriopisella sechellensis showed its higher density at the stations with low organic content but fine grains. The combination of water temperature, salinity, pH of bottom water, water and sulfur content of the surface sediment could explain 71% of the spatial distribution of macrobenthic fauna from the Bio-Env analysis. From the cluster analysis, the study area consisted of 6 distinct station groups lineated from offshore area toward inner area. Ampharete arctica, Goniada maculata, Eriopisella sechellensis, Theora fragilis, Caprella sp. were identified as the main contributing faunas in classification by the SIMPER analysis. From the value of BPI, the benthic communities at the inner and central Wando-Doam Bay were assessed to be in a normal condition whereas those at the outer Wando harbor and Gogeum-Sinji-Joyakdo area were assessed in a poor or very poor condition due to the high concentration of particulate organic matter might be originated from the nearby dense aquaculture facilities. This study indicated that pristine inner bay has been influenced by the organic material supplied from the outer bay. Thus it is necessary to establish an ecological management plan to reduce organic enrichment of sediment from dense aquaculture facilities in the outer bay.

The Topsoil Characteristics, and Estimation of Topsoil Organic Carbon Storage at Restoration Areas in Riparian Zones of the Han River (한강 수변구역 복원지의 표토 특성 및 유기탄소 저장량 추정)

  • Lee, Jong-Mun;Cho, Yong-Hyeon;Kim, Yoon-Ho;Park, Sung-Woo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.47 no.4
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    • pp.12-23
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    • 2019
  • This study was carried out to investigate and analyze the environmental characteristics of restoration areas in the riparian zones of the Han River, and to quantify the amount of topsoil organic carbon storage. As a result of investigation and analysis of 21 survey sites, the total number of species planted was found to be 17, and the mean number of species was $2.86{\pm}0.13$ species per site. At least one species and a maximum of 7 species were planted at each site. The mean diameter at breast height was $9.1{\pm}0.6cm$, the mean height was $6.2{\pm}0.3m$ and the root content in soil was $0.13{\pm}0.18g/cm^2$. As a result of the analysis of the soil characteristics, 6 out of 21 items, such as the bulk density, solid ratio, gravel ratio, soil hardness, sand content, and pH increased as the soil layer deepened. The topsoil organic carbon storage by layer was $11.54{\pm}1.08ton/ha$ at 0-10cm, $8.69{\pm}0.81ton/ha$ at 10-20cm, $7.97{\pm}0.79ton/ha$ at 20-30cm, and the total from 0 to 30cm was $28.21{\pm}7.31ton/ha$. The highest amount of topsoil organic carbon storage by land use in the past was $35.17{\pm}5.31ton/ha$ in agricultural lands, followed by $28.16{\pm}8.31ton/ha$ in residential areas, $21.87{\pm}9.05ton/ha$ in commercial areas, $19.23{\pm}12.48ton/ha$ in industrial areas, and $17.07{\pm}11.33ton/ha$ in the barren areas. The highest amount of topsoil organic carbon storage in the restored areas was $38.46{\pm}3.14ton/ha$ in 2006, followed by $28.57{\pm}7.84ton/ha$ in 2016, and $16.78{\pm}6.06ton/ha$ in 2011. The results of this study are expected to provide a basic database and evaluation criteria for enhancing the carbon abatement effects of the restoration sites in riparian zones in the future.