• 한국환경과학회지
• /
• 제14권7호
• /
• pp.691-697
• /
• 2005

Waste sludge may be used to recovery wastewater contaminated with heavy metals. The waste sludge is an inexpensive readily available source of biomass for biosorption with metal-bearing wastewater. The biosorption of heavy metals such as Pb(II), Cu(II), Cr(II), and Cd(II) onto waste sludge was investigated in batch ex­periments and waste sludge loaded heavy metals was separated by dissolved air flotation. The biosorption equi­bria of heavy metals could be described by Langmuir and Freundich isotherms. The adsorption capacity for waste sludge was in the sequence of Pb(II)>Cr(II)>Cu(II)>Cd(II). The system attained equilibrium about 20 min. The Langmuir and Freundlich adsorption model effectively described the biosorption equilibrium of Cu(II) and Cr(II) ions on waste sludge. Maximum adsorption capacity of Cu(II) and Cr(II) were 196.08 and 158.73 mg/g, respectively. Solid-liquid separation efficiencies were kept above $95\%$ on waste sludge loaded heavy metals, and were decreased with pH increasing.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2008년도 추계 학술발표회
• /
• pp.267-267
• /
• 2008

시멘트를 이용한 지반개량 및 시멘트계 건설폐기물을 (예, 폐콘크리트, 및 시멘트 개량토 등) 성토재로 재활용하는 경우 지반 환경에 미칠 수 있는 영향으로는 (1) 시멘트에 함유된 6가 크롬($Cr^{6+}$) 및 (2) 강알칼리 물질의 용출이 있을 수 있다. 특히 $Cr^{6+}$의 경우 인체에 치명적인 발암성물질로 알려져 있어 이에 따른 주의가 필요하다. 최근 일본에서는 시멘트의 $Cr^{6+}$에 의한 지반오염이 우려됨에 따라 2000년 시멘트계 고화재를 지반에 사용하는 경우와 개량된 토양을 재이용하는 경우에는 토양환경기준을 만족하도록 규제하고 있다. $Cr^{6+}$외의 시멘트계 물질에 의한 환경오염으로는 강알칼리 물질의 유출이 있을 수 있다. 시멘트 개량토나 폐콘크리트 등의 건설폐기물을 성토재로 재활용하는 경우, 강우의 유입에 따라 구성물질인 수산화칼슘이 용해되어 높은 pH의 유출수가 발생한다. 강알칼리 유출수가 주변 하천 등으로 유입되는 경우 심각한 환경문제를 유발할 수 있으므로 이에 대한 기술적 검토가 필요하다. 본 발표에서는 시멘트계 물질에 의한 일본의 지반환경오염 사례 및 대책을 소개하였다.

• Structural Engineering and Mechanics
• /
• 제25권4호
• /
• pp.383-403
• /
• 2007

The contact problem for an elastic layer resting on an elastic half plane is considered according to the theory of elasticity with integral transformation technique. External loads P and Q are transmitted to the layer by means of two dissimilar rigid flat punches. Widths of punches are different and the thickness of the layer is h. All surfaces are frictionless and it is assumed that the layer is subjected to uniform vertical body force due to effect of gravity. The contact along the interface between elastic layer and half plane will be continuous, if the value of load factor, ${\lambda}$, is less than a critical value, ${\lambda}_{cr}$. However, if tensile tractions are not allowed on the interface, for ${\lambda}$ > ${\lambda}_{cr}$ the layer separates from the interface along a certain finite region. First the continuous contact problem is reduced to singular integral equations and solved numerically using appropriate Gauss-Chebyshev integration formulas. Initial separation loads, ${\lambda}_{cr}$, initial separation points, $x_{cr}$, are determined. Also the required distance between the punches to avoid any separation between the punches and the layer is studied and the limit distance between punches that ends interaction of punches, is investigated. Then discontinuous contact problem is formulated in terms of singular integral equations. The numerical results for initial and end points of the separation region, displacements of the region and the contact stress distribution along the interface between elastic layer and half plane is determined for various dimensionless quantities.

• 대한금속재료학회지
• /
• 제47권5호
• /
• pp.283-289
• /
• 2009

This paper dealt with a statistical analysis for evaluating the creep crack growth rate (CCGR) for Modified 9Cr-1Mo (ASTM Grade 91) steel. The CCGR data was obtained by the creep crack growth (CCG) tests conducted under various applied loads at $600^{\circ}C$. To obtain logically the B and q values used in the CCGR equation, three methods such as the least square fitting method (LSFM), the mean value method (MVM) and the probabilistic distribution method (PDM) were adopted and their CCGR lines were compared, respectively. In addition, a number of random variables were generated by using the Monte Carlo simulation (MCS), and the CCGR lines were predicted probabilistically. It was found that both the B and q coefficients followed a 2-parameter Weibull distribution well. In the case of the ranges of 10-90% for the probability variables, P(B, q), the CCGR lines were predicted. Fractographic study was conducted from the specimen after the CCG tests.

• 한국농공학회:학술대회논문집
• /
• 한국농공학회 2001년도 학술발표회 발표논문집
• /
• pp.509-512
• /
• 2001

In this study, pollutant load from paddy field was estimated by regression equation from 5 to 8 in 2001. During study period, total rainfall was 511.3mm and runoff discharge was 968.71mm. Regression equation between flow rate(m3/s) and pollutant loading rate(g/s) is exponential relationship. For site 1, coefficient of determination (R2) for $COD_{cr}$, T-P, T-N were 0.7068, 0.8441, 0.6806 respectively and site 2, 0.9369, 0.8855, 0.4262 respectively. Considering unit loads, Jun was the highest valus as 13.85 $COD_{c}kg/km2/day$, 0.24 T-Pkg/km2/day, 1.22 T-Nkg/km2/day. Until study period, total $COD_{cr}$ load estimated regression equation is 19.32kg/km2/day and, T-P, T-N were 0.264, 1.88 respectively

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2001년도 추계학술발표회
• /
• pp.249-253
• /
• 2001

퇴적물에 오염된 중금속의 지화학적 특성을 규명하고자, 연속추출방법을 이용하여 구성광물 과의 지구화학적 수반관계와 산성화에 따른 중금속 용출특성을 연구하였다. 용출실험과 연속추출 실험을 종합한 연구결과, 서울시 도로변의 하수퇴적물이 산성비와 같은 요인에 의해 pH 5.0정도의 약산성환경과 접촉하였을 때 중금속의 상대적인 용출특성은 Zn>>Cd$\geq$Co>Ni>Cu$\geq$Pb>Cr이며, 원소별 용출량은 Zn 40-90%, Cd 10-30%, Co 15-25%, Ni 5-25%, Cu 0-20%, Pb 0% 및 Cr 0% 이었다. 하수퇴적물에 오염된 Zn, Cd, Cu 및 Ni의 용출은 매우 우려할 만한 수준이며, 수계의 물리화학적 변화(pH 등)에 따라 이들 원소의 일부분이 용해되어 지표수 및 강물을 오염시킬 것으로 예상된다.

• 대한간호학회지
• /
• 제5권1호
• /
• pp.87-92
• /
• 1975

This study was performed from July to December 1974 to investigate the rates of contamination of distilled water for injection and local anesthetics. 222 vials were sampled from 7 different places of St. Mary's Hospital The samples were cultured for isolation of microorganisms. The results were as follows; 1. Of 222 vials, 11 were Contaminated by 6 types: Staphylococcus epidermis, Bacillus subtilis, Mima polymorph a, Alcaligenes faecalis, Herellea vaginicala and pepto- streptococcus. 2. 5(9.1 %) of 55 vials from surgical wards, 2 (4.2 %) of 48 vials from surgical OPD, and 4 (12,l %) of 33 vials from pediatric wards were contaminated 3. Between rates of contamination of distilled water for injection and local anesthetics and the number of punctures, there was no significant relationship. (CR=1.42 P〉0.1) 4. There was no significant relationship (CR=1.02 P〉0.1) between the rates of contamination of vials and the duration of the first and the last punctures. 5. The ratios of contamination between 75% alcohol and 2% phenol used for disinfection of rubber lids of vials did not show significant difference.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2007년 추계학술발표대회 개요집
• /
• pp.39-41
• /
• 2007

In this study, actual scale welding were conducted at the USC thermal power plant turbine and main steam pipe casting candidate mock up material 9Cr-1.5Mo-CoVNbNB steel(CB2) and 9Cr-0.5Mo-MVNbN steel(P92). And to evaluate the welding process for the actual production, mechanical property testes were conducted for the weld metal. The Mock-up welding condition successfully led to an excellent structural welding joint between casting and pipe material.

• 한국자원식물학회지
• /
• 제3권2호
• /
• pp.107-114
• /
• 1990

In view of the results to have measured metallic elements which is included in 45 sorts of herb medicines and surveyed their distribution, 8 kinds ofmetals including Co, Ge, Ga, TL, Cd, As, 8i, Pb, are never or little includedin almost herb medicines . Other twenty-five sorts of elements (Mo, Sc, Be, V,Ni, Sn, Se, Ba, Cr, Sb, Si, Ti, B, Li, Mg, Ca, Cr, Mn, Fe, Cu, Zn, p, Al, Na,K) are more or Less included in all herb Bedicines ana Na, Ca, p and K aremetals that are included in Large quentities in comrarison with others . Patri-uiae Radix Contains 7 kinds of metal lic elements more than other herb medicinesdoes .

• 자원환경지질
• /
• 제40권4호
• /
• pp.347-360
• /
• 2007

고성군에 위치한 폐구리광산의 중금속 오염범위와 정도 및 환경위해성을 평가하기 위하여 광산지역으로부터 토양과 벼를 채취하여 중금속 함량을 분석하였다. 중금속 함량은 논토양에 비해 산토양에서 훨씬 높았다. 중금속 전함량은 산토양에서 Cu>Zn>Pb>As>Cr>Cd, 논토양에서 Zn>Pb>Cu>Cr>As>Cd 순으로 감소하였으며, 0.1/1N HCl에 의한 중금속 용출량은 산토양에서 Cu>Pb>Zn>As>Cd>Cr, 논토양에서 Pb>Cu>Zn>As>Cd>Cr 순으로 나타났다. 중금속 용출비는 시료채취지점에 따라 매우 다양하였지만 평균적으로는 Cd(16%)>Pb(10%)>Cu(9%)>As(4.5%)>Zn-Cr(${\le}2.5%$)의 순이었다. 조사대상 토양들은 지각평균값에 비해 중금속이 부화되어 있으며 그 순서는 $As{\ge}Cd>Pb>Zn>Cu>Cr$이었다. 토양의 중금속 전함량 또는 용출량으로부터 계산한 오염지수는 중금속 오염이 폐구리광산 특히 삼산제일광산 주변의 산토양에 국한되어 있음을 나타내었다. 현미 중의 중금속함량은 As $nd{\sim}0.87mg/kg,\;Cd\;0.02{\sim}0.34mg/kg,\;Cu\;1.01{\sim}6.25mg/kg,\;Mn\;13.4{\sim}43.2mg/kg,\;Pb\;0.09{\sim}2.83mg/kg$ 및 $Zn\;16.5{\sim}79.1mg/kg$으로 심각하게 오염된 수준은 아니었다. 토양 pH와 함께 중금속의 용출 및 분포특성들은 이 지역 중금속 오염의 대부분이 중금속의 용해 순환보다는 폐광석과 맥석광물의 쇄설성 이동에 의해 진행되고 있음을 시사하였다.